Persulfate decontamination technologies utilizing radical‐driven processes are powerful tools for the treatment of a broad range of impurities.However,the design of high‐performance catalytic activators with multi‐...Persulfate decontamination technologies utilizing radical‐driven processes are powerful tools for the treatment of a broad range of impurities.However,the design of high‐performance catalytic activators with multi‐functionality remains a great challenge.Therefore,in this study,three‐dimensional multifunctional FexOy/N‐GN/CNTs(N‐GN:nitrogen‐doped graphene,CNTs:carbon nanotubes)heterojunctions,which can be employed as microwave absorbers and catalysts,were synthesized via a solvothermal method and applied to activate peroxymonosulfate for the degradation of methylene blue(MB).X‐ray diffraction(XRD),Fourier transform infrared spectrometer(FTIR),scanning electron microscope(SEM),and X‐ray photoelectron microscopy(XPS)analyses revealed that the FexOy were anchored in‐situ onto the N‐GN network.Using MB as the model organic dye,various factors,such as degradation systems,PMS loading,initial organic pollutant concentration,and catalyst dosage were optimized.The results revealed that the remarkable efficiency was attributable to the synergistic effects of carbon,nitrogen,and iron‐based species.The oxidation system corresponded to the pseudo‐first‐order kinetic with a k value of^0.33 min^-1.It was demonstrated that both SO4^-and OH^-were the predominant reactive species through quenching experiments.Because these heterojunctions were employed as microwave absorbers and have a semiconductor‐like texture,the Fe/N co‐rich hierarchical porous carbon skeleton favored electron transport and storage.These heterojunctions increase the options for transitional metal catalysts and highlights the importance of designing other heterojunctions for specific applications,such as supercapacitors,energy storage,CO2 capture,and oxygen reduction electrocatalysts.展开更多
基金supported by the National Natural Science Foundation of China(21676039)Innovative talents in Liaoning universities and colleges(LR2017045)the Opening Foundation of State Key Laboratory of Inorganic Synthesis and Preparative Chemistry of Jilin University(2016–04)~~
文摘Persulfate decontamination technologies utilizing radical‐driven processes are powerful tools for the treatment of a broad range of impurities.However,the design of high‐performance catalytic activators with multi‐functionality remains a great challenge.Therefore,in this study,three‐dimensional multifunctional FexOy/N‐GN/CNTs(N‐GN:nitrogen‐doped graphene,CNTs:carbon nanotubes)heterojunctions,which can be employed as microwave absorbers and catalysts,were synthesized via a solvothermal method and applied to activate peroxymonosulfate for the degradation of methylene blue(MB).X‐ray diffraction(XRD),Fourier transform infrared spectrometer(FTIR),scanning electron microscope(SEM),and X‐ray photoelectron microscopy(XPS)analyses revealed that the FexOy were anchored in‐situ onto the N‐GN network.Using MB as the model organic dye,various factors,such as degradation systems,PMS loading,initial organic pollutant concentration,and catalyst dosage were optimized.The results revealed that the remarkable efficiency was attributable to the synergistic effects of carbon,nitrogen,and iron‐based species.The oxidation system corresponded to the pseudo‐first‐order kinetic with a k value of^0.33 min^-1.It was demonstrated that both SO4^-and OH^-were the predominant reactive species through quenching experiments.Because these heterojunctions were employed as microwave absorbers and have a semiconductor‐like texture,the Fe/N co‐rich hierarchical porous carbon skeleton favored electron transport and storage.These heterojunctions increase the options for transitional metal catalysts and highlights the importance of designing other heterojunctions for specific applications,such as supercapacitors,energy storage,CO2 capture,and oxygen reduction electrocatalysts.
