Ultrafine grain pure aluminum was produced by equal channel angular pressing and cold rolling, the deformed aluminum was annealed at 200 ℃ for 1 h. The tensile curves of deformed and annealed aluminum show that yield...Ultrafine grain pure aluminum was produced by equal channel angular pressing and cold rolling, the deformed aluminum was annealed at 200 ℃ for 1 h. The tensile curves of deformed and annealed aluminum show that yield strength of deformed aluminum increases by 100%-300% and its elongation decreases by about 20%. After low temperature annealing, strength of annealed aluminum increases by 20% and elongation decreases by over 50%, the recovery of dislocations may be the main cause of annealing strengthening. In addition, there is an abrupt stress drop in the tensile curves of annealed aluminum and the formation of shear band is responsible for it.展开更多
Carbothermic reduction alumina in vacuum was conducted, and the products were analysed by means of XRD and gas chromatography. Thermodynamic analysis shows that in vacuum the initial carbothermic reduction reaction te...Carbothermic reduction alumina in vacuum was conducted, and the products were analysed by means of XRD and gas chromatography. Thermodynamic analysis shows that in vacuum the initial carbothermic reduction reaction temperature reduces compared with that under normal pressure, and the preferential order of products is Al404C, Al4C3, Al2OC, Al20 and A1. Experiment results show that the carbothermic reduction products of alumina are A1404C and A14C3, and neither A12OC, Al20 or Al was found. During the carbothermic reduction process, the reaction rate of Al203 and carbon decreases gradually with increasing time. Meanwhile, lower system pressure or higher temperature is beneficial to the carbothermic reduction of alumina process. A1404C is firstly formed in the carbothermic reaction, and then A14C3 is formed in lower system pressure or at higher temperature.展开更多
The effects of acid deposition on pine forest ecosystems in Longli of Guizhou Province, southwestern China are studied using indoor experiments and model simulations. Indoor experiments are designed to explore the alu...The effects of acid deposition on pine forest ecosystems in Longli of Guizhou Province, southwestern China are studied using indoor experiments and model simulations. Indoor experiments are designed to explore the aluminum toxicity on pine seedlings, and the long-term soil acidification model (LTSAM) and a terrestrial biogeochemistry model (CENTURY) are used to simulate the influences of acid deposition on pine forest ecosystems. The indoor experiment results of aluminum toxicishow that aluminum ions in solution limit plant growth and acid deposition enhances this effect by facilitating the release of aluminum ions from the soil. Pine seedling bio- mass and root elongation decrease as the aluminum concentration increases. The results of model simulations show that the soil chemis- try varies significantly with different changes in acid deposition. When the acid deposition increases, the pH value in the soil solution decreases and the soil A13+ concentration increases. The increased acid deposition also has negative impacts on the forest ecosystem, i.e., decreases plant biomass, net primary productivity (NPP) and net C02 uptake. As a result, the soil organic carbon (SOC) decreases be- cause of the limited supply of decomposition material. Thus acid deposition need be reduced to help protect the forest ecosystems.展开更多
基金Project(gjd08011) supported by Shanghai Municipal Education Commission,ChinaProject (J51402) supported by Shanghai Leading Academic Discipline,China
文摘Ultrafine grain pure aluminum was produced by equal channel angular pressing and cold rolling, the deformed aluminum was annealed at 200 ℃ for 1 h. The tensile curves of deformed and annealed aluminum show that yield strength of deformed aluminum increases by 100%-300% and its elongation decreases by about 20%. After low temperature annealing, strength of annealed aluminum increases by 20% and elongation decreases by over 50%, the recovery of dislocations may be the main cause of annealing strengthening. In addition, there is an abrupt stress drop in the tensile curves of annealed aluminum and the formation of shear band is responsible for it.
基金Project(U0837604) supported by the Natural Science Foundation of Yunnan Province,ChinaProject(Jinchuan 201114) supported by the Pre Research Foundation of Jinchuan Group Ltd.,ChinaProject(2011148) supported by the Analysis and Testing Funds of Kunming University of Science and Technology,China
文摘Carbothermic reduction alumina in vacuum was conducted, and the products were analysed by means of XRD and gas chromatography. Thermodynamic analysis shows that in vacuum the initial carbothermic reduction reaction temperature reduces compared with that under normal pressure, and the preferential order of products is Al404C, Al4C3, Al2OC, Al20 and A1. Experiment results show that the carbothermic reduction products of alumina are A1404C and A14C3, and neither A12OC, Al20 or Al was found. During the carbothermic reduction process, the reaction rate of Al203 and carbon decreases gradually with increasing time. Meanwhile, lower system pressure or higher temperature is beneficial to the carbothermic reduction of alumina process. A1404C is firstly formed in the carbothermic reaction, and then A14C3 is formed in lower system pressure or at higher temperature.
基金Under the auspices of National Basic Research Program of China(No.2010CB951802,2005CB422207)Knowledge Innovation Program of Chinese Academy of Sciences(No.KZCX2-YW-219)National High Technology Research and Development Program of China(No.2009AA122104)
文摘The effects of acid deposition on pine forest ecosystems in Longli of Guizhou Province, southwestern China are studied using indoor experiments and model simulations. Indoor experiments are designed to explore the aluminum toxicity on pine seedlings, and the long-term soil acidification model (LTSAM) and a terrestrial biogeochemistry model (CENTURY) are used to simulate the influences of acid deposition on pine forest ecosystems. The indoor experiment results of aluminum toxicishow that aluminum ions in solution limit plant growth and acid deposition enhances this effect by facilitating the release of aluminum ions from the soil. Pine seedling bio- mass and root elongation decrease as the aluminum concentration increases. The results of model simulations show that the soil chemis- try varies significantly with different changes in acid deposition. When the acid deposition increases, the pH value in the soil solution decreases and the soil A13+ concentration increases. The increased acid deposition also has negative impacts on the forest ecosystem, i.e., decreases plant biomass, net primary productivity (NPP) and net C02 uptake. As a result, the soil organic carbon (SOC) decreases be- cause of the limited supply of decomposition material. Thus acid deposition need be reduced to help protect the forest ecosystems.