Micro-honeycomb ceramics were successfully fabricated through brush-coating with cloth fabric as pore-forming agent. The influence of pore-forming agent and slurry’s moisture content on the micro-honeycomb ceramics w...Micro-honeycomb ceramics were successfully fabricated through brush-coating with cloth fabric as pore-forming agent. The influence of pore-forming agent and slurry’s moisture content on the micro-honeycomb ceramics was investigated. The results indicated that micro-honeycomb ceramics made from pore-forming agent cloth fabric with fibre diameter of 100 μm and slurry with 45% （mass fraction） moisture content have the porosity of 65% （volume fraction）, bending strength of 24.3 MPa, pore size of about 100 μm, cell wall thickness of about 50 μm and porosity of 1131 pore/cm2. It was suggested that the pore size and the porosity could be adjusted using the pore-forming agent and moisture content of the slurry respectively.展开更多
In the present work,TiAlN coatings were deposited on Ti(C,N)-based cermet substrates by physical vapor deposition method.Emphasis was focused on the influence of grain size of cermet substrates on the microstructure,g...In the present work,TiAlN coatings were deposited on Ti(C,N)-based cermet substrates by physical vapor deposition method.Emphasis was focused on the influence of grain size of cermet substrates on the microstructure,growth behavior,mechanical properties,adhesion strength and wear behavior of the coatings.The results show that finer Ti(C,N)grain size leads to higher nucleation density and lower growth rate of coatings,indicating the crystallite size of the TiAlN coatings decreases with decreasing Ti(C,N)grain size.Nanoindentation tests show that the coatings deposited on cermets of the finest grain size exhibit the highest hardness(H),elastic modulus(E),H/E and H3/E2 of 34.5 GPa,433.2 GPa,0.080 and 0.22,respectively.The adhesion strength between coating and substrate is also enhanced with decreasing Ti(C,N)grain size by scratch test,which corresponds to the grain size and H/E and H3/E2 of the coating.Besides,the lower surface roughness and better mechanical properties of the coating deposited on finer grained cermet contribute to the better wear resistance of the coating.展开更多
The dispersion, stabilization and rheological properties of the slurry with various relative molecular masses of PVB were studied. The sintering properties, microstructure and dielectric properties of borosilicate gla...The dispersion, stabilization and rheological properties of the slurry with various relative molecular masses of PVB were studied. The sintering properties, microstructure and dielectric properties of borosilicate glass/Al203 composites were also investigated. The intensities of the typical vibrating bands decrease with the decrease of the relative molecular mass of PVB, which demonstrates that the content of butyral groups in PVB binders decreases correspondingly, leading to a rapid decrease in the viscosity of the mixed slurry. The solid content of samples increases with the decrease of the relative molecular mass of PVB, and this further leads to the increase of tape thickness, bulk density and dried-shrinkage coefficient of tapes. The bulk density, relative density, three-point strength and dielectric constant of sintered samples increase with the increase of the solid content, and the shrinkage and dielectric loss decrease. By contrast, samples for PVB-5s exhibit better properties of a bulk density of 3.10 g/cm3, a relative density of 98.1%, a three-point strength of 208 MPa, aεt value of 8.01, a tanδ value of 7.6× 10^-4 at 10 MHz and a well matching with Ag electrodes.展开更多
Ceramic fiber reinforced silica aerogel composites are novel insulation materials in the thermal protection field for hypersonic vehicles. Before the aerogel composites are applied in load-bearing structures, it is ne...Ceramic fiber reinforced silica aerogel composites are novel insulation materials in the thermal protection field for hypersonic vehicles. Before the aerogel composites are applied in load-bearing structures, it is necessary to investigate their mechanical properties including load-bearing and deformation recovery capabilities. High temperature from service conditions will have important effects on the mechanical properties of thermal protection materials. In this paper, compression tests including loading and unloading stages were conducted for ceramic fiber reinforced silica aerogel composites at room temperature and elevated temperatures(300℃, 600℃ and 900℃). Influences of thermal exposure to high temperature and high temperature service environment on the compression property and deformation recovery were both investigated. Scanning electron microscopy(SEM), Fourier transform infrared spectroscopy(FT-IR) and X-ray diffraction(XRD) were applied to help understand the mechanisms of mechanical property variations. The experimental results show that the compression modulus and strength both increase with the increasing thermal exposure temperature and testing temperature,but the deformation recovery capability decreases. The micro structure changes caused by thermal sintering are considered as the main reason for the property variations.Viscous flow and matter transport due to high temperature resulted in the fusion of aerogel particles. This made the particle skeleton thicker and stronger, which led to higher stiffness and strength of the composites. However, matrix cracks induced by the formation and fracture of larger pores made unrecoverable deformation more serious. In the tests at elevated temperatures,the aggregation of aerogel particles in a fused state got more severe because of the addition of mechanical load. As a result, the degradation of deformation recovery capability became more significant.展开更多
LA-ICP-MS zircon U-Pb isotopic dating and rock geochemical analysis were done of the Xarru granite in the middle section of the Yarlung Zangbo junction zone. Zircon 2-6pb/Z38u weighted mean ages of 474.9±2.3 and ...LA-ICP-MS zircon U-Pb isotopic dating and rock geochemical analysis were done of the Xarru granite in the middle section of the Yarlung Zangbo junction zone. Zircon 2-6pb/Z38u weighted mean ages of 474.9±2.3 and 478.3±1.7 Ma have been obtained for two gneiss granite samples respectively, which represent the formation age of the granite. This is the first discovery of the Early Ordovician magmatism in the Yarlung Zangbo junction zone. The rocks are high-K calcic-alkalic granite, contain tour- maline but not hornblende, with aluminum saturation index （ASI） of A/CNK〉I.1 （1.10-1.20）, and are enriched in Rb, Th and U and relatively depleted in Ba, Nb, Sr, Zr, Ti and Eu. They are strongly peraluminous S-type granite, resulting from partial melting of argillaceous components in the crust in a syn-collisional setting. According to previous studies as well as the analy- sis in this paper, the formation of the Xarru granite is probably related to the Andean-type orogeny in the process of subduction of the Proto-Tethys Ocean towards the Gondwanaland, and it is a product of partial melting of the thickened upper crust as a result of collision between blocks or micro-blocks in the northern margin of the Gondwana supercontinent in the process of oceanic subduction. The Xarru granite is identified as the Early Ordovician granite, indicating that the wall rocks had probably formed in the Cambrian or Precambrian.展开更多
基金Project (2011WK4013) supported by the Basic Research Program of Hunan Provincial Science and Technology Department, ChinaProject (K1003031-11) supported by the Major Program for the Fundamental Research of Changsha Science and Technology Bureau, China
文摘Micro-honeycomb ceramics were successfully fabricated through brush-coating with cloth fabric as pore-forming agent. The influence of pore-forming agent and slurry’s moisture content on the micro-honeycomb ceramics was investigated. The results indicated that micro-honeycomb ceramics made from pore-forming agent cloth fabric with fibre diameter of 100 μm and slurry with 45% （mass fraction） moisture content have the porosity of 65% （volume fraction）, bending strength of 24.3 MPa, pore size of about 100 μm, cell wall thickness of about 50 μm and porosity of 1131 pore/cm2. It was suggested that the pore size and the porosity could be adjusted using the pore-forming agent and moisture content of the slurry respectively.
基金Projects(51634006,51575368)supported by the National Natural Science Foundation of ChinaProject(2017GZ0041)supported by Science and Technology Support Program of Sichuan Province,China。
文摘In the present work,TiAlN coatings were deposited on Ti(C,N)-based cermet substrates by physical vapor deposition method.Emphasis was focused on the influence of grain size of cermet substrates on the microstructure,growth behavior,mechanical properties,adhesion strength and wear behavior of the coatings.The results show that finer Ti(C,N)grain size leads to higher nucleation density and lower growth rate of coatings,indicating the crystallite size of the TiAlN coatings decreases with decreasing Ti(C,N)grain size.Nanoindentation tests show that the coatings deposited on cermets of the finest grain size exhibit the highest hardness(H),elastic modulus(E),H/E and H3/E2 of 34.5 GPa,433.2 GPa,0.080 and 0.22,respectively.The adhesion strength between coating and substrate is also enhanced with decreasing Ti(C,N)grain size by scratch test,which corresponds to the grain size and H/E and H3/E2 of the coating.Besides,the lower surface roughness and better mechanical properties of the coating deposited on finer grained cermet contribute to the better wear resistance of the coating.
基金Project(2007AA03Z455) supported by the National High Technology Research and Development Program of ChinaProjects(BE2009168)supported by Science&Technology Pillar Program of Jiangsu Province, China+2 种基金Project supported by the Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions, ChinaProject(CXZZ12_0415) supported by the Innovation Foundation for Graduate Students of Jiangsu Province, ChinaProject(IRT1146) supported for Changjiang Scholars and Innovative Research Teamin University (PCSIRT) of China
文摘The dispersion, stabilization and rheological properties of the slurry with various relative molecular masses of PVB were studied. The sintering properties, microstructure and dielectric properties of borosilicate glass/Al203 composites were also investigated. The intensities of the typical vibrating bands decrease with the decrease of the relative molecular mass of PVB, which demonstrates that the content of butyral groups in PVB binders decreases correspondingly, leading to a rapid decrease in the viscosity of the mixed slurry. The solid content of samples increases with the decrease of the relative molecular mass of PVB, and this further leads to the increase of tape thickness, bulk density and dried-shrinkage coefficient of tapes. The bulk density, relative density, three-point strength and dielectric constant of sintered samples increase with the increase of the solid content, and the shrinkage and dielectric loss decrease. By contrast, samples for PVB-5s exhibit better properties of a bulk density of 3.10 g/cm3, a relative density of 98.1%, a three-point strength of 208 MPa, aεt value of 8.01, a tanδ value of 7.6× 10^-4 at 10 MHz and a well matching with Ag electrodes.
基金supported by the National Natural Science Foundation of China(Grant No.51275023)
文摘Ceramic fiber reinforced silica aerogel composites are novel insulation materials in the thermal protection field for hypersonic vehicles. Before the aerogel composites are applied in load-bearing structures, it is necessary to investigate their mechanical properties including load-bearing and deformation recovery capabilities. High temperature from service conditions will have important effects on the mechanical properties of thermal protection materials. In this paper, compression tests including loading and unloading stages were conducted for ceramic fiber reinforced silica aerogel composites at room temperature and elevated temperatures(300℃, 600℃ and 900℃). Influences of thermal exposure to high temperature and high temperature service environment on the compression property and deformation recovery were both investigated. Scanning electron microscopy(SEM), Fourier transform infrared spectroscopy(FT-IR) and X-ray diffraction(XRD) were applied to help understand the mechanisms of mechanical property variations. The experimental results show that the compression modulus and strength both increase with the increasing thermal exposure temperature and testing temperature,but the deformation recovery capability decreases. The micro structure changes caused by thermal sintering are considered as the main reason for the property variations.Viscous flow and matter transport due to high temperature resulted in the fusion of aerogel particles. This made the particle skeleton thicker and stronger, which led to higher stiffness and strength of the composites. However, matrix cracks induced by the formation and fracture of larger pores made unrecoverable deformation more serious. In the tests at elevated temperatures,the aggregation of aerogel particles in a fused state got more severe because of the addition of mechanical load. As a result, the degradation of deformation recovery capability became more significant.
基金supported by China Geologi-cal Survey Project(Grant No.1212011086039)
文摘LA-ICP-MS zircon U-Pb isotopic dating and rock geochemical analysis were done of the Xarru granite in the middle section of the Yarlung Zangbo junction zone. Zircon 2-6pb/Z38u weighted mean ages of 474.9±2.3 and 478.3±1.7 Ma have been obtained for two gneiss granite samples respectively, which represent the formation age of the granite. This is the first discovery of the Early Ordovician magmatism in the Yarlung Zangbo junction zone. The rocks are high-K calcic-alkalic granite, contain tour- maline but not hornblende, with aluminum saturation index （ASI） of A/CNK〉I.1 （1.10-1.20）, and are enriched in Rb, Th and U and relatively depleted in Ba, Nb, Sr, Zr, Ti and Eu. They are strongly peraluminous S-type granite, resulting from partial melting of argillaceous components in the crust in a syn-collisional setting. According to previous studies as well as the analy- sis in this paper, the formation of the Xarru granite is probably related to the Andean-type orogeny in the process of subduction of the Proto-Tethys Ocean towards the Gondwanaland, and it is a product of partial melting of the thickened upper crust as a result of collision between blocks or micro-blocks in the northern margin of the Gondwana supercontinent in the process of oceanic subduction. The Xarru granite is identified as the Early Ordovician granite, indicating that the wall rocks had probably formed in the Cambrian or Precambrian.
