In order to investigate the micro-process and inner mechanism of rock failure under impact loading, the laboratory tests were carried out on an improved split Hopkinson pressure bar (SHPB) system with synchronized m...In order to investigate the micro-process and inner mechanism of rock failure under impact loading, the laboratory tests were carried out on an improved split Hopkinson pressure bar (SHPB) system with synchronized measurement devices including a high-speed camera and a dynamic strain meter. The experimental results show that the specimens were in the state of good stress equilibrium during the post failure stage even when visible cracks were forming in the specimens. Rock specimens broke into strips but still could bear the external stress and keep force balance. Meanwhile, numerical tests with particle flow code (PFC) revealed that the failure process of rocks can be described by the evolution of micro-fractures. Shear cracks emerged firstly and stopped developing when the external stress was not high enough. Tensile cracks, however, emerged when the rock specimen reached its peak strength and played an important role in controlling the ultimate failure during the post failure stage.展开更多
Residual coal pillars play an important role in mining the adjacent coal seam safely,managing the gobs and maintaining the stability of abandoned coal mines.The height to diameter ratio(H/D)affects the stability of re...Residual coal pillars play an important role in mining the adjacent coal seam safely,managing the gobs and maintaining the stability of abandoned coal mines.The height to diameter ratio(H/D)affects the stability of residual coal pillars.In this study,uniaxial compressive tests of coal specimens with five H/D(2.0,1.5,1.0,0.8 and 0.6)were performed,and the stress,strain and acoustic emission(AE)were monitored.Results show that the uniaxial compressive strength(UCS)and peak strain increase with H/D decreasing.An empirical equation is proposed to calculate the UCS based on the H/D.The AE activities during coal failure process can be separated into four periods.The span of quiet period and rapid decline period shorten with H/D decreasing.The smaller the H/D is,the more complicated the failure characteristics of coal will be.The failure form of coal with H/D of 2.0,1.5,and 1.0 is primarily shear failure,while splitting failure along the axial direction is the mainly mode when H/D is 0.8 or 0.6.The initiation,expansion,aggregation and connection of micro-cracks can be reflected by the real-time spatial evolution of AE event points.展开更多
Through rock mechanics test, similar simulation experiment, borehole photographic observation of rock fissure, numerical simulation calculation of plastic zone distribution and deformation monitoring of rock mass duri...Through rock mechanics test, similar simulation experiment, borehole photographic observation of rock fissure, numerical simulation calculation of plastic zone distribution and deformation monitoring of rock mass during undersea mining, the fractal evolution mechanisms of rock fracture in undersea metallic deposits of Sanshandao Gold Mine were studied by fractal theory. The experimental researches on granite mechanics test in undersea deposit indicate that with the increase of load, the granite deformation energy and the fractal dimension of acoustic emission(FDAE) increase gradually. However, after reaching the peak stress of specimen, the fractal dimensions of acoustic emission(FDAEs) decrease and the granite specimen fails. Therefore, the fractal dimension evolution of rock failure can be divided into four stages, which are fissure inoculation stage, fissure growth stage, fissure expansion stage and fracture instability stage, respectively. By calculating and analyzing the damage photographs of rock specimens in Sanshandao Gold Mine, the fractal dimension of rock fissure is 1.4514, which is close to the average value of FDAE during granite destruction, i.e., 1.4693. Similar simulation experiments of undersea mining show that with the excavation proceeding, the FDAE in rock stratum increases gradually, and when the thickness of the isolation roof is less than 40 m, the FDAE begins to decrease, and meanwhile the sign of water inrush emerges. The numerical simulation researches on the plastic zone distribution of undersea mining in Sanshandao Gold Mine indicate that the fractal dimension of plastic zone(FDPZ) where the failure characteristics occur is 1.4598, close to the result of similar simulation experiment of 1.4364, which shows the sign of water inrush. Meanwhile, the thickness of the isolation roof for undersea mining should be more than 40 m, which is consistent with the results of similar simulation experiment. In Sanshandao Gold Mine, the rock fissures in undersea mining were observed by borehole photography and the rock mass deformation was monitored by multi-point displacement meters, and at the same time the fractal dimensions of strata borehole fissure distribution and energy release ratio(ERR) of rock mass were calculated by fractal principle, which are 1.2328 and 1.2685, respectively. The results demonstrate that rock deformation and fissure propagation are both in the second stage of fissure growth, and have not reached the fourth stage of fracture instability. Therefore, the conclusion can be obtained that the undersea mining in Sanshandao Gold Mine is safe at present.展开更多
From observing cores of 18 wells,identifying 175 ordinary thin sections and 61 thin casting sections,energy spectrum analyses of 37 samples,homogenization temperature measurement of fluid inclusions of 11 samples,we d...From observing cores of 18 wells,identifying 175 ordinary thin sections and 61 thin casting sections,energy spectrum analyses of 37 samples,homogenization temperature measurement of fluid inclusions of 11 samples,we determine the types of diagenesis and pores of the Fuyu oil reservoir in the north Qijia region.We classified the pores and measured their plane porosity using CIA 2000,the software of rock image analysis,calculated the effect of different kinds of diagenesis on porosity,studied the controlling actions of diagenesis to pore evolution quantitatively,combined with burial history,thermal history and their diagenetic environments.Our results show that mechanical compaction and carbonate cementation are the major destructive diagenesed,developed during early diagenesis stages.The reduction in porosity by mechanical compaction and carbonate cementation are about 25% and 8%,while the destructive intensity of siliceous cementation and clay mineral cementation is relatively much smaller,i.e.,the reduction of porosity is about 2% and 0.2% Dissolution is constructive diagenesis,the increment of porosity is about 6%.There are four diagenesis evolution stages,during which the porosity reduced from 30%~38% to 2%~20%.Mechanical compaction and early cementation are the main diageneses in the early diagenesis stages,when porosity was reduced to 2%~10%.Dissolution is the main diagenesis of an A I substage of the middle diagenesis stage,when porosity increased 1%~8%.The dissolution of the A Ⅱ substage of the middle diagenesis stage affected by late cementation,raised porosity 1%~5%.The porosity varied slightly during the middle stage B.展开更多
It is becoming an important controlling factor of gas exploration and exploitation in the east part of Sulige gas field in the Ordos Basin where the reservoir of main gas formations is tight sandstones. Employing expe...It is becoming an important controlling factor of gas exploration and exploitation in the east part of Sulige gas field in the Ordos Basin where the reservoir of main gas formations is tight sandstones. Employing experimental methods of slice identification, casting slice, scan electron microscope, and X-ray diffrac- tions, we studied the characteristics of petrology and diagenesis on reservoirs in Shanl section of Shanxi formation and He8 section of Shihezi formation of the Permian system in the East II part of Sulige gas field. The results include: (1) the main sandstones in these areas are dominated by lithic sandstone and litbic silicarenite with low grade of maturity; (2) the diagenesis of sandstone in these areas mainly include compaction, cementation, corrosion and alteration. Conclusions are as follows: (1) the diagenetic stage reached period B of the middle diagenetic stage; (2) the early diagenetic compaction is one of the main factors to decreasing porosity; (3) the secondary pores formed by corrosion in acidity medium con- ditions in period A of the middle diagenetic stage can distinctly ameliorate the poor reservoir capability of sandstone and, (4) cementation in period B of the middle diagenetic stage is the most important factor leading; to poor physical property of sandstone reservoirs.展开更多
In order to study the evolution laws during the development process of the coal face overburden rock mining-induced fissure,we studied the process of evolution of overburden rock mining-induced fissures and dynamicall...In order to study the evolution laws during the development process of the coal face overburden rock mining-induced fissure,we studied the process of evolution of overburden rock mining-induced fissures and dynamically quantitatively described its fractal laws,based on the high-precision microseismic monitoring method and the nonlinear Fractal Geometry Theory.The results show that:the overburden rock mining-induced fissure fractal dimension experiences two periodic change processes with the coal face advance,namely a Small→ Big→ Small process,which tends to be stable;the functional relationship between the extraction step distance and the overburden rock mining-induced fissure fractal dimension is a cubic curve.The results suggest that the fractal dimension reflects the evolution characteristics of the overburden rock mining-induced fissure,which can be used as an evaluation index of the stability of the overburden rock strata,and it provides theoretical guidance for stability analysis of the overburden rock strata,goaf roof control and the support movements in the mining face.展开更多
Void swelling is an important phenomenon observed in both nuclear fuels and cladding materials in operating nuclear reactors. In this work we develop a phase-field model to simulate void evolution and void volume chan...Void swelling is an important phenomenon observed in both nuclear fuels and cladding materials in operating nuclear reactors. In this work we develop a phase-field model to simulate void evolution and void volume change in irradiated materials. Important material processes, including the generation of defects such as vacancies and self-interstitials, their diffusion and annihilation, and void nucleation and evolution, have been taken into account in this model. The thermodynamic and kinetic properties, such as chemical free energy, interfacial energy, vacancy mobility, and annihilation rate of vacancies and interstitials, are expressed as a function of temperature and/or defect concentrations in a general manner. The model allows for parametric studies of critical void nucleus size, void growth kinetics, and void volume fraction evolutions. Our simulations demonstrated that void swelling displays a quasi-bell shape distribution with temperature often observed in experiments.展开更多
The Upper Ordovician Lianglitag Formation carbonate rocks are important oil and gas reservoirs in the Tarim Basin, Northwest China, with obviously distinct reservoir properties among different oilfields. As a case are...The Upper Ordovician Lianglitag Formation carbonate rocks are important oil and gas reservoirs in the Tarim Basin, Northwest China, with obviously distinct reservoir properties among different oilfields. As a case area of the above carbonate reser- voirs correlation, Tahe and Tazhong oilfields are chosen for the study through an integrated analysis of biostratigraphic isoch- ronous framework, cores, thin sections, logs, and strontium isotopes. The research shows that the two areas were respectively attributed to different carbonate platforms during the Lianglitag Formation depositional phase. For the Lianglitag Formation, five fourth-order sequences may be divided in Tazhong, whereas only four fourth-order sequences are preserved in Tahe that correspond to the lower ones observed in Tazhong. The Lianglitag Formation carbonate platform in Tahe was characterized by ramp and/or weak rimmed types, with low depositional rates (37 ktm/a), higher whole-rock clastic contents, and higher 878r/86Sr isotope ratios of carbonate matrix, showing relatively deep-water environment and evident terrigenous input for car- bonate deposition. However, a strongly rimmed carbonate platform was developed in Tazhong, with high depositional rates of 250 p.m/a and less whole-rock clastic contents, indicating a high-energy depositional environment. Because of the sedimentary environment differences mentioned above, less high-energy facies but relatively intense syndepositional (early diagenetic) sea-water cementation of carbonates were developed in Tahe, and ubiquitous high-energy reef and shoal facies, with a frequent exposure to subaerial, and weak syndepositional sea-water cementation of carbonates in Tazhong. Therefore, fewer primary pores occurred in the Lianglitag Formation carbonate rocks of Tahe, whereas more primary pores were preserved in the same lithostratigraphic unit of the Tazhong (No. 1 fault zone). Available high-energy reef-shoal facies and early diagenesis, with more primary pores preserved, provided a key material basis for the Lianglitag Formation carbonate reservoirs that largely oc- curred in Tazhong.展开更多
The adsorption of organic matter(OM)onto clay minerals has long been considered as a significant way of OM preservation in source rock.Here we analyzed the relationship between OM and the specific surface area(SSA)of ...The adsorption of organic matter(OM)onto clay minerals has long been considered as a significant way of OM preservation in source rock.Here we analyzed the relationship between OM and the specific surface area(SSA)of <2μm clay size fraction isolated from 13 source rock cores collected from Dongying depression.Rock-Eval pyrolysis and N2 adsorption experiment were employed to probe the characteristics of OM and SSA(denoted SBET)in samples before and after OM extraction using trichloromethane.The results indicate that various kinds of OM occurrence coexist in clay size fraction and their contributions to hydrocarbon are different in each period of OM evolution.The occurrence and amount of OM affect the S BET of clay size fraction,and a nonlinear negative correlation between total organic carbon(TOC)and S BET can be recognized.The soluble OM(chloroform extract "A"),mainly stored in the pore space of clay size fraction,shows a negative correlation in amount with S BET.Our data also indicate that free hydrocarbon(S1)was stored mainly in the pore space and/or the surface of clay size fraction,whereas pyrolysis hydrocarbon(S2)was mingled mainly with clay minerals.Therefore,to understand various OM occurrences and their relationship with SBET in the clay size fraction is significant in the study of generation,accumulation,and migration of hydrocarbon in muddy source rock.展开更多
The dynamic evolution of a multi-level atom in the three-dimensional photonic crystal under an applied magnetic field is investigated.By combining the Zeeman effect with the photonic band gap effect,the dynamic quantu...The dynamic evolution of a multi-level atom in the three-dimensional photonic crystal under an applied magnetic field is investigated.By combining the Zeeman effect with the photonic band gap effect,the dynamic quantum superposition states and steady quantum coherent trapping states of the atom can be flexibly controlled.This paves the way for coherent manipulation of quantum states in the solid-state system,which has important applications in quantum information processing.展开更多
基金Project(2015CB060200)supported by the National Basic Research and Development Program of ChinaProjects(51322403,51274254)supported by the National Natural Science Foundation of China
文摘In order to investigate the micro-process and inner mechanism of rock failure under impact loading, the laboratory tests were carried out on an improved split Hopkinson pressure bar (SHPB) system with synchronized measurement devices including a high-speed camera and a dynamic strain meter. The experimental results show that the specimens were in the state of good stress equilibrium during the post failure stage even when visible cracks were forming in the specimens. Rock specimens broke into strips but still could bear the external stress and keep force balance. Meanwhile, numerical tests with particle flow code (PFC) revealed that the failure process of rocks can be described by the evolution of micro-fractures. Shear cracks emerged firstly and stopped developing when the external stress was not high enough. Tensile cracks, however, emerged when the rock specimen reached its peak strength and played an important role in controlling the ultimate failure during the post failure stage.
基金Projects(51974192,52004172)supported by the National Natural Science Foundation of ChinaProject(51925402)supported by the Distinguished Youth Funds of National Natural Science Foundation of ChinaProject(U1710258)supported by the Joint Funds of National Natural Science Foundation of China and Shanxi Province,China。
文摘Residual coal pillars play an important role in mining the adjacent coal seam safely,managing the gobs and maintaining the stability of abandoned coal mines.The height to diameter ratio(H/D)affects the stability of residual coal pillars.In this study,uniaxial compressive tests of coal specimens with five H/D(2.0,1.5,1.0,0.8 and 0.6)were performed,and the stress,strain and acoustic emission(AE)were monitored.Results show that the uniaxial compressive strength(UCS)and peak strain increase with H/D decreasing.An empirical equation is proposed to calculate the UCS based on the H/D.The AE activities during coal failure process can be separated into four periods.The span of quiet period and rapid decline period shorten with H/D decreasing.The smaller the H/D is,the more complicated the failure characteristics of coal will be.The failure form of coal with H/D of 2.0,1.5,and 1.0 is primarily shear failure,while splitting failure along the axial direction is the mainly mode when H/D is 0.8 or 0.6.The initiation,expansion,aggregation and connection of micro-cracks can be reflected by the real-time spatial evolution of AE event points.
基金Project(2019sdzy05)supported by the Major Scientific and Technological Innovation Project of Shandong Province,ChinaProjects(51674288,51974359)supported by the National Natural Science Foundation of China。
文摘Through rock mechanics test, similar simulation experiment, borehole photographic observation of rock fissure, numerical simulation calculation of plastic zone distribution and deformation monitoring of rock mass during undersea mining, the fractal evolution mechanisms of rock fracture in undersea metallic deposits of Sanshandao Gold Mine were studied by fractal theory. The experimental researches on granite mechanics test in undersea deposit indicate that with the increase of load, the granite deformation energy and the fractal dimension of acoustic emission(FDAE) increase gradually. However, after reaching the peak stress of specimen, the fractal dimensions of acoustic emission(FDAEs) decrease and the granite specimen fails. Therefore, the fractal dimension evolution of rock failure can be divided into four stages, which are fissure inoculation stage, fissure growth stage, fissure expansion stage and fracture instability stage, respectively. By calculating and analyzing the damage photographs of rock specimens in Sanshandao Gold Mine, the fractal dimension of rock fissure is 1.4514, which is close to the average value of FDAE during granite destruction, i.e., 1.4693. Similar simulation experiments of undersea mining show that with the excavation proceeding, the FDAE in rock stratum increases gradually, and when the thickness of the isolation roof is less than 40 m, the FDAE begins to decrease, and meanwhile the sign of water inrush emerges. The numerical simulation researches on the plastic zone distribution of undersea mining in Sanshandao Gold Mine indicate that the fractal dimension of plastic zone(FDPZ) where the failure characteristics occur is 1.4598, close to the result of similar simulation experiment of 1.4364, which shows the sign of water inrush. Meanwhile, the thickness of the isolation roof for undersea mining should be more than 40 m, which is consistent with the results of similar simulation experiment. In Sanshandao Gold Mine, the rock fissures in undersea mining were observed by borehole photography and the rock mass deformation was monitored by multi-point displacement meters, and at the same time the fractal dimensions of strata borehole fissure distribution and energy release ratio(ERR) of rock mass were calculated by fractal principle, which are 1.2328 and 1.2685, respectively. The results demonstrate that rock deformation and fissure propagation are both in the second stage of fissure growth, and have not reached the fourth stage of fracture instability. Therefore, the conclusion can be obtained that the undersea mining in Sanshandao Gold Mine is safe at present.
基金the National Basic Research Program of China (No.2009 CB219306)the Important National Science & Technology Specific Projects (No.2009GYXQ14)
文摘From observing cores of 18 wells,identifying 175 ordinary thin sections and 61 thin casting sections,energy spectrum analyses of 37 samples,homogenization temperature measurement of fluid inclusions of 11 samples,we determine the types of diagenesis and pores of the Fuyu oil reservoir in the north Qijia region.We classified the pores and measured their plane porosity using CIA 2000,the software of rock image analysis,calculated the effect of different kinds of diagenesis on porosity,studied the controlling actions of diagenesis to pore evolution quantitatively,combined with burial history,thermal history and their diagenetic environments.Our results show that mechanical compaction and carbonate cementation are the major destructive diagenesed,developed during early diagenesis stages.The reduction in porosity by mechanical compaction and carbonate cementation are about 25% and 8%,while the destructive intensity of siliceous cementation and clay mineral cementation is relatively much smaller,i.e.,the reduction of porosity is about 2% and 0.2% Dissolution is constructive diagenesis,the increment of porosity is about 6%.There are four diagenesis evolution stages,during which the porosity reduced from 30%~38% to 2%~20%.Mechanical compaction and early cementation are the main diageneses in the early diagenesis stages,when porosity was reduced to 2%~10%.Dissolution is the main diagenesis of an A I substage of the middle diagenesis stage,when porosity increased 1%~8%.The dissolution of the A Ⅱ substage of the middle diagenesis stage affected by late cementation,raised porosity 1%~5%.The porosity varied slightly during the middle stage B.
基金supported by the Science Development Project of Shandong Province (No.2009GG20001021-07)the Open Fund of Shandong Provincial Key Laboratory of Depositional Mineralization & Sedimentary Minerals (No. DMSM200803)the SDUST Research Fund (No.2010KYTD103)
文摘It is becoming an important controlling factor of gas exploration and exploitation in the east part of Sulige gas field in the Ordos Basin where the reservoir of main gas formations is tight sandstones. Employing experimental methods of slice identification, casting slice, scan electron microscope, and X-ray diffrac- tions, we studied the characteristics of petrology and diagenesis on reservoirs in Shanl section of Shanxi formation and He8 section of Shihezi formation of the Permian system in the East II part of Sulige gas field. The results include: (1) the main sandstones in these areas are dominated by lithic sandstone and litbic silicarenite with low grade of maturity; (2) the diagenesis of sandstone in these areas mainly include compaction, cementation, corrosion and alteration. Conclusions are as follows: (1) the diagenetic stage reached period B of the middle diagenetic stage; (2) the early diagenetic compaction is one of the main factors to decreasing porosity; (3) the secondary pores formed by corrosion in acidity medium con- ditions in period A of the middle diagenetic stage can distinctly ameliorate the poor reservoir capability of sandstone and, (4) cementation in period B of the middle diagenetic stage is the most important factor leading; to poor physical property of sandstone reservoirs.
基金Financial support for this work,provided by the National Natural Science Foundation of China(No.51304154)the Natural Science Foundation Anhui Province(No.1408085MKL92)
文摘In order to study the evolution laws during the development process of the coal face overburden rock mining-induced fissure,we studied the process of evolution of overburden rock mining-induced fissures and dynamically quantitatively described its fractal laws,based on the high-precision microseismic monitoring method and the nonlinear Fractal Geometry Theory.The results show that:the overburden rock mining-induced fissure fractal dimension experiences two periodic change processes with the coal face advance,namely a Small→ Big→ Small process,which tends to be stable;the functional relationship between the extraction step distance and the overburden rock mining-induced fissure fractal dimension is a cubic curve.The results suggest that the fractal dimension reflects the evolution characteristics of the overburden rock mining-induced fissure,which can be used as an evaluation index of the stability of the overburden rock strata,and it provides theoretical guidance for stability analysis of the overburden rock strata,goaf roof control and the support movements in the mining face.
基金supported by the US Department of Energy’s Nuclear Energy Advance Modeling and Simulation (NEAMS) Program in Pacific Northwest National Laboratory, which is operated by Battelle Memorial Institute for the US Department of Energy (Grant No. DE-AC05- 76RL01830)Two of the authors (LI YuLan and GAO Fei) were partially supported by the Materials Sciences and Engineering Division, Office of Basic Energy Sciences, US Department of Energy
文摘Void swelling is an important phenomenon observed in both nuclear fuels and cladding materials in operating nuclear reactors. In this work we develop a phase-field model to simulate void evolution and void volume change in irradiated materials. Important material processes, including the generation of defects such as vacancies and self-interstitials, their diffusion and annihilation, and void nucleation and evolution, have been taken into account in this model. The thermodynamic and kinetic properties, such as chemical free energy, interfacial energy, vacancy mobility, and annihilation rate of vacancies and interstitials, are expressed as a function of temperature and/or defect concentrations in a general manner. The model allows for parametric studies of critical void nucleus size, void growth kinetics, and void volume fraction evolutions. Our simulations demonstrated that void swelling displays a quasi-bell shape distribution with temperature often observed in experiments.
基金supported by National Major Project of China (Grant No. 2011ZX05008-003)National Natural Science Foundation of China (Grant No. 41172096)
文摘The Upper Ordovician Lianglitag Formation carbonate rocks are important oil and gas reservoirs in the Tarim Basin, Northwest China, with obviously distinct reservoir properties among different oilfields. As a case area of the above carbonate reser- voirs correlation, Tahe and Tazhong oilfields are chosen for the study through an integrated analysis of biostratigraphic isoch- ronous framework, cores, thin sections, logs, and strontium isotopes. The research shows that the two areas were respectively attributed to different carbonate platforms during the Lianglitag Formation depositional phase. For the Lianglitag Formation, five fourth-order sequences may be divided in Tazhong, whereas only four fourth-order sequences are preserved in Tahe that correspond to the lower ones observed in Tazhong. The Lianglitag Formation carbonate platform in Tahe was characterized by ramp and/or weak rimmed types, with low depositional rates (37 ktm/a), higher whole-rock clastic contents, and higher 878r/86Sr isotope ratios of carbonate matrix, showing relatively deep-water environment and evident terrigenous input for car- bonate deposition. However, a strongly rimmed carbonate platform was developed in Tazhong, with high depositional rates of 250 p.m/a and less whole-rock clastic contents, indicating a high-energy depositional environment. Because of the sedimentary environment differences mentioned above, less high-energy facies but relatively intense syndepositional (early diagenetic) sea-water cementation of carbonates were developed in Tahe, and ubiquitous high-energy reef and shoal facies, with a frequent exposure to subaerial, and weak syndepositional sea-water cementation of carbonates in Tazhong. Therefore, fewer primary pores occurred in the Lianglitag Formation carbonate rocks of Tahe, whereas more primary pores were preserved in the same lithostratigraphic unit of the Tazhong (No. 1 fault zone). Available high-energy reef-shoal facies and early diagenesis, with more primary pores preserved, provided a key material basis for the Lianglitag Formation carbonate reservoirs that largely oc- curred in Tazhong.
基金supported by National Natural Science Foundation of China (Grant No. 41072089)National Oil and Gas Special Fund (Grant No.2011ZX05006-001)Program of the State Key Laboratory of Oil-gas of Petroleum University (Beijing) (Grant No. P08026)
文摘The adsorption of organic matter(OM)onto clay minerals has long been considered as a significant way of OM preservation in source rock.Here we analyzed the relationship between OM and the specific surface area(SSA)of <2μm clay size fraction isolated from 13 source rock cores collected from Dongying depression.Rock-Eval pyrolysis and N2 adsorption experiment were employed to probe the characteristics of OM and SSA(denoted SBET)in samples before and after OM extraction using trichloromethane.The results indicate that various kinds of OM occurrence coexist in clay size fraction and their contributions to hydrocarbon are different in each period of OM evolution.The occurrence and amount of OM affect the S BET of clay size fraction,and a nonlinear negative correlation between total organic carbon(TOC)and S BET can be recognized.The soluble OM(chloroform extract "A"),mainly stored in the pore space of clay size fraction,shows a negative correlation in amount with S BET.Our data also indicate that free hydrocarbon(S1)was stored mainly in the pore space and/or the surface of clay size fraction,whereas pyrolysis hydrocarbon(S2)was mingled mainly with clay minerals.Therefore,to understand various OM occurrences and their relationship with SBET in the clay size fraction is significant in the study of generation,accumulation,and migration of hydrocarbon in muddy source rock.
基金supported by the National Key Basic Research Special Foundation of China (Grant Nos. 2006CB921706 and 2010CB923200)the National Natural Science Foundation of China (Grant Nos. 10574160 and10725420)
文摘The dynamic evolution of a multi-level atom in the three-dimensional photonic crystal under an applied magnetic field is investigated.By combining the Zeeman effect with the photonic band gap effect,the dynamic quantum superposition states and steady quantum coherent trapping states of the atom can be flexibly controlled.This paves the way for coherent manipulation of quantum states in the solid-state system,which has important applications in quantum information processing.