The porosity of titanium foams obtained from the space holder technique was theoretically analyzed in the cases of volume shrinking, retaining and expanding during sintering. The relationship between porosity and spac...The porosity of titanium foams obtained from the space holder technique was theoretically analyzed in the cases of volume shrinking, retaining and expanding during sintering. The relationship between porosity and spacer content was compared under different conditions. The kind of volume change of macropores during sintering was discussed. The results indicate that the relationship between porosity and spacer content depends on the decreased volume of macropores and the volume of micropores in cell-walls in the first case, while the porosity will be greater than the spacer content for the other two cases. It proves that the volume change of macropores during sintering decreases based on theory and practice.展开更多
It is a great advantage to design advanced materials with outstanding porosity and controllable band gab. In this study, （Fe, Ti）-containing mesoporous silica （x Fe/Ti-HMS） nanoparticles were prepared by a photo-a...It is a great advantage to design advanced materials with outstanding porosity and controllable band gab. In this study, （Fe, Ti）-containing mesoporous silica （x Fe/Ti-HMS） nanoparticles were prepared by a photo-assisted deposition PAD technique, where x is a nominal composition ofFe （l to 4 wt%））. The prepared samples were characterized by DR-UV, XRD, and TEM techniques. The results showed the insertion of Fe into intra-framework of Ti-HMS resulted in a gradual narrowing of the band gap of Ti-HMS samples with increment of Fe wt%. TEM observations reveal that Fe nanoparticles are evenly distributed within Ti-HSM matrix at different Fe wt%. Such results indicate the possibility to control the band gap of a single-site photocatalyst （Ti-HMS） by coupling it with the conventional nano-sized Fe catalysts.展开更多
基金Project(51174243)supported by the National Natural Science Foundation of ChinaProject(106112015CDJZR135502)supported by the Fundamental Research Funds for the Central Universities,China
文摘The porosity of titanium foams obtained from the space holder technique was theoretically analyzed in the cases of volume shrinking, retaining and expanding during sintering. The relationship between porosity and spacer content was compared under different conditions. The kind of volume change of macropores during sintering was discussed. The results indicate that the relationship between porosity and spacer content depends on the decreased volume of macropores and the volume of micropores in cell-walls in the first case, while the porosity will be greater than the spacer content for the other two cases. It proves that the volume change of macropores during sintering decreases based on theory and practice.
文摘It is a great advantage to design advanced materials with outstanding porosity and controllable band gab. In this study, （Fe, Ti）-containing mesoporous silica （x Fe/Ti-HMS） nanoparticles were prepared by a photo-assisted deposition PAD technique, where x is a nominal composition ofFe （l to 4 wt%））. The prepared samples were characterized by DR-UV, XRD, and TEM techniques. The results showed the insertion of Fe into intra-framework of Ti-HMS resulted in a gradual narrowing of the band gap of Ti-HMS samples with increment of Fe wt%. TEM observations reveal that Fe nanoparticles are evenly distributed within Ti-HSM matrix at different Fe wt%. Such results indicate the possibility to control the band gap of a single-site photocatalyst （Ti-HMS） by coupling it with the conventional nano-sized Fe catalysts.
