In western China, most petroliferous basins are superposed due to their multi-periodic tectonic evolution, and the mechanisms of petroleum migration and accumulation are so complex that much more sophis- ticated metho...In western China, most petroliferous basins are superposed due to their multi-periodic tectonic evolution, and the mechanisms of petroleum migration and accumulation are so complex that much more sophis- ticated methodologies are necessary for depiction of these mechanisms and identification of petroleum occurrences. For this purpose, in this article, a new methodology was formulated which includes: (I) ver- tical identification of petroleum migration and accumulation fluid dynamic systems in the superposed basins; (2) analysis of the effect of large scale regional faults and fault combinations on the fluids exchange between the vertically identified different systems; (3) analysis of petroleum migration and accumulation in each vertically identified system, and establishment of appropriate geological model of petroleum migration and accumulation for each vertically identified system. Using this methodology, the satisfactory results obtained in the Lunnan Uplift of Tarim Basin and Ludong Uplift of Jungar Basin case studies are: (1) existence of different vertical fluid dynamic systems in western China's superposed basins which are very necessary for understanding the mechanism of petroleum migration and accumu- lation; (2) in deep system, long-distance lateral petroleum migration and accumulation mainly take place along the long time exposed unconformity with weathered, fractured or karst reservoir rocks; (3) regio- nal faults are the main conducts for fluids migration from deep system up to middle and/or upper sys- tems. As to middle and/or upper systems, regional faults play a role of "petroleum source". Small faults within middle and/or upper systems conduct petroleum to carrier beds with less impeding force; (4) petroleum migrated from deep system vertically up to middle and/or upper systems will migrate lat- erally in carrier beds of these systems and accumulate to form nools near or far from faults.展开更多
Computational fluid dynamics is an efficient numerical approach for spray atomization study, but it is challenging to accurately capture the gas-liquid interface. In this work, an accurate conservative level set metho...Computational fluid dynamics is an efficient numerical approach for spray atomization study, but it is challenging to accurately capture the gas-liquid interface. In this work, an accurate conservative level set method is intro- duced to accurately track the gas-liquid interfaces in liquid atomization. To validate the capability of this method, binary drop collision and drop impacting on liquid film are investigated. The results are in good agreement with experiment observations. In addition, primary atomization (swirling sheet atomization) is studied using this method. To the swirling sheet atomization, it is found that Rayleigh-Taylor instability in the azimuthal direction causes the primary breakup of liquid sheet and complex vortex structures are clustered around the rim of the liq- uid sheet. The effects of central gas velocity and liquid-gas density ratio on atomization are also investigated. This work lays a solid foundation for further studvin~ the mechanism of s^rav atomization.展开更多
We investigated the effect of supply air rate and temperature on formaldehyde emission characteristics in an environment chamber.A three-dimensional computational fluid dynamics(CFD) chamber model for simulating forma...We investigated the effect of supply air rate and temperature on formaldehyde emission characteristics in an environment chamber.A three-dimensional computational fluid dynamics(CFD) chamber model for simulating formaldehyde emission in twelve different cases was developed for obtaining formaldehyde concentration by the area-weighted average method.Laboratory experiments were conducted in an environment chamber to validate the simulation results of twelve different cases and the formaldehyde concentration was measured by continuous sampling.The results show that there was good agreement between the model prediction and the experimental values within 4.3 difference for each case.The CFD simulation results varied in the range from 0.21 mg/m3 to 0.94 mg/m3,and the measuring results in the range from 0.17 mg/m3 to 0.87 mg/m3.The variation trend of formaldehyde concentration with supply air rate and temperature variation for CFD simulation and experiment measuring was consistent.With the existence of steady formaldehyde emission sources,formaldehyde concentration generally increased with the increase of temperature,and it decreased with the increase of air supply rate.We also provided some reasonable suggestions to reduce formaldehyde concentration and to improve indoor air quality for newly decorated rooms.展开更多
Ethoxylation and propoxylation reactions are performed in the industry to produce mainly non-ionic surfactants and ethylene oxide(EO)–propylene oxide(PO) copolymers.Both the reactions occur in gas–liquid reactors by...Ethoxylation and propoxylation reactions are performed in the industry to produce mainly non-ionic surfactants and ethylene oxide(EO)–propylene oxide(PO) copolymers.Both the reactions occur in gas–liquid reactors by feeding gaseous EO,PO or both into the reactor containing a solution of an alkaline catalyst(KOH or Na OH).Non-ionic surfactants are produced by using liquid starters like fatty alcohols,fatty acids or alkyl-phenols,while when the scope is to prepare EO–PO copolymers the starter can be a mono-or multi-functional alcohol of low molecular weight.Both reactions are strongly exothermic,and EO and PO,in some conditions,can give place to runaway and also to explosive side reactions.Therefore,the choice of a suitable reactor is a key factor for operating in safe conditions.A correct reactor design requires:(i) the knowledge of the kinetic laws governing the rates of the occurring reactions;(ii) the role of mass and heat transfer in affecting the reaction rate;(iii) the solubility of EO and PO in the reacting mixture with the non-ideality of the reacting solutions considered;(iv) the density of the reacting mixture.All these aspects have been studied by our research group for different starters of industrial interest,and the data collected by using semibatch well stirred laboratory reactors have been employed for the simulation of industrial reactors,in particular Gas–Liquid Spray Tower Loop Reactors.展开更多
We have investigated the properties of cellulose diacetate in solution by using laser light scattering. The cellulose diacetate molecules can form micelles and micellar clusters in acetone besides the individual chain...We have investigated the properties of cellulose diacetate in solution by using laser light scattering. The cellulose diacetate molecules can form micelles and micellar clusters in acetone besides the individual chains. As the concentration increases, the average hydrodynamic radius (Rh) linearly increases, whereas the ratio of gyration radius to hydrodynamic radins 〈Rg〉/〈Rh〉 linearly decreases. It indicates that the micelles associate and form micellar clusters due to the intermolecular interactions.展开更多
One of the collective phenomena that has allowed a theoretical debate on the social movements in the current context is the neo-Zapatista of Chiapas. From a discussion on some significant events and possible interpret...One of the collective phenomena that has allowed a theoretical debate on the social movements in the current context is the neo-Zapatista of Chiapas. From a discussion on some significant events and possible interpretations about their identities, strategies, demands and speeches, the aim is to place the movement in a structural dynamics that will acquire different views. In apparent confirmation of an "identitarian community of resistance", the neo-Zapatismo seems to move toward a new scenario, in which "your chance" is configured from its structural flexibility and fluidity. In this way, the neo-Zapatista movement seems to confirm that the theoretical antinomies on the social movements relating to the American school, its emphasis on "strategy" of collective actions, and the ones referring to the European version, emphasizing the dimension of "identity", cannot be considered completely contradictory. The neo-Zapatismo has shown that a particular strategy developed a specific corresponding identitarian construction, and vice versa.展开更多
In the design of Hydraulic Manifold Blocks (HMB), dynamic performance of inner pipeline networks usually should be evaluated. To meet the design requirements, dynamic characteristic simulation is often needed. Based o...In the design of Hydraulic Manifold Blocks (HMB), dynamic performance of inner pipeline networks usually should be evaluated. To meet the design requirements, dynamic characteristic simulation is often needed. Based on comprehensive study on the existing simulation methods, a new method combined of Power Bond Graph(PBG) and Computational Fluid Dynamic (CFD) is proposed. In this method, flow field of typical channels inside HMB is analyzed with CFD to obtain the local resistance coefficients. Then, with these coefficients, a new sectional lumped-parameter model including kinetic friction factor is developed using PBG. A typical HMB design example is given and the comparison between the simulation and the experimental results demonstrates the feasibility and effectiveness of the proposed method.展开更多
We propose a monomer adsorption model, in which only the monomers are allowed to diffuse and adsorb onto other clusters. By means of the generalized rate equation we investigate the kinetic behavior of the system with...We propose a monomer adsorption model, in which only the monomers are allowed to diffuse and adsorb onto other clusters. By means of the generalized rate equation we investigate the kinetic behavior of the system with a special rate kernel. For the system without monomer input, the concentration aj(t) of the Aj clusters (j 〉 1) asymptotically retains a nonzero quantity, while for the system with monomer input, it decays with time and vanishes finally. We also investigate the kinetics of an interesting model with fixed-rate monomer adsorption. For the ease without monomer source, the evolution of the system will halt at a finite time; while the system evolves infinitely in time in the case with monomer source. Finally, we also suggest a connection between the fixed-rate monomer adsorption systems and growing networks.展开更多
Producing kaon mesons in heavy-ion collisions at beam energies below their threshold energy is an important way to investigate the properties of dense nuclear matter. In this study, based on the newly updated version ...Producing kaon mesons in heavy-ion collisions at beam energies below their threshold energy is an important way to investigate the properties of dense nuclear matter. In this study, based on the newly updated version of the ultrarelativistic quantum molecular dynamics model, we introduce the kaon-nucleon(KN) potential, including both the scalar and vector(also dubbed Lorentz-like)aspects. We revisit the influence of the KN potential on the collective flow of K+mesons produced in Au+Au collisions at Elab= 1.5 Ge V/nucleon and find that the contribution of the newly included Lorentz-like force is very important, particulary for describing the directed flow of K+. Finally, the corresponding Kao S data of both directed and elliptic flows can be simultaneously reproduced well.展开更多
A two-dinmnsional red blood cell (RBC) membrane model based on elastic and Euler- Bernoulli beam theories is introduced in the frame of immersed boundary-lattice Boltz- mann method (IB-LBM). The effect of the flex...A two-dinmnsional red blood cell (RBC) membrane model based on elastic and Euler- Bernoulli beam theories is introduced in the frame of immersed boundary-lattice Boltz- mann method (IB-LBM). The effect of the flexible membrane is handled by the immersed boundary method in which the stress exerted by the RBC on the ambient fluid is spread onto the collocated grid points near the boundary. The fluid dynamics is obtained by solving the discrete lattice Boltzmann equation. A "ghost shape", to which the RBC returns when restoring, is introduced by prescribing a bending force along the bound- ary. Numerical examples involving tumbling, tank-treading and RBC aggregation in shear flow and deformation and restoration in poiseuille flow are presented to verify the method and illustrate its efficiency. As an application of the present method, a ten-RBC colony being compressed through a stenotic microvessel is studied focusing the cell-cell interaction strength. Quantitative comparisons of the pressure and velocity on speci- fled microvessel interfaces are made between each aggregation case. It reveals that the stronger aggregation may lead to more resistance against blood flow and result in higher pressure difference at the stenosis.展开更多
This contribution provides a summary of proposed theoretical and computational studies on excited state dynamics in molecular aggregates, as an important part of the National Natural Science Foundation (NNSF) Major Pr...This contribution provides a summary of proposed theoretical and computational studies on excited state dynamics in molecular aggregates, as an important part of the National Natural Science Foundation (NNSF) Major Project entitled "Theoretical study of the low-lying electronic excited state for molecular aggregates". This study will focus on developments of novel methods to simulate excited state dynamics of molecular aggregates, with the aim of understanding several important chemical physics processes, and providing a solid foundation for predicting the opto-electronic properties of organic functional materials and devices. The contents of this study include: (1) The quantum chemical methods for electronic excited state and electronic couplings targeted for dynamics in molecular aggregates; (2) Methods to construct effective Hamiltonian models, and to solve their dynamics using system-bath approaches; (3) Non-adiabatic mixed quantum-classic methods targeted for molecular aggregates; (4) Theoretical studies of charge and energy transfer, and related spectroscopic phenomena in molecular aggregates.展开更多
Electron-boson interaction is fundamental to a thorough understanding of various exotic properties emerging in many-body physics. In photoemission spectroscopy, photoelectron emission due to photon absorption would tr...Electron-boson interaction is fundamental to a thorough understanding of various exotic properties emerging in many-body physics. In photoemission spectroscopy, photoelectron emission due to photon absorption would trigger diverse collective excitations in solids, including the emergence of phonons,magnons, electron-hole pairs, and plasmons, which naturally provides a reliable pathway to study electron-boson couplings. While fingerprints of electron–phonon/-magnon interactions in this state-ofthe-art technique have been well investigated, much less is known about electron-plasmon coupling,and direct observation of the band renormalization solely due to electron-plasmon interactions is extremely challenging. Here by utilizing integrated oxide molecular-beam epitaxy and angle-resolved photoemission spectroscopy, we discover the long sought-after pure electron-plasmon couplinginduced low-lying plasmonic-polaron replica bands in epitaxial semimetallic SrIrO_(3) films, in which the characteristic low carrier concentration and narrow bandwidth combine to provide a unique platform where the electron-plasmon interaction can be investigated kinematically in photoemission spectroscopy. This finding enriches the forms of electron band normalization on collective modes in solids and demonstrates that, to obtain a complete understanding of the quasiparticle dynamics in 5 d electron systems, the electron-plasmon interaction should be considered on equal footing with the acknowledged electron–electron interaction and spin–orbit coupling.展开更多
基金provided by the National Basic Research Program of China (No. 2006CB20235)
文摘In western China, most petroliferous basins are superposed due to their multi-periodic tectonic evolution, and the mechanisms of petroleum migration and accumulation are so complex that much more sophis- ticated methodologies are necessary for depiction of these mechanisms and identification of petroleum occurrences. For this purpose, in this article, a new methodology was formulated which includes: (I) ver- tical identification of petroleum migration and accumulation fluid dynamic systems in the superposed basins; (2) analysis of the effect of large scale regional faults and fault combinations on the fluids exchange between the vertically identified different systems; (3) analysis of petroleum migration and accumulation in each vertically identified system, and establishment of appropriate geological model of petroleum migration and accumulation for each vertically identified system. Using this methodology, the satisfactory results obtained in the Lunnan Uplift of Tarim Basin and Ludong Uplift of Jungar Basin case studies are: (1) existence of different vertical fluid dynamic systems in western China's superposed basins which are very necessary for understanding the mechanism of petroleum migration and accumu- lation; (2) in deep system, long-distance lateral petroleum migration and accumulation mainly take place along the long time exposed unconformity with weathered, fractured or karst reservoir rocks; (3) regio- nal faults are the main conducts for fluids migration from deep system up to middle and/or upper sys- tems. As to middle and/or upper systems, regional faults play a role of "petroleum source". Small faults within middle and/or upper systems conduct petroleum to carrier beds with less impeding force; (4) petroleum migrated from deep system vertically up to middle and/or upper systems will migrate lat- erally in carrier beds of these systems and accumulate to form nools near or far from faults.
基金the National Natural Science Foundation of China(51176170,51276163)the Zhejiang Provincial Natural Science Foundation for Distinguished Young Scholars(LR12E06001)supported by the Fundamental Research Funds for the Central Universities
文摘Computational fluid dynamics is an efficient numerical approach for spray atomization study, but it is challenging to accurately capture the gas-liquid interface. In this work, an accurate conservative level set method is intro- duced to accurately track the gas-liquid interfaces in liquid atomization. To validate the capability of this method, binary drop collision and drop impacting on liquid film are investigated. The results are in good agreement with experiment observations. In addition, primary atomization (swirling sheet atomization) is studied using this method. To the swirling sheet atomization, it is found that Rayleigh-Taylor instability in the azimuthal direction causes the primary breakup of liquid sheet and complex vortex structures are clustered around the rim of the liq- uid sheet. The effects of central gas velocity and liquid-gas density ratio on atomization are also investigated. This work lays a solid foundation for further studvin~ the mechanism of s^rav atomization.
基金Funded by National Science Foundation(No.50778415 and No.50878177)
文摘We investigated the effect of supply air rate and temperature on formaldehyde emission characteristics in an environment chamber.A three-dimensional computational fluid dynamics(CFD) chamber model for simulating formaldehyde emission in twelve different cases was developed for obtaining formaldehyde concentration by the area-weighted average method.Laboratory experiments were conducted in an environment chamber to validate the simulation results of twelve different cases and the formaldehyde concentration was measured by continuous sampling.The results show that there was good agreement between the model prediction and the experimental values within 4.3 difference for each case.The CFD simulation results varied in the range from 0.21 mg/m3 to 0.94 mg/m3,and the measuring results in the range from 0.17 mg/m3 to 0.87 mg/m3.The variation trend of formaldehyde concentration with supply air rate and temperature variation for CFD simulation and experiment measuring was consistent.With the existence of steady formaldehyde emission sources,formaldehyde concentration generally increased with the increase of temperature,and it decreased with the increase of air supply rate.We also provided some reasonable suggestions to reduce formaldehyde concentration and to improve indoor air quality for newly decorated rooms.
文摘Ethoxylation and propoxylation reactions are performed in the industry to produce mainly non-ionic surfactants and ethylene oxide(EO)–propylene oxide(PO) copolymers.Both the reactions occur in gas–liquid reactors by feeding gaseous EO,PO or both into the reactor containing a solution of an alkaline catalyst(KOH or Na OH).Non-ionic surfactants are produced by using liquid starters like fatty alcohols,fatty acids or alkyl-phenols,while when the scope is to prepare EO–PO copolymers the starter can be a mono-or multi-functional alcohol of low molecular weight.Both reactions are strongly exothermic,and EO and PO,in some conditions,can give place to runaway and also to explosive side reactions.Therefore,the choice of a suitable reactor is a key factor for operating in safe conditions.A correct reactor design requires:(i) the knowledge of the kinetic laws governing the rates of the occurring reactions;(ii) the role of mass and heat transfer in affecting the reaction rate;(iii) the solubility of EO and PO in the reacting mixture with the non-ideality of the reacting solutions considered;(iv) the density of the reacting mixture.All these aspects have been studied by our research group for different starters of industrial interest,and the data collected by using semibatch well stirred laboratory reactors have been employed for the simulation of industrial reactors,in particular Gas–Liquid Spray Tower Loop Reactors.
基金ACKNOWLEDGMENTS This work was supported by China Tobacco Guangdong Industrial Co., Ltd., National Natural Science Foundation of China (No21234003 and No.51303059), and the Fundamental Research Funds for Central Universities.
文摘We have investigated the properties of cellulose diacetate in solution by using laser light scattering. The cellulose diacetate molecules can form micelles and micellar clusters in acetone besides the individual chains. As the concentration increases, the average hydrodynamic radius (Rh) linearly increases, whereas the ratio of gyration radius to hydrodynamic radins 〈Rg〉/〈Rh〉 linearly decreases. It indicates that the micelles associate and form micellar clusters due to the intermolecular interactions.
文摘One of the collective phenomena that has allowed a theoretical debate on the social movements in the current context is the neo-Zapatista of Chiapas. From a discussion on some significant events and possible interpretations about their identities, strategies, demands and speeches, the aim is to place the movement in a structural dynamics that will acquire different views. In apparent confirmation of an "identitarian community of resistance", the neo-Zapatismo seems to move toward a new scenario, in which "your chance" is configured from its structural flexibility and fluidity. In this way, the neo-Zapatista movement seems to confirm that the theoretical antinomies on the social movements relating to the American school, its emphasis on "strategy" of collective actions, and the ones referring to the European version, emphasizing the dimension of "identity", cannot be considered completely contradictory. The neo-Zapatismo has shown that a particular strategy developed a specific corresponding identitarian construction, and vice versa.
基金National Natural Science Foundation of China (No.50375023)
文摘In the design of Hydraulic Manifold Blocks (HMB), dynamic performance of inner pipeline networks usually should be evaluated. To meet the design requirements, dynamic characteristic simulation is often needed. Based on comprehensive study on the existing simulation methods, a new method combined of Power Bond Graph(PBG) and Computational Fluid Dynamic (CFD) is proposed. In this method, flow field of typical channels inside HMB is analyzed with CFD to obtain the local resistance coefficients. Then, with these coefficients, a new sectional lumped-parameter model including kinetic friction factor is developed using PBG. A typical HMB design example is given and the comparison between the simulation and the experimental results demonstrates the feasibility and effectiveness of the proposed method.
基金Supported by the National Natural Science Foundation of China under Grant Nos. 10775104 and 10305009
文摘We propose a monomer adsorption model, in which only the monomers are allowed to diffuse and adsorb onto other clusters. By means of the generalized rate equation we investigate the kinetic behavior of the system with a special rate kernel. For the system without monomer input, the concentration aj(t) of the Aj clusters (j 〉 1) asymptotically retains a nonzero quantity, while for the system with monomer input, it decays with time and vanishes finally. We also investigate the kinetics of an interesting model with fixed-rate monomer adsorption. For the ease without monomer source, the evolution of the system will halt at a finite time; while the system evolves infinitely in time in the case with monomer source. Finally, we also suggest a connection between the fixed-rate monomer adsorption systems and growing networks.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11375062, 11505057, and 11747312)the Zhejiang Provincial Natural Science Foundation of China (Grant No. LY18A050002)the project is sponsored by SRF for ROCS, SEM
文摘Producing kaon mesons in heavy-ion collisions at beam energies below their threshold energy is an important way to investigate the properties of dense nuclear matter. In this study, based on the newly updated version of the ultrarelativistic quantum molecular dynamics model, we introduce the kaon-nucleon(KN) potential, including both the scalar and vector(also dubbed Lorentz-like)aspects. We revisit the influence of the KN potential on the collective flow of K+mesons produced in Au+Au collisions at Elab= 1.5 Ge V/nucleon and find that the contribution of the newly included Lorentz-like force is very important, particulary for describing the directed flow of K+. Finally, the corresponding Kao S data of both directed and elliptic flows can be simultaneously reproduced well.
文摘A two-dinmnsional red blood cell (RBC) membrane model based on elastic and Euler- Bernoulli beam theories is introduced in the frame of immersed boundary-lattice Boltz- mann method (IB-LBM). The effect of the flexible membrane is handled by the immersed boundary method in which the stress exerted by the RBC on the ambient fluid is spread onto the collocated grid points near the boundary. The fluid dynamics is obtained by solving the discrete lattice Boltzmann equation. A "ghost shape", to which the RBC returns when restoring, is introduced by prescribing a bending force along the bound- ary. Numerical examples involving tumbling, tank-treading and RBC aggregation in shear flow and deformation and restoration in poiseuille flow are presented to verify the method and illustrate its efficiency. As an application of the present method, a ten-RBC colony being compressed through a stenotic microvessel is studied focusing the cell-cell interaction strength. Quantitative comparisons of the pressure and velocity on speci- fled microvessel interfaces are made between each aggregation case. It reveals that the stronger aggregation may lead to more resistance against blood flow and result in higher pressure difference at the stenosis.
基金the National Natural Science Foundation of China (21290194)
文摘This contribution provides a summary of proposed theoretical and computational studies on excited state dynamics in molecular aggregates, as an important part of the National Natural Science Foundation (NNSF) Major Project entitled "Theoretical study of the low-lying electronic excited state for molecular aggregates". This study will focus on developments of novel methods to simulate excited state dynamics of molecular aggregates, with the aim of understanding several important chemical physics processes, and providing a solid foundation for predicting the opto-electronic properties of organic functional materials and devices. The contents of this study include: (1) The quantum chemical methods for electronic excited state and electronic couplings targeted for dynamics in molecular aggregates; (2) Methods to construct effective Hamiltonian models, and to solve their dynamics using system-bath approaches; (3) Non-adiabatic mixed quantum-classic methods targeted for molecular aggregates; (4) Theoretical studies of charge and energy transfer, and related spectroscopic phenomena in molecular aggregates.
基金This work was supported by the National Key R&D Program of the MOST of China(2016YFA0300204)the National Natural Science Foundation of China(11574337,11874199,and 11874263)+2 种基金supported by the National Basic Research Program of China(2015CB654901)Part of this research used Beamline 03U of the Shanghai Synchron Radiation Facility,which is supported by ME2 project(11227902)from the National Natural Science Foundation of Chinasupported by‘‘Award for Outstanding Member in Youth Innovation Promotion Association CAS”。
文摘Electron-boson interaction is fundamental to a thorough understanding of various exotic properties emerging in many-body physics. In photoemission spectroscopy, photoelectron emission due to photon absorption would trigger diverse collective excitations in solids, including the emergence of phonons,magnons, electron-hole pairs, and plasmons, which naturally provides a reliable pathway to study electron-boson couplings. While fingerprints of electron–phonon/-magnon interactions in this state-ofthe-art technique have been well investigated, much less is known about electron-plasmon coupling,and direct observation of the band renormalization solely due to electron-plasmon interactions is extremely challenging. Here by utilizing integrated oxide molecular-beam epitaxy and angle-resolved photoemission spectroscopy, we discover the long sought-after pure electron-plasmon couplinginduced low-lying plasmonic-polaron replica bands in epitaxial semimetallic SrIrO_(3) films, in which the characteristic low carrier concentration and narrow bandwidth combine to provide a unique platform where the electron-plasmon interaction can be investigated kinematically in photoemission spectroscopy. This finding enriches the forms of electron band normalization on collective modes in solids and demonstrates that, to obtain a complete understanding of the quasiparticle dynamics in 5 d electron systems, the electron-plasmon interaction should be considered on equal footing with the acknowledged electron–electron interaction and spin–orbit coupling.