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超临界二氧化碳中功能化聚乙二醇稳定的钯纳米粒子催化醇的选择氧化反应
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作者 汪向锐 冯博 +6 位作者 杨汉民 侯震山 赵秀阁 胡玉 乔云香 李欢 潘珍燕 《催化学报》 SCIE CAS CSCD 北大核心 2009年第12期1215-1221,共7页
以超临界二氧化碳(scCO2)/聚乙二醇(PEG)两相为反应介质,双齿氮配体功能化聚乙二醇稳定的Pd纳米颗粒作为催化剂,进行了醇的需氧氧化反应.系统研究了催化剂制备条件和反应条件对苯甲醇需氧氧化反应的影响.结果表明,以氢气为还原剂制备的P... 以超临界二氧化碳(scCO2)/聚乙二醇(PEG)两相为反应介质,双齿氮配体功能化聚乙二醇稳定的Pd纳米颗粒作为催化剂,进行了醇的需氧氧化反应.系统研究了催化剂制备条件和反应条件对苯甲醇需氧氧化反应的影响.结果表明,以氢气为还原剂制备的Pd纳米粒子的催化活性最高.反应结束后,可以利用scCO2直接进行原位萃取得到产物,实现了催化剂与产物的有效分离和催化剂的循环使用.反应中没有检测到钯的流失.催化剂经过5次循环利用后转化率仍可达98%. 展开更多
关键词 超临界二化碳 聚乙二醇 反应 钯纳米粒子
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喹诺酮类药物的光促反应特征 被引量:7
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作者 胡昌勤 杨亚莉 《国外医药(抗生素分册)》 CAS 2001年第6期259-261,共3页
喹诺酮类药物在临床中应用广泛 ,其中以喹啉羧酸类产品最多 ,但喹啉羧酸类药物大多对光不稳定 ,易发生光解反应 ,使抗菌活性下降。临床中有喹诺酮类药物发生光毒性反应和光敏反应的报道。近年来对喹诺酮类药物的光促反应特性的研究结果... 喹诺酮类药物在临床中应用广泛 ,其中以喹啉羧酸类产品最多 ,但喹啉羧酸类药物大多对光不稳定 ,易发生光解反应 ,使抗菌活性下降。临床中有喹诺酮类药物发生光毒性反应和光敏反应的报道。近年来对喹诺酮类药物的光促反应特性的研究结果提示 :光促反应为放热反应 ,在溶液状态和有氧的条件下更易发生 ;其反应速度与溶液的 p H及药物本身的结构有关 ,光降解反应有敏感位点 ,组氨酸对光促反应有抑制作用 ;且光促反应不仅可产生降解物 。 展开更多
关键词 喹诺酮类药物 光促反应 光分解反应 溶液 放热反应 需氧反应
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Study on Piggery Anaerobic Fermentation Slurry Treated by Anoxic/Oxic Process 被引量:3
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作者 李卓坪 牛明芬 +1 位作者 刘知远 侯迎 《Agricultural Science & Technology》 CAS 2009年第6期155-158,共4页
[Objective] The aim of this study was to provide a fast, stable and efficient piggery wastewater processing technology. [Method] The start-up process was studied through the experiment of piggery anaerobic fermentatio... [Objective] The aim of this study was to provide a fast, stable and efficient piggery wastewater processing technology. [Method] The start-up process was studied through the experiment of piggery anaerobic fermentation slurry treated by Anoxic/Oxic (A/O) reactor. The process was divided into two stages: at the first stage, dominant micro flora were cultivated in Anoxic and Oxic reaction tanks respectively; at the second stage. Anoxic and Oxic reaction tanks were initiated jointly to gradually enhance water load and continued to cultivate and domesticate microorganisms, and finally the start-up process was completed. [ Result] The results showed that return mixture ratio and return sludge ratio was 2 and 1 respectively when the temperature reached 32 ±2 ℃. However. when aeration rate of Oxic reaction amounted to 0.5 m^3/h, the re- moval rate of COD and NH4^+ -H were 89.87% and 89.31% respectively through practical operation within 50 days, which indicated that the start- up process through A/O reactor was successful. Conclusion This study can provide a scientific basis and reference for innocuous technique of piggery anaerobic fermentation slurry treatment. 展开更多
关键词 Piggery wastewater Anoxic/Oxic (A/O) reactor COD NH4^+ -H
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Enhanced Biological Phosphorus Removal in Anaerobic/Aerobic Sequencing Batch Reactor Supplied with Glucose as Carbon Source 被引量:1
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作者 刘亚男 于水利 +2 位作者 荆国林 赵冰洁 郭思远 《Journal of Donghua University(English Edition)》 EI CAS 2005年第3期95-99,共5页
Phosphorus removal performance in an aerobic/aerobic sequencing batch reactor (SBR) supplied with glucose as carbon source was investigated. It was found that there was no phosphate release concomitant with the storin... Phosphorus removal performance in an aerobic/aerobic sequencing batch reactor (SBR) supplied with glucose as carbon source was investigated. It was found that there was no phosphate release concomitant with the storing of poly-β-hydroxyalkanoate (PHA) during the anaerobic phase. Whereas, glycogen was soon built up followed by rapid consumption, at the same time, glucose was depleted rapidly. Based on the analysis of different fractions of phosphorus in activated sludge, the relative ratio of organically bound phosphorus in sludge changed at the end of anaerobic and aerobic phases. The ratios were 45.3% and 51.8% respectively. This showed that the polyphosphate broke down during the anaerobic phase to supply part of energy for PHA synthesis. The reason why there was no phosphate release might be the biosorption effect of extracellular exopolymers (EPS). It was also proved by the analysis of EPS with scanning electron microscopy (SEM) combined with energy dispersive spectrometry (EDS). The phosphorus weight percentage of EPS at the end of anaerobic phase was 9.22%. 展开更多
关键词 Biological phosphorus removal GLUCOSE extracellular exopolymers BIOSORPTION
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The Role of Formed Microorganism in Sludge on Processing of Wastewater Treatment
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作者 Ahmed Aidan Al-Hussieny Saba Hussein Obeid Noor Nihad Baqer Sajida Frhan Hussain Ayad Gheni Mohammed 《Journal of Life Sciences》 2015年第3期103-110,共8页
Several microorganisms such as bacteria, fungi, Protozoa, Rotifera, cystic amoeba and algae diagnosed in activated sludge aerobic (Rustumiya treatment plant) and anaerobic reactor. Results have shown a reduction in ... Several microorganisms such as bacteria, fungi, Protozoa, Rotifera, cystic amoeba and algae diagnosed in activated sludge aerobic (Rustumiya treatment plant) and anaerobic reactor. Results have shown a reduction in the turbidity rates when using activated sludge at Rustumiya plant of 76.3 to 2.653 NTU in pre-treatment and final tank respectively, also COD (chemical oxygen demand) amount reduced from 427.263 to 82 mg/L respectively, In addition, concentrations of phosphates and nitrates decreased from 12.083 to 8.426 mg/L and 3.59 to 2.43 mg/L respectively, by removing 30.2% and 32.3% respectively of the final tank. The ratio of ammonia removing was 89.6% for ammonia, reducing process from 1358 to 140 mg/L. Furthermore, sulfates concentration decreased from 30.883 to 23.337 mg/L. However, the system in the anaerobic reactor depends on non-aerated activated sludge. Results show turbidity reduced from 12.5 to 2 NTU in pre-treatment and final tank respectively, also the COD mount reduced from 191 to 130 mg/L, the percentage removal of 31.9%. In addition phosphates, nitrates and sulfates concentrations were decreased by using activated sludge from 17.15 to 8.15, 1.2 to 0.1 and 28 to 9.2 mg/L respectively. The ammonia concentration has reduced from 1.2 to 0. i mg/L where at a removal percentage of 90.9%. 展开更多
关键词 MICROORGANISM SLUDGE WASTEWATER removing chemical oxygen demand PROTOZOA bacteria algae.
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Experimental study on zero excess sludge production process with ozonation unit in MBR process 被引量:1
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作者 王正 王琳 +2 位作者 王宝贞 刘硕 蒋轶锋 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2010年第1期42-46,共5页
In order to investigate the influence factors of zero excess activated sludge (EAS) process by ozonation, a 100 L membrane bioreactor coupled with a sludge ozonation unit (MBR-SO) was performed for 80 d without EAS wa... In order to investigate the influence factors of zero excess activated sludge (EAS) process by ozonation, a 100 L membrane bioreactor coupled with a sludge ozonation unit (MBR-SO) was performed for 80 d without EAS wasting. Some mathematical models were developed to elucidate the relationship between process parameters and the operating effects. It is considered that the sludge lysing ratio (ξ), produced COD per unit mass lysed MLSS (η), observed sludge yield coefficient (Yobs) and intrinsic yield coefficient for COD produced by lysed sludge (Y2) significantly affect the flowrate to ozonation unit (q). When q is 0.0067 times of influent flowrate (Q) and ξ is about 0.72 for each batch ozonation, a relatively stable MLSS concentration of 8168 mg/L and zero Yobs are achieved in the MBR-SO system. The calculation of sludge disintegration number indicates that the high ξ can apparently decrease the sludge amount needed for ozonation. At the same ozone dose, the low input ozone concentration and high flowrate can enhance the sludge lysing effects and a low energy consumption of 0.041 Yuan/m3 wastewater is obtained. 展开更多
关键词 excess activated sludge ozonation MBR modeling economic analysis
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