The interaction of proteins with salt ions plays an important role in life activities.We used butyramide as a model molecule to investigate the interaction of protein backbones with cations.The experiment was performe...The interaction of proteins with salt ions plays an important role in life activities.We used butyramide as a model molecule to investigate the interaction of protein backbones with cations.The experiment was performed in an aqueous solution of metal chloride using UV Raman spectroscopy.It was found that well-hydrated metal cations(Ca^(2+),Mg^(2+))tend to bind to C=O in the amide bond,resulting in redistribution of the amide I band peaks.Specifically,the peak intensity ratio of 1655 cm^(-1)to 1610 cm^(-1)increases significantly with increasing concentrations.However,this phenomenon is not obviously observed in NaCl solution.Furthermore,we studied the effect of salt ions on the water structures.The addition of Ca^(2+)and Mg^(2+)is beneficial to the enhancement of the water signal at the 3400 cm^(-1)position,while the Na^(+)at the same concentration is not obvious.The results have shown that the interaction between cations and amides satisfies the following order:Ca^(2+)>Mg^(2+)>Na^(+),which conforms to the Hofmeister series.展开更多
Split Hopkinson Pressure Bar(SHPB) test was simulated to investigate the distribution of the first principal stress and damage zone of specimen subjected to dynamic compressive load. Numerical models of plate-type spe...Split Hopkinson Pressure Bar(SHPB) test was simulated to investigate the distribution of the first principal stress and damage zone of specimen subjected to dynamic compressive load. Numerical models of plate-type specimen containing cracks with inclined angles of 0°,45° and 90° were also established to investigate the crack propagation and damage evolution under dynamic loading. The results show that the simulation results are in accordance with the failure patterns of specimens in experimental test. The interactions between stress wave and crack with different inclined angles are different; damage usually appears around the crack tips firstly; and then more damage zones develop away from the foregoing damage zone after a period of energy accumulation; eventually,the damage zones run through the specimen in the direction of applied loading and split the specimen into pieces.展开更多
We show that there is a quantum Sl_q(2) group symmetry in Hofstadter problem on square lattice.The cyclic representation of the quantum group is discussed and its application for computing the degeneracy density of th...We show that there is a quantum Sl_q(2) group symmetry in Hofstadter problem on square lattice.The cyclic representation of the quantum group is discussed and its application for computing the degeneracy density of the model is shown.展开更多
基金supported by the National Natural Science Foundation of China(No.62005108,No.62205134)the Natural Science Foundation of the Higher Education Institutions of Jiangsu Province(No.21KJB140008)the Graduate Research and Practice Innovation Program of Jiangsu Normal University(No.2021XKT1201,No.2021XKT1204).
文摘The interaction of proteins with salt ions plays an important role in life activities.We used butyramide as a model molecule to investigate the interaction of protein backbones with cations.The experiment was performed in an aqueous solution of metal chloride using UV Raman spectroscopy.It was found that well-hydrated metal cations(Ca^(2+),Mg^(2+))tend to bind to C=O in the amide bond,resulting in redistribution of the amide I band peaks.Specifically,the peak intensity ratio of 1655 cm^(-1)to 1610 cm^(-1)increases significantly with increasing concentrations.However,this phenomenon is not obviously observed in NaCl solution.Furthermore,we studied the effect of salt ions on the water structures.The addition of Ca^(2+)and Mg^(2+)is beneficial to the enhancement of the water signal at the 3400 cm^(-1)position,while the Na^(+)at the same concentration is not obvious.The results have shown that the interaction between cations and amides satisfies the following order:Ca^(2+)>Mg^(2+)>Na^(+),which conforms to the Hofmeister series.
基金Projects(50534030, 50674107, 50490274) supported by the National Natural Science Foundation of ChinaProject(06JJ3028) supported by the Provincial Natural Science Foundation of Hunan, China
文摘Split Hopkinson Pressure Bar(SHPB) test was simulated to investigate the distribution of the first principal stress and damage zone of specimen subjected to dynamic compressive load. Numerical models of plate-type specimen containing cracks with inclined angles of 0°,45° and 90° were also established to investigate the crack propagation and damage evolution under dynamic loading. The results show that the simulation results are in accordance with the failure patterns of specimens in experimental test. The interactions between stress wave and crack with different inclined angles are different; damage usually appears around the crack tips firstly; and then more damage zones develop away from the foregoing damage zone after a period of energy accumulation; eventually,the damage zones run through the specimen in the direction of applied loading and split the specimen into pieces.
文摘We show that there is a quantum Sl_q(2) group symmetry in Hofstadter problem on square lattice.The cyclic representation of the quantum group is discussed and its application for computing the degeneracy density of the model is shown.
