Nanofiltration separation has become a popular technique for removing largeorganic molecules and inorganic substances from water. It is achieved by a combination of threemechanisms: electrostatic repulsion, sieving an...Nanofiltration separation has become a popular technique for removing largeorganic molecules and inorganic substances from water. It is achieved by a combination of threemechanisms: electrostatic repulsion, sieving and diffusion. In the present work, a model based onirreversible thermodynamics is extended and used to estimate rejection of inorganic salts andorganic substances. Binary systems are modeled, where the feed contains an ion that is much lesspermeable to the membrane as compared with the other ion. The two model parameters are estimated byfitting the model to the experimental data. Variation of these parameters with the composition ofthe feed is described by an empirical correlation. This work attempts to describe transport throughthe nanofiltration membranes by a simple model.展开更多
Stimulus-responsive energy storage devices,which can respond to external stimuli,such as heat,pH,moisture,pressure,or electric field,have recently attracted intensive attention,aiming at the ever-increasing demand for...Stimulus-responsive energy storage devices,which can respond to external stimuli,such as heat,pH,moisture,pressure,or electric field,have recently attracted intensive attention,aiming at the ever-increasing demand for safe batteries and smart electronics.The most typical stimulus-responsive materials are polymers that can change their conformation by forming and destroying secondary forces,including hydrogen bonds and electrostatic interactions in response to external stimuli,accompanied by changes in the intrinsic properties such as conductivity and hydrophobicity.Although the applications of stimulus-responsive functions in rechargeable batteries are still in the early stage because of the complexity and compatibility of battery architectures,many new concepts of regulating the polymer structures upon applications of stimuli have already been developed.In this review,we discuss the recent progress of stimulus-responsive polymers on energy storage devices featuring thermal protection and intelligent scenarios,with a focus on the detailed structural transformations of polymers under a given stimulus and the corresponding changes in battery performance.Finally,we present perspectives on the current limitations and future research directions of stimulus-responsive polymers for energy storage devices.展开更多
文摘Nanofiltration separation has become a popular technique for removing largeorganic molecules and inorganic substances from water. It is achieved by a combination of threemechanisms: electrostatic repulsion, sieving and diffusion. In the present work, a model based onirreversible thermodynamics is extended and used to estimate rejection of inorganic salts andorganic substances. Binary systems are modeled, where the feed contains an ion that is much lesspermeable to the membrane as compared with the other ion. The two model parameters are estimated byfitting the model to the experimental data. Variation of these parameters with the composition ofthe feed is described by an empirical correlation. This work attempts to describe transport throughthe nanofiltration membranes by a simple model.
基金financially supported by the National Key R&D Program of China(2017YFE0127600)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA22010600)+4 种基金the National Natural Science Foundation of China(21975271)the Key-Area Research and Development Program of Guangdong Province(2020B090919005)Shandong Natural Science Foundation(ZR2020ZD07 and ZR2021QB106)the financial support from the Youth Innovation Promotion Association of CAS(2019214)Shandong Energy Institute(SEI 1202127)。
文摘Stimulus-responsive energy storage devices,which can respond to external stimuli,such as heat,pH,moisture,pressure,or electric field,have recently attracted intensive attention,aiming at the ever-increasing demand for safe batteries and smart electronics.The most typical stimulus-responsive materials are polymers that can change their conformation by forming and destroying secondary forces,including hydrogen bonds and electrostatic interactions in response to external stimuli,accompanied by changes in the intrinsic properties such as conductivity and hydrophobicity.Although the applications of stimulus-responsive functions in rechargeable batteries are still in the early stage because of the complexity and compatibility of battery architectures,many new concepts of regulating the polymer structures upon applications of stimuli have already been developed.In this review,we discuss the recent progress of stimulus-responsive polymers on energy storage devices featuring thermal protection and intelligent scenarios,with a focus on the detailed structural transformations of polymers under a given stimulus and the corresponding changes in battery performance.Finally,we present perspectives on the current limitations and future research directions of stimulus-responsive polymers for energy storage devices.
