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几种非晶态Ni-B合金催化剂的物化和催化性能比较 被引量:3
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作者 胡长员 李凤仪 +1 位作者 张荣斌 华丽 《南昌大学学报(理科版)》 CAS 北大核心 2006年第6期564-568,573,共6页
用化学还原法制备非晶态N i-B合金和浸渍-化学还原法制备非晶态N i-B/A l2O3、N i-B/S iO2、N i-B/CNTs合金,研究了催化剂的乙炔选择加氢性能,并运用TEM、ICP、XPS、H2-TPD、CO化学吸附法对非晶态合金催化剂进行表征。结果表明,A l2O3、... 用化学还原法制备非晶态N i-B合金和浸渍-化学还原法制备非晶态N i-B/A l2O3、N i-B/S iO2、N i-B/CNTs合金,研究了催化剂的乙炔选择加氢性能,并运用TEM、ICP、XPS、H2-TPD、CO化学吸附法对非晶态合金催化剂进行表征。结果表明,A l2O3、S iO2、CNTs载体不同程度促进了N i-B合金的分散,提高了催化剂的活性镍表面积,其中以CNTs的效果最为突出。平均径粒为10 nm左右的N i-B粒子在CNTs表面均匀分散,使活性镍的表面积达30.6 m2/g,提高了氢的吸附量。此外,CNTs向非晶态N i-B合金中的N i转移电子,形成富电子的N i。N i-B/CNTs催化剂具有最好的乙炔加氢活性,N i-B催化剂乙烯选择性最差。 展开更多
关键词 非品态Ni—B合金 负载 碳纳米管 乙炔选择加氢
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药品冷冻干燥过程的退火机理分析 被引量:6
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作者 周新丽 翁宇 陈光明 《化学工程》 EI CAS CSCD 北大核心 2005年第6期4-7,共4页
运用热力学和动力学理论分析了药品冷冻干燥过程中的退火操作改变冻结药品结构的机理。通过对化学势随晶粒曲率半径变化、重结晶过程中冰晶半径随时间变化、非晶态基质的粘度随温度变化几个关系式的分析,得出退火温度必须要高于冻结药... 运用热力学和动力学理论分析了药品冷冻干燥过程中的退火操作改变冻结药品结构的机理。通过对化学势随晶粒曲率半径变化、重结晶过程中冰晶半径随时间变化、非晶态基质的粘度随温度变化几个关系式的分析,得出退火温度必须要高于冻结药品的玻璃化转变温度;最佳退火持续时间与重结晶的速率紧密相关,且是退火温度的函数;退火后再冷却过程的冷却速率不影响升华干燥速率等结论。 展开更多
关键词 冷冻干燥 退火 冰晶 非品态
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CoP非晶合金催化分解磷化氢制高纯磷的研究 被引量:3
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作者 梁培玉 韩长秀 +1 位作者 林徐明 张宝贵 《南开大学学报(自然科学版)》 CAS CSCD 北大核心 2006年第4期20-23,共4页
以次磷酸钠为还原剂、柠檬酸钠为配体,用化学还原法制备CoP非晶态合金.利用Co-P非晶态合金来催化分解磷化氢制备半导体级高纯黄磷,可以使磷化氢的实际分解温度从800~1000C降低到约470℃.得到的黄磷纯度为99.99%,磷化氢的实际分... 以次磷酸钠为还原剂、柠檬酸钠为配体,用化学还原法制备CoP非晶态合金.利用Co-P非晶态合金来催化分解磷化氢制备半导体级高纯黄磷,可以使磷化氢的实际分解温度从800~1000C降低到约470℃.得到的黄磷纯度为99.99%,磷化氢的实际分解率99.80%;黄磷中砷含量降至3μg/g以下,可以作为优质黄磷使用. 展开更多
关键词 Co-P非品态合金 磷化氢 高纯磷
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DMSO中制备Eu-Fe合金膜的研究
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作者 周豪 柯琴芳 +2 位作者 黄开胜 刘冠昆 童叶翔 《稀有金属》 EI CAS CSCD 北大核心 2004年第6期987-991,共5页
研究了二甲基亚砜 (DMSO)中Eu3+ 和Fe2 + 在Pt电极上的电化学行为。Eu3+ 的还原为二步不可逆还原 ,先还原为Eu2 + ,Eu2 + 再还原为Eu ;而Fe2 + 则经过一步两电子不可逆过程还原为Fe,并利用循环伏安法测得在 0 .0 1mol·dm- 3FeCl2 ... 研究了二甲基亚砜 (DMSO)中Eu3+ 和Fe2 + 在Pt电极上的电化学行为。Eu3+ 的还原为二步不可逆还原 ,先还原为Eu2 + ,Eu2 + 再还原为Eu ;而Fe2 + 则经过一步两电子不可逆过程还原为Fe,并利用循环伏安法测得在 0 .0 1mol·dm- 3FeCl2 0 .0 2mol·dm- 3柠檬酸 0 .1 0mol·dm- 3Li ClO4 DMSO溶液中 ,Fe2 + 离子的扩散系数和传递系数分别为 4 .90× 1 0 - 6 cm2 ·s- 1 和 0 .1 2。以铜为基体 ,在Eu(NO3) 3 FeCl2 柠檬酸 LiClO4 DMSO体系中 ,- 1 .50~ - 2 .2 0V (vs.SCE)区间内恒电位电解制得含Eu量 2 3 .34 %~ 86 .0 0 % (质量分数 )的Eu Fe合金膜。X射线衍射证实所得到的Eu Fe合金膜都是非晶态的。 展开更多
关键词 Eu-Fe合金 二甲基亚砜 扩散系数 传递系数 电沉积 非品态
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纳米晶Fe-Si-B-Nb-Cu合金棒的软磁性能
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作者 玉燕 《金属功能材料》 CAS 2003年第2期42-42,共1页
关键词 铸造非品态合金棒 纳米晶 Fe-Si-B-Nb-Cu合金 软磁性能
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Visual Evaluation of the Morphologic Structure of Nonwovens Using Image Analysis and Fractal Geometry 被引量:1
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作者 杨旭红 李栋高 《Journal of Donghua University(English Edition)》 EI CAS 2004年第3期162-165,共4页
Nonwovens are fiber materials which are based on nonwoven technologies. For the complexity and randomness of nonwovens morphologic structures, it is difficult to express them effectively using classical method. Fracta... Nonwovens are fiber materials which are based on nonwoven technologies. For the complexity and randomness of nonwovens morphologic structures, it is difficult to express them effectively using classical method. Fractal geometry gives us a new idea and a powerful tool to study on irregularity of geometric objects. Therefore, we studied on the pore size, pore shape, pore size distribution and fiber orientation distribution of real nonwovens using fractal geometry combined with computer image analysis to evaluate nonwovens’ morphologic structures. 展开更多
关键词 NONWOVENS morphologic structure fractal geometry image analysis
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An Assessment of Non-timber Forest Products in the Four Ecological Zones of Swaziland as a Basis for Policy and Strategy Development
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作者 C. S. Dlamini C. J. Geldenhuys 《Journal of Agricultural Science and Technology(B)》 2011年第4期579-585,共7页
The aim of the study was to assess the flow and inventory values of non-timber foret products (NTFPs). The methods used for user surveys included literature research, community consultations, household visits and in... The aim of the study was to assess the flow and inventory values of non-timber foret products (NTFPs). The methods used for user surveys included literature research, community consultations, household visits and interviews, household profiles and economic valuation models. Resource surveys incorporated a total often sampling plots (50 m × 50 m) under each landscape area in each study area and economic valuation of standing stock. The findings of the study re-affirm that NTFPs play a crucial role on the provision of subsistence and income to people's livelihoods, especially the poor and marginalized communities. Harvesting patterns of NTFPs normally vary within and between communities and villages adjacent to natural forests and woodlands. Increased and uncontrolled harvesting of NTFPs often leads to disappearance of numerous plant species and ultimately forest degradation. The key factors determining the variability in harvested quantities and values per household are: the wealth status, variability of species per site, season and duration of harvesting, commercialization, number of accessible natural woodlands within a site, need and demand, the household profile with regard to gender and age, and farm gate price differences. The study ultimately recommended that government, private sector, NGOs, communities, individuals, all interested and affected parties work together towards matching resource use with resource availability in order to promote sustainable resource use. 展开更多
关键词 Economic value natural forest natural woodland SUSTAINABILITY economic valuation.
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The Viable but Non-culturable State in Xanthomonas citri subsp, citri is a Reversible State Induced by Low Nutrient Availability and Copper Stress Conditions
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作者 Morteza Golmohammadi Jaime Cubero +1 位作者 Maria M. Lopez Pablo Llop 《Journal of Life Sciences》 2013年第10期1019-1029,共11页
Xcc (Xanthomonas citri subsp, citri) causes citrus bacterial canker, a leaf, stem and fruit spotting disease that affects most commercial citrus species and cultivars. Copper compounds, widely used for management of... Xcc (Xanthomonas citri subsp, citri) causes citrus bacterial canker, a leaf, stem and fruit spotting disease that affects most commercial citrus species and cultivars. Copper compounds, widely used for management of this pathogen, have been reported as inducers of a VBNC (viable but non-culturable state) in plant pathogenic bacteria. VBNC may be considered as a state preceding bacterial death or as a survival mechanism under adverse conditions. Several experiments were performed to characterize the reversibility and persistence of the VBNC state in Xcc. VBNC was induced in low nutrient medium or with amendment of copper at concentrations used for field disease control. The VBNC condition was demonstrated to persist up to 150 days after copper treatment and was reversed after the addition of culture media without copper or amendment with citrus leaf extract. Xcc viability was evaluated by recovery of colonies on culture media, confirmed by membrane integrity, respiratory activity and by real-time RT-PCR targeting a sequence from the gumD gene. Besides, the colonies recovered were pathogenic on citrus leaves. These results confirm that the VBNC state in Xcc is inducible and reversible and therefore may occur in the phyllosphere when Xcc is under copper stress or starvation. 展开更多
关键词 VBNC RESUSCITATION Xanthomonas citri subsp citri.
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