This paper theoretically studies the recombination-dominated nonequilibrium reacting flow inside the stagnation point bound- ary layer （SPBL） and the heat transfer characteristics under rarefied conditions. A genera...This paper theoretically studies the recombination-dominated nonequilibrium reacting flow inside the stagnation point bound- ary layer （SPBL） and the heat transfer characteristics under rarefied conditions. A general model is intuitively proposed to de- scribe the energy transfer and conversion along the stagnation streamline towards a slightly blunted nose with non-catalytic wall surface. It is found that the atoms recombination effects inside the SPBL could be equivalent to a modification on the de- gree of dissociation in the external flow. As a result, a recombination nonequilibrium criterion Dar, that is a specific DamktSh- let number, is introduced to characterize the nonequilibrium degree of the reacting flow in the SPBL, and then, based on the general model and Dar, a bridging function indicating the nonequilibrium chemical effects on the SPBL heat transfer is estab- lished. By using the explicitly analytical bridging function, the flow and heat transfer mechanisms, including the real gas flow similarity law and the nonequilibrium flow regimes classification, are discussed. In addition, the direct simulation Monte Carlo （DSMC） method has also been employed to systematically validate the analytical results.展开更多
Interfacial transfer plays an important role in multi-phase chemical processes. However, it is difficult to describe the complex interfacial transport behavior by the traditional mass transfer model. In this paper, we...Interfacial transfer plays an important role in multi-phase chemical processes. However, it is difficult to describe the complex interfacial transport behavior by the traditional mass transfer model. In this paper, we describe an interfacial mass transfer model based on linear non-equilibrium thermodynamics for the analysis of the rate of interfacial transport. The interfacial transfer process rate J depends on the interface mass transfer coefficient K, interfacial area A and chemical potential gradient at the interface. Potassium compounds were selected as model systems. A model based on linear non-equilibrium thermo-dynamics was established in order to describe and predict the transport rate at the solid-solution interface. Together with accurate experimental kinetic data for potassium ions obtained using ion-selective electrodes, a general model which can be used to describe the dissolution rate was established and used to analyze ways of improving the process rate.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos.91116012 and 11202224)the Postdoctoral Science Foundation of China (Grant No.2011M500415)
文摘This paper theoretically studies the recombination-dominated nonequilibrium reacting flow inside the stagnation point bound- ary layer （SPBL） and the heat transfer characteristics under rarefied conditions. A general model is intuitively proposed to de- scribe the energy transfer and conversion along the stagnation streamline towards a slightly blunted nose with non-catalytic wall surface. It is found that the atoms recombination effects inside the SPBL could be equivalent to a modification on the de- gree of dissociation in the external flow. As a result, a recombination nonequilibrium criterion Dar, that is a specific DamktSh- let number, is introduced to characterize the nonequilibrium degree of the reacting flow in the SPBL, and then, based on the general model and Dar, a bridging function indicating the nonequilibrium chemical effects on the SPBL heat transfer is estab- lished. By using the explicitly analytical bridging function, the flow and heat transfer mechanisms, including the real gas flow similarity law and the nonequilibrium flow regimes classification, are discussed. In addition, the direct simulation Monte Carlo （DSMC） method has also been employed to systematically validate the analytical results.
基金supported by the Chinese National Key Technology Research and Development Program (2006AA03Z455)the National Natural Science Foundation of China (NSFC)+3 种基金the National Natural Science Foundation of China (20976080, 20736002)the Research Grants Council(RGC) of Hong Kong Joint Research Scheme (JRS) (20731160614)Program for Changjiang Scholars and Innovative Research Team in University (IRT0732)National Basic Research Program of China (2009CB226103)
文摘Interfacial transfer plays an important role in multi-phase chemical processes. However, it is difficult to describe the complex interfacial transport behavior by the traditional mass transfer model. In this paper, we describe an interfacial mass transfer model based on linear non-equilibrium thermodynamics for the analysis of the rate of interfacial transport. The interfacial transfer process rate J depends on the interface mass transfer coefficient K, interfacial area A and chemical potential gradient at the interface. Potassium compounds were selected as model systems. A model based on linear non-equilibrium thermo-dynamics was established in order to describe and predict the transport rate at the solid-solution interface. Together with accurate experimental kinetic data for potassium ions obtained using ion-selective electrodes, a general model which can be used to describe the dissolution rate was established and used to analyze ways of improving the process rate.
