Nanofluidics in hydrophilic nanopores is a common issue in many natural and industrial processes. Among all,the mass transport of nanofluidics is most concerned. Besides that, the heat transfer of a fluid flow in nano...Nanofluidics in hydrophilic nanopores is a common issue in many natural and industrial processes. Among all,the mass transport of nanofluidics is most concerned. Besides that, the heat transfer of a fluid flow in nano or micro channels is always considered with adding nanoparticles into the flow, so as to enhance the heat transfer by convection between the fluid and the surface. However, for some applications with around 1 nm channels such as nano filtration or erosion of rocks, there should be no nanoparticles included. Hence, it is necessary to figure out the heat transfer mechanism in the single phase nanofluidics. Via non-equilibrium molecular dynamics simulations, we revealed the heat transfer inside nanofluidics and the one between fluid and walls by setting simulation into extremely harsh condition. It was found that the heat was conducted by molecular motion without temperature gradient in the area of low viscous heat, while it was transferred to the walls by increasing the temperature of fluids. If the condition back to normal, it was found that the viscous heat of nanofluidics could be easily removed by the fluid-wall temperature drop of less than 1 K.展开更多
In this paper, the methodology of non-equilibrium thermodynamics is introduced for kinetics research of CO2 capture by ionic liquids, and the following three key scientific problems are proposed to apply the methodolo...In this paper, the methodology of non-equilibrium thermodynamics is introduced for kinetics research of CO2 capture by ionic liquids, and the following three key scientific problems are proposed to apply the methodology in kinetics research of CO2 capture by ionic liquids: reliable thermodynamic models, interfacial transport rate description and accurate experimental flux. The obtaining of accurate experimental flux requires reliable experimental kinetics data and the effective transport area in the CO2 capture process by ionic liquids. Research advances in the three key scientific problems are reviewed systematically and further work is analyzed. Finally, perspectives of non-equilibrium thermodynamic research of the kinetics of CO2 capture by ionic liquids are proposed.展开更多
Research on the dynamic properties of a plasma sheath coupled with pitching motion of the vehicle has great significance in solving the problem of communication interruption in the process of vehicle reentry.This pape...Research on the dynamic properties of a plasma sheath coupled with pitching motion of the vehicle has great significance in solving the problem of communication interruption in the process of vehicle reentry.This paper investigates the dynamic properties of the plasma sheath by using the simplified conventional Burnett(SCB)equations and the Navier-Stokes(NS)equations with the thermochemical non-equilibrium effect.The eleven-species chemical kinetic models are applied to the comparison and there is verification of a dynamic plasma sheath simulation for the first time.After the introduction of vehicle pitching motion,the dynamic results are more consistent with the experimental data than the simulated results when treating it as static state.The plasma sheath characteristic parameters show periodic properties,whose changing period is the same as the pitching motion period.However,because of different velocities of the pitching motion,phase shifts exist in different positions of the vehicle.The enhancement of the rarefied effect weakens the disturbance to the plasma sheath.This research reveals the distribution and regularities of the dynamic plasma sheath.It is significant in solving the ionization blackout problem and the design of the reentry vehicle,and provides reliable data for further research on the dynamic plasma sheath.展开更多
基金Supported by the National Basic Research Program of China(2015CB655301)the National Natural Science Foundation of China(21506091)+2 种基金the Jiangsu Natural Science Foundations(BK20150944)the Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fund(the second phase)the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘Nanofluidics in hydrophilic nanopores is a common issue in many natural and industrial processes. Among all,the mass transport of nanofluidics is most concerned. Besides that, the heat transfer of a fluid flow in nano or micro channels is always considered with adding nanoparticles into the flow, so as to enhance the heat transfer by convection between the fluid and the surface. However, for some applications with around 1 nm channels such as nano filtration or erosion of rocks, there should be no nanoparticles included. Hence, it is necessary to figure out the heat transfer mechanism in the single phase nanofluidics. Via non-equilibrium molecular dynamics simulations, we revealed the heat transfer inside nanofluidics and the one between fluid and walls by setting simulation into extremely harsh condition. It was found that the heat was conducted by molecular motion without temperature gradient in the area of low viscous heat, while it was transferred to the walls by increasing the temperature of fluids. If the condition back to normal, it was found that the viscous heat of nanofluidics could be easily removed by the fluid-wall temperature drop of less than 1 K.
基金supported by the National Basic Research Program of China (2009CB226103, 2009CB219902)Swedish Research Councilgrateful to the support by the 363rd Session of Xiangshan Science Conferences, "Scientific Issues of Energy Conservation Mechanism for Waste-decreasing Process"
文摘In this paper, the methodology of non-equilibrium thermodynamics is introduced for kinetics research of CO2 capture by ionic liquids, and the following three key scientific problems are proposed to apply the methodology in kinetics research of CO2 capture by ionic liquids: reliable thermodynamic models, interfacial transport rate description and accurate experimental flux. The obtaining of accurate experimental flux requires reliable experimental kinetics data and the effective transport area in the CO2 capture process by ionic liquids. Research advances in the three key scientific problems are reviewed systematically and further work is analyzed. Finally, perspectives of non-equilibrium thermodynamic research of the kinetics of CO2 capture by ionic liquids are proposed.
文摘Research on the dynamic properties of a plasma sheath coupled with pitching motion of the vehicle has great significance in solving the problem of communication interruption in the process of vehicle reentry.This paper investigates the dynamic properties of the plasma sheath by using the simplified conventional Burnett(SCB)equations and the Navier-Stokes(NS)equations with the thermochemical non-equilibrium effect.The eleven-species chemical kinetic models are applied to the comparison and there is verification of a dynamic plasma sheath simulation for the first time.After the introduction of vehicle pitching motion,the dynamic results are more consistent with the experimental data than the simulated results when treating it as static state.The plasma sheath characteristic parameters show periodic properties,whose changing period is the same as the pitching motion period.However,because of different velocities of the pitching motion,phase shifts exist in different positions of the vehicle.The enhancement of the rarefied effect weakens the disturbance to the plasma sheath.This research reveals the distribution and regularities of the dynamic plasma sheath.It is significant in solving the ionization blackout problem and the design of the reentry vehicle,and provides reliable data for further research on the dynamic plasma sheath.
