In the present study,high-zirconium ternary Zr-Al-Fe bulk metallic glasses(BMGs) with low Young's modulus and good plasticity were developed.Zr75 Al7.5 Fe17.5 BMG exhibits a low Young's modulus of 70 GPa and h...In the present study,high-zirconium ternary Zr-Al-Fe bulk metallic glasses(BMGs) with low Young's modulus and good plasticity were developed.Zr75 Al7.5 Fe17.5 BMG exhibits a low Young's modulus of 70 GPa and high Poisson's ratio of 0.403.Pronounced plasticity was demonstrated under both compression and bending conditions for the BMGs.Furthermore,the alloys show high corrosion resistance in phosphate buffered solution.The combination of desirable mechanical and chemical properties implies potential for biomedical applications.展开更多
Ir-Ni-Ta metallic glasses(MGs)exhibit an array of superior high-temperature properties,making them attractive for applications at high temperatures or in harsh environments.However,Ir-Ni-Ta bulk MGs are quite brittle ...Ir-Ni-Ta metallic glasses(MGs)exhibit an array of superior high-temperature properties,making them attractive for applications at high temperatures or in harsh environments.However,Ir-Ni-Ta bulk MGs are quite brittle and often fracture catastrophically even before plastic yielding,significantly undercutting their high-strength advantage.Here,we show that the Ir-Ni-Ta MGs are not intrinsically brittle,but rather malleable when the feature size is reduced to micro/nano-scales.All tested Ir-Ni-Ta MG micropillars with a diameter ranging from~500 nm to~5μm display a large plastic strain above 25%(the maximum up to 35%),together with a yield strength up to 7 GPa,well exceeding the strength recorded in most metallic materials.The intrinsic shear stability of Ir-Ni-Ta MGs,as characterized by the normalized shear displacement during a shear event,is much larger than those malleable Zr-and Cu-based MGs.Our results suggest that Ir-Ni-Ta MGs are excellent candidates for micro/nanoscale structural applications used at high-temperature or extreme conditions.展开更多
基金supported by the National Natural Science Foundation of China (Grant No. 51071008,51131002 and 51161130526)
文摘In the present study,high-zirconium ternary Zr-Al-Fe bulk metallic glasses(BMGs) with low Young's modulus and good plasticity were developed.Zr75 Al7.5 Fe17.5 BMG exhibits a low Young's modulus of 70 GPa and high Poisson's ratio of 0.403.Pronounced plasticity was demonstrated under both compression and bending conditions for the BMGs.Furthermore,the alloys show high corrosion resistance in phosphate buffered solution.The combination of desirable mechanical and chemical properties implies potential for biomedical applications.
基金supported by the National Key Research and Development Plan(2018YFA0703603)Guangdong Major Project of Basic and Applied Basic Research,China(2019B030302010)+1 种基金the National Natural Science Foundation of China(51822107,11790291 and 61888102)the Strategic Priority Research Program of Chinese Academy of Sciences(XDB30000000)。
文摘Ir-Ni-Ta metallic glasses(MGs)exhibit an array of superior high-temperature properties,making them attractive for applications at high temperatures or in harsh environments.However,Ir-Ni-Ta bulk MGs are quite brittle and often fracture catastrophically even before plastic yielding,significantly undercutting their high-strength advantage.Here,we show that the Ir-Ni-Ta MGs are not intrinsically brittle,but rather malleable when the feature size is reduced to micro/nano-scales.All tested Ir-Ni-Ta MG micropillars with a diameter ranging from~500 nm to~5μm display a large plastic strain above 25%(the maximum up to 35%),together with a yield strength up to 7 GPa,well exceeding the strength recorded in most metallic materials.The intrinsic shear stability of Ir-Ni-Ta MGs,as characterized by the normalized shear displacement during a shear event,is much larger than those malleable Zr-and Cu-based MGs.Our results suggest that Ir-Ni-Ta MGs are excellent candidates for micro/nanoscale structural applications used at high-temperature or extreme conditions.