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加盐萃取精馏分离苯中低含量正庚烷的实验研究 被引量:3
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作者 董红星 刘剑 +2 位作者 李占双 侯智尧 裴健 《哈尔滨工程大学学报》 EI CAS CSCD 2004年第6期728-731,共4页
为获得高纯度苯,须除去粗苯中正庚烷等杂质,在正庚烷质量分数较低时,苯与正庚烷之间的相对挥发度趋近于1,采用萃取精馏进行分离存在萃取剂耗量过大等缺点,溶剂加盐萃取精馏克服了萃取精馏的缺点,该技术是目前学术界高度关注的方法,其在... 为获得高纯度苯,须除去粗苯中正庚烷等杂质,在正庚烷质量分数较低时,苯与正庚烷之间的相对挥发度趋近于1,采用萃取精馏进行分离存在萃取剂耗量过大等缺点,溶剂加盐萃取精馏克服了萃取精馏的缺点,该技术是目前学术界高度关注的方法,其在分离醇—水、酯—水等极性体系得到了广泛的应用.但该技术应用于非极性体系的研究刚刚起步.这里采用加盐萃取精馏方法对苯-正庚烷非极性体系进行了实验研究,考察了盐的类型、盐的质量分数、溶剂体积比等因素对分离苯-正庚烷两组分的分离效果影响,并分析了上述因素对其相对挥发度影响的规律.结果表明:采用DMF为溶剂(溶剂与原料液体积比为1∶1)加KSCN(质量分数为13%)分离苯中低含量正庚烷取得了令人满意的结果,其相对挥发度在全组成范围内有较大提高. 展开更多
关键词 加盐萃取精馏 DMF+KSCN 非极性体 苯和正庚烷
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A Perfect Shape Factor Corresponding States Principle for Pure Non-Polar and Polar Fluids
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作者 陈新志 王连尉 侯虞钧 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2001年第4期421-426,共6页
In the two-parameter corresponding states principle(CSP), the critical compressibility factors of the fluid under study(called 'a' fluid) and the reference fluid(called 'o' fluid) must be identical. Th... In the two-parameter corresponding states principle(CSP), the critical compressibility factors of the fluid under study(called 'a' fluid) and the reference fluid(called 'o' fluid) must be identical. This is not generally observed in nature. To overcome this limitation, a perfect shape factor CSP is proposed in which the compressibility factors of 'a' and 'o' fluids are corresponded perfectly by introducing a new pressure shape factor 8. Using methane as the 'o' fluid, the shape factors of many fluids are calculated from PVT properties at saturation state and the second virial coefficients. Models are also formulated for the shape factors with the assumption of is a function of temperature and volume while 6 and 5 are temperature dependent only. The models described the shape factors satisfactorily in whole region including vapor, liquid and their co-existing phases. The perfect shape factor CSP could be applied for both polar and non-polar fluids. 展开更多
关键词 perfect shape factor corresponding states principle thermodynamic property equation of state
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All-optical diode effect of a nonlinear photonic crystal with a defect
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作者 WANG Wei-jiang ZHOU Jin-yun XIAO Wan-neng 《Optoelectronics Letters》 EI 2006年第3期237-239,共3页
An all-optical diode behavior that uses a nonlinear one-dimensional photonic crystal (NPC) with a defect Kerr medium is numerically simulated by the use of a nonlinear finite-difference time-domain (NFDTD) method.The ... An all-optical diode behavior that uses a nonlinear one-dimensional photonic crystal (NPC) with a defect Kerr medium is numerically simulated by the use of a nonlinear finite-difference time-domain (NFDTD) method.The numerical results show that for an incident pulse with appropriate intensity and temporal width,the transmittance can be several times greater in one direction of NPC than in the opposite direction at the pulse carrier frequency. This behaves like an all-optical diode and has promising applications in some areas such as optical isolation and all-optical processing.The ways to obtain low threshold of pulse field strength to realize an all-optical diode are also analyzed in detail. 展开更多
关键词 光学二极管 线性光子晶 KERR介质 有限微分时间域
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A Theoretic Model for the Shock Observed in Geo-space
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作者 SHIJian-Kui WANGXiao +2 位作者 ZHANGTie-Long TorkarKlaus LIUZhen-Xing 《Communications in Theoretical Physics》 SCIE CAS CSCD 2005年第5期923-926,共4页
An electrostatic model for the shock observed in the earth's polar region is established by deriving the 'Sagdeev potential' from the magnetohydrodynamic equations in a cylindrical coordinate system. The r... An electrostatic model for the shock observed in the earth's polar region is established by deriving the 'Sagdeev potential' from the magnetohydrodynamic equations in a cylindrical coordinate system. The results show that the shock can develop from the ion acoustic wave or ion cyclotron wave in the polar region, and can exist when the Mach number M and the initial electric field E-0 satisfy the condition of vertical bar(a/M-2-1)E(0)vertical bar = 1. Also, some features of the shock wave are discussed. The result can interpret the electrostatic shock observed in the earth's polar region. 展开更多
关键词 MAGNETOHYDRODYNAMICS shock wave polar ionosphere
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Wavelength conversion based on nonlinear polarization rotation in gain transparent SOA
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作者 豆荣社 余重秀 +4 位作者 王葵如 王拥军 桑新柱 张琦 颜玢玢 《Optoelectronics Letters》 EI 2012年第4期289-292,共4页
We describe an all-optical wavelength conversion scheme for 1310 nm to 1550 nm based on nonlinear polarization rotation in a gain-transparent semiconductor optical amplifier (GT-SOA) which brings in the assistant li... We describe an all-optical wavelength conversion scheme for 1310 nm to 1550 nm based on nonlinear polarization rotation in a gain-transparent semiconductor optical amplifier (GT-SOA) which brings in the assistant light to improve the property of the converted light. From the SOA carder density equations, the 1310 nm-to-1550 nm wavelength conversion scheme is analyzed by the Jones matrix. The phase shift between TE and TM modes and the converted light are simulated at bit rate of 30 Gbit/s. We also analyze the influence of the input signal power, the injected current and the assistant light power on the extinction ratio of the converted li~,ht. 展开更多
关键词 POLARIZATION
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