采用非模型拟合法研究了Mg_(17)Al_(12)储氢合金燃烧合成过程动力学,为今后规模化制备该合金提供理论指导。首先比较不同样品燃烧合成过程热效应及产物相组分,指出压片预处理方法及小尺寸Al粉均有利于促进合金化反应;然后分别采用Kissin...采用非模型拟合法研究了Mg_(17)Al_(12)储氢合金燃烧合成过程动力学,为今后规模化制备该合金提供理论指导。首先比较不同样品燃烧合成过程热效应及产物相组分,指出压片预处理方法及小尺寸Al粉均有利于促进合金化反应;然后分别采用Kissinger法和Flynn-Wall-Ozawa法计算出该反应活化能分别为140.5和142 k J/mol,对应的最概然机制函数为G(α)=[-ln(1-α)]1/3,符合Avrami-Erofeev方程的随机成核和随后生长机制。最后通过反应前后期产物相组成分析,揭示该燃烧合成过程中Mg-Al合金化反应机制。展开更多
Numerous experimental studies reveal that the mechanical and deformational behaviors of sands are dependent on the combined effect of void ratio and stress. To predict this complex behavior of sands, a hypo-elastic mo...Numerous experimental studies reveal that the mechanical and deformational behaviors of sands are dependent on the combined effect of void ratio and stress. To predict this complex behavior of sands, a hypo-elastic model is developed based on the cross-anisotropic elasticity model, which involves four parameters: bulk module, tangent Young's module, volume deformation coefficient and Poisson ratio. A parameter defined as virtual peak deviatoric stress dependent on state parameter is introduced into hyperbolic stress strain relationship to determine tangent Young's module. In addition, an existing fitting equation for isotropic compression curves and an existing dilatancy equation, which can consider the effect of state of sands, are employed to determine bulk module and volume deformation coefficient. Thirteen model constants are involved in the proposed model, the values of which are fixed for a sand over a wide range of initial void ratios and initial confining pressures. Well known experimental data for drained and undrained triaxial compression tests of Toyoura sand are successfully modeled.展开更多
文摘采用非模型拟合法研究了Mg_(17)Al_(12)储氢合金燃烧合成过程动力学,为今后规模化制备该合金提供理论指导。首先比较不同样品燃烧合成过程热效应及产物相组分,指出压片预处理方法及小尺寸Al粉均有利于促进合金化反应;然后分别采用Kissinger法和Flynn-Wall-Ozawa法计算出该反应活化能分别为140.5和142 k J/mol,对应的最概然机制函数为G(α)=[-ln(1-α)]1/3,符合Avrami-Erofeev方程的随机成核和随后生长机制。最后通过反应前后期产物相组成分析,揭示该燃烧合成过程中Mg-Al合金化反应机制。
基金Project(2010BC732101)supported by the National Basic Research Program of China
文摘Numerous experimental studies reveal that the mechanical and deformational behaviors of sands are dependent on the combined effect of void ratio and stress. To predict this complex behavior of sands, a hypo-elastic model is developed based on the cross-anisotropic elasticity model, which involves four parameters: bulk module, tangent Young's module, volume deformation coefficient and Poisson ratio. A parameter defined as virtual peak deviatoric stress dependent on state parameter is introduced into hyperbolic stress strain relationship to determine tangent Young's module. In addition, an existing fitting equation for isotropic compression curves and an existing dilatancy equation, which can consider the effect of state of sands, are employed to determine bulk module and volume deformation coefficient. Thirteen model constants are involved in the proposed model, the values of which are fixed for a sand over a wide range of initial void ratios and initial confining pressures. Well known experimental data for drained and undrained triaxial compression tests of Toyoura sand are successfully modeled.
