We present a short and direct derivation of Hawking radiation by using the Damour-Ruffini method, as taking into account the self-gravitational interaction from the Kerr-Newman black hole, It is found that the radiati...We present a short and direct derivation of Hawking radiation by using the Damour-Ruffini method, as taking into account the self-gravitational interaction from the Kerr-Newman black hole, It is found that the radiation is not exactly thermal, and because the derivation obey conservation laws, the non-thermal Hawking radiation can carry information from the black hole. So it can be used to explain the black hole information paradox, and the process satisfies unitary.展开更多
A chemical process may involve multiple adiabatic electronic states, and non-adiabatic couplings play an important role in the reaction mechanism. In this work, the effect of non-adiabatic couplings in the H+MgH;→Mg;...A chemical process may involve multiple adiabatic electronic states, and non-adiabatic couplings play an important role in the reaction mechanism. In this work, the effect of non-adiabatic couplings in the H+MgH;→Mg;+H;reaction are studied using the time-dependent wave packet method and trajectory surface hopping method. The calculated results show that the reaction follows a direct abstraction process when the non-adiabatic couplings are neglected. However, when non-adiabatic couplings are included in the calculations, a longlived excited state complex(MgH_(2)+)*can be formed during the reaction. These direct and complex-forming reaction pathways are revealed by trajectory surface hopping calculations.The non-adiabatic couplings induced complex-forming mechanism not only increases the reactivity but also has significant effect on the product vibrational state distribution.展开更多
Understanding the interaction between a fluid and a solid phase is of fundamental importance to the design of an adsorption process.Because the heat effects associated with adsorption are comparatively large,the as-su...Understanding the interaction between a fluid and a solid phase is of fundamental importance to the design of an adsorption process.Because the heat effects associated with adsorption are comparatively large,the as-sumption of isothermal behavior is a valid approximation only when uptake rates are relatively slow.In this article,we propose to determine when it is needed to choose the isothermal or non-isothermal assumption according to two physical parametersα（ratio convection/capacity） andβ（quantity of energy/capacity） .The proposed problem is solved by a mathematical method in the Laplace domain.Whenα→∞（infinitely high heat transfer coefficient） or β→0（infinitely large heat capacity） ,the limiting case is isothermal.When the diffusion is rapid（α10） the kinetics of sorption is controlled entirely by heat transfer.If the adsorption process is to be used as a heat pump,it shall be represented by an isotherm model withαandβas high as possible.展开更多
Stresses, particularly those at geometric discontinuities, influence the structural integrity of engineering components. Motivated by the prevalence of complicated-shaped perforated components, the objective of this p...Stresses, particularly those at geometric discontinuities, influence the structural integrity of engineering components. Motivated by the prevalence of complicated-shaped perforated components, the objective of this paper is to demonstrate the ability to stress analyze loaded finite members containing asymmetrical, irregularly-shaped cutouts. Recognizing the difficulties in obtaining purely theoretical or numerical solutions for these situations, the paper presents an expeditious means of experimentally stress analyzing such structures. Processing the load-induced temperature information with a series representation of a stress function provides the independent stress components reliably full-field, including on the edge of a hole. The stresses satisfy equilibrium and strains satisfy compatibility. In addition to being able to stress analyze complicated shapes using real, rather than complex variables, the technique is significant in which it smooths the recorded thermal information, is widely applicable, and requires neither differentiating the measured data nor knowing the elastic properties or external boundary conditions. The latter is extremely important since the external loading is often unknown in practice. That the approach provides the independent stresses is also significant since fatigue analyses and strength criteria typically necessitate knowing the individual components of stress. Present results are supported by those from a finite element analysis, strain gage measurements and load equilibrium.展开更多
Co-based Co63Fe4B22.4Si5.6Nb5 amorphous ribbons with a width of 150 μm and a thickness of 50 μm were prepared by single-roller melt-spinning process.The giant magneto-impedance(GMI) effect of the stress-joule-heated...Co-based Co63Fe4B22.4Si5.6Nb5 amorphous ribbons with a width of 150 μm and a thickness of 50 μm were prepared by single-roller melt-spinning process.The giant magneto-impedance(GMI) effect of the stress-joule-heated ribbons under applied tensile stress ranging from 37 to 148 MPa was investigated.Experimental results show that the spectra of GMI ratio vs.external direct current(dc) field(Hex) of the samples changes dramatically with annealing tension() and driving frequency.The single-peak(SP) GMI curve with maximum GMI ratio of 260% and magnetic field sensitivity of 52%/Oe was obtained in the sample applied tensile stress of 74 MPa at frequency of 3.6 MHz.A three-peak behaviour appeared in the samples under σ of 111 and 148 MPa.The uncommon three-peak behaviour was attributed to several factors,which effectively originated from the balance between domain-wall movement and magnetization rotation.展开更多
Interfacial transfer plays an important role in multi-phase chemical processes. However, it is difficult to describe the complex interfacial transport behavior by the traditional mass transfer model. In this paper, we...Interfacial transfer plays an important role in multi-phase chemical processes. However, it is difficult to describe the complex interfacial transport behavior by the traditional mass transfer model. In this paper, we describe an interfacial mass transfer model based on linear non-equilibrium thermodynamics for the analysis of the rate of interfacial transport. The interfacial transfer process rate J depends on the interface mass transfer coefficient K, interfacial area A and chemical potential gradient at the interface. Potassium compounds were selected as model systems. A model based on linear non-equilibrium thermo-dynamics was established in order to describe and predict the transport rate at the solid-solution interface. Together with accurate experimental kinetic data for potassium ions obtained using ion-selective electrodes, a general model which can be used to describe the dissolution rate was established and used to analyze ways of improving the process rate.展开更多
基金supported by the Scientific and Technological Foundation of Chongqing Municipal Education Commission under Grant No.KJ0707011
文摘We present a short and direct derivation of Hawking radiation by using the Damour-Ruffini method, as taking into account the self-gravitational interaction from the Kerr-Newman black hole, It is found that the radiation is not exactly thermal, and because the derivation obey conservation laws, the non-thermal Hawking radiation can carry information from the black hole. So it can be used to explain the black hole information paradox, and the process satisfies unitary.
基金supported by the National Natural Science Foundation of China(No.11774043)。
文摘A chemical process may involve multiple adiabatic electronic states, and non-adiabatic couplings play an important role in the reaction mechanism. In this work, the effect of non-adiabatic couplings in the H+MgH;→Mg;+H;reaction are studied using the time-dependent wave packet method and trajectory surface hopping method. The calculated results show that the reaction follows a direct abstraction process when the non-adiabatic couplings are neglected. However, when non-adiabatic couplings are included in the calculations, a longlived excited state complex(MgH_(2)+)*can be formed during the reaction. These direct and complex-forming reaction pathways are revealed by trajectory surface hopping calculations.The non-adiabatic couplings induced complex-forming mechanism not only increases the reactivity but also has significant effect on the product vibrational state distribution.
文摘Understanding the interaction between a fluid and a solid phase is of fundamental importance to the design of an adsorption process.Because the heat effects associated with adsorption are comparatively large,the as-sumption of isothermal behavior is a valid approximation only when uptake rates are relatively slow.In this article,we propose to determine when it is needed to choose the isothermal or non-isothermal assumption according to two physical parametersα（ratio convection/capacity） andβ（quantity of energy/capacity） .The proposed problem is solved by a mathematical method in the Laplace domain.Whenα→∞（infinitely high heat transfer coefficient） or β→0（infinitely large heat capacity） ,the limiting case is isothermal.When the diffusion is rapid（α10） the kinetics of sorption is controlled entirely by heat transfer.If the adsorption process is to be used as a heat pump,it shall be represented by an isotherm model withαandβas high as possible.
文摘Stresses, particularly those at geometric discontinuities, influence the structural integrity of engineering components. Motivated by the prevalence of complicated-shaped perforated components, the objective of this paper is to demonstrate the ability to stress analyze loaded finite members containing asymmetrical, irregularly-shaped cutouts. Recognizing the difficulties in obtaining purely theoretical or numerical solutions for these situations, the paper presents an expeditious means of experimentally stress analyzing such structures. Processing the load-induced temperature information with a series representation of a stress function provides the independent stress components reliably full-field, including on the edge of a hole. The stresses satisfy equilibrium and strains satisfy compatibility. In addition to being able to stress analyze complicated shapes using real, rather than complex variables, the technique is significant in which it smooths the recorded thermal information, is widely applicable, and requires neither differentiating the measured data nor knowing the elastic properties or external boundary conditions. The latter is extremely important since the external loading is often unknown in practice. That the approach provides the independent stresses is also significant since fatigue analyses and strength criteria typically necessitate knowing the individual components of stress. Present results are supported by those from a finite element analysis, strain gage measurements and load equilibrium.
基金supported by the National Natural Science Foundation of China(Grant Nos.50825103 and 51271194)Ningbo Science and Technology Innovation Team(Grant No.2011B82004)Equipment Project for Research of the Chinese Academy of Sciences(Grant No.Y2010010)
文摘Co-based Co63Fe4B22.4Si5.6Nb5 amorphous ribbons with a width of 150 μm and a thickness of 50 μm were prepared by single-roller melt-spinning process.The giant magneto-impedance(GMI) effect of the stress-joule-heated ribbons under applied tensile stress ranging from 37 to 148 MPa was investigated.Experimental results show that the spectra of GMI ratio vs.external direct current(dc) field(Hex) of the samples changes dramatically with annealing tension() and driving frequency.The single-peak(SP) GMI curve with maximum GMI ratio of 260% and magnetic field sensitivity of 52%/Oe was obtained in the sample applied tensile stress of 74 MPa at frequency of 3.6 MHz.A three-peak behaviour appeared in the samples under σ of 111 and 148 MPa.The uncommon three-peak behaviour was attributed to several factors,which effectively originated from the balance between domain-wall movement and magnetization rotation.
基金supported by the Chinese National Key Technology Research and Development Program (2006AA03Z455)the National Natural Science Foundation of China (NSFC)+3 种基金the National Natural Science Foundation of China (20976080, 20736002)the Research Grants Council(RGC) of Hong Kong Joint Research Scheme (JRS) (20731160614)Program for Changjiang Scholars and Innovative Research Team in University (IRT0732)National Basic Research Program of China (2009CB226103)
文摘Interfacial transfer plays an important role in multi-phase chemical processes. However, it is difficult to describe the complex interfacial transport behavior by the traditional mass transfer model. In this paper, we describe an interfacial mass transfer model based on linear non-equilibrium thermodynamics for the analysis of the rate of interfacial transport. The interfacial transfer process rate J depends on the interface mass transfer coefficient K, interfacial area A and chemical potential gradient at the interface. Potassium compounds were selected as model systems. A model based on linear non-equilibrium thermo-dynamics was established in order to describe and predict the transport rate at the solid-solution interface. Together with accurate experimental kinetic data for potassium ions obtained using ion-selective electrodes, a general model which can be used to describe the dissolution rate was established and used to analyze ways of improving the process rate.
