The present work concerns the study of solvent effects on the geometrical structures, as well as one- and two-photon absorption （TPA） processes, for two series of alkyne and alkene π-bridging molecules, within the ...The present work concerns the study of solvent effects on the geometrical structures, as well as one- and two-photon absorption （TPA） processes, for two series of alkyne and alkene π-bridging molecules, within the framework of the polarization continuum model. Particular emphasis was put on the characterization of solvent effects on the molecular geometrical structures and geometric distortion, which were measured by the bond-length-alternation parameter. The π centres in the compounds are seen to play a decisive role in increasing the TPA cross section and nonlinear optical properties. All studied molecules have relatively strong TPA characteristics, while the alkyne π-bridging ones yield larger TPA cross sections.展开更多
In the present work,nonlinear interaction of elliptical laser beam with collisional plasma is studied by using paraxial ray approximation.Nonlinear differential equations for the beam width parameters of semi-major ax...In the present work,nonlinear interaction of elliptical laser beam with collisional plasma is studied by using paraxial ray approximation.Nonlinear differential equations for the beam width parameters of semi-major axis and semi-minor axis of elliptical laser beam have been set up and solved numerically to study the variation of beam width parameters with normalized distance of propagation.Effects of variation in absorption coefficient and plasma density on the beam width parameters are also analyzed.It is observed from the analysis that extent of self-focusing of beam increases with increase/decrease in plasma density/absorption coefficient.展开更多
文摘The present work concerns the study of solvent effects on the geometrical structures, as well as one- and two-photon absorption （TPA） processes, for two series of alkyne and alkene π-bridging molecules, within the framework of the polarization continuum model. Particular emphasis was put on the characterization of solvent effects on the molecular geometrical structures and geometric distortion, which were measured by the bond-length-alternation parameter. The π centres in the compounds are seen to play a decisive role in increasing the TPA cross section and nonlinear optical properties. All studied molecules have relatively strong TPA characteristics, while the alkyne π-bridging ones yield larger TPA cross sections.
文摘In the present work,nonlinear interaction of elliptical laser beam with collisional plasma is studied by using paraxial ray approximation.Nonlinear differential equations for the beam width parameters of semi-major axis and semi-minor axis of elliptical laser beam have been set up and solved numerically to study the variation of beam width parameters with normalized distance of propagation.Effects of variation in absorption coefficient and plasma density on the beam width parameters are also analyzed.It is observed from the analysis that extent of self-focusing of beam increases with increase/decrease in plasma density/absorption coefficient.
