The similarities of the non-linear chemical (NLC) fingerprints of Radix Glycyrrhizaes from four producing areas and eight other traditional Chinese medicines (TCMs) were calculated, using a systemic similarity cal...The similarities of the non-linear chemical (NLC) fingerprints of Radix Glycyrrhizaes from four producing areas and eight other traditional Chinese medicines (TCMs) were calculated, using a systemic similarity calculation method proposed and three other main calculation ones (Euclidean distance, correlation coefficient and included angle cosine). All of the correlation coefficient similarities of different TCMs are higher than 0.952, and the included angle cosines are all higher than 0.962. So, both the conelation coefficient and included angle cosine similarities are unable to be used as the criteria for quantitatively evaluating the similarities of NLC fingerprints of TCMs. Although all of the Euclidean distance similarities of Berry Liquorices from four producing areas are less than 73, those of the other eight TCMs are all more than 180. The Euclidean distance cannot reflect the relative magnitudes of the feature differences in the NLC fingerprints very correctly. The systemic similarity method is the best among the four ones. All of the systemic similarities of Berry Liquorices from the four producing areas are higher than 0.962, while those of the other eight TCMs are all lower than 0.805, and the systemic similarity can reflect the differences between samples most faithfully, and can be used as a quantitative one evaluating the similarities of NLC fingerprints of TCMs, by which TCM could be distinguished and evaluated quickly, simply and exactly.展开更多
Mooring system plays an important role in station keeping of floating offshore structures. Coupled analysis on mooring-buoy interactions has been increasingly studied in recent years. At present, chains and wire ropes...Mooring system plays an important role in station keeping of floating offshore structures. Coupled analysis on mooring-buoy interactions has been increasingly studied in recent years. At present, chains and wire ropes are widely used in offshore engineering practice. On the basis of mooring line statics, an explicit formulation of single mooring chain/wire rope stiffness coefficients and mooring stiffness matrix of the mooring system were derived in this article, taking into account the horizontal restoring force, vertical restoring force and their coupling terms. The nonlinearity of mooring stiffness was analyzed, and the influences of various parameters, such as material, displacement, pre-tension and water depth, were investigated. Finally some application cases of the mooring stiffness in hydrodynamic calculation were presented. Data shows that this kind of stiffness can reckon in linear and nonlinear forces of mooring system. Also, the stiffness can be used in hydrodynamic analysis to get the eieenfrequencv of slow drift motions.展开更多
In this paper, the incremental harmonic balance nonlinear identification (IHBNID) is presented for modelling and parametric identification of nonlinear systems. The effects of harmonic balance nonlinear identification...In this paper, the incremental harmonic balance nonlinear identification (IHBNID) is presented for modelling and parametric identification of nonlinear systems. The effects of harmonic balance nonlinear identification (HBNID) and IHBNID are also studied and compared by using numerical simulation. The effectiveness of the IHBNID is verified through the Mathieu-Duffing equation as an example. With the aid of the new method, the derivation procedure of the incremental harmonic balance method is simplified. The system responses can be represented by the Fourier series expansion in complex form. By keeping several lower-order primary harmonic coefficients to be constant, some of the higher-order harmonic coefficients can be self-adaptive in accordance with the residual errors. The results show that the IHBNID is highly efficient for computation, and excels the HBNID in terms of computation accuracy and noise resistance.展开更多
The third-order nonlinear optical(NLO)materials with stimuli-responsive properties have received extraordinary attention due to their controllable photophysical properties.In this work,two attractive metal complexes t...The third-order nonlinear optical(NLO)materials with stimuli-responsive properties have received extraordinary attention due to their controllable photophysical properties.In this work,two attractive metal complexes third-order NLO switches,which are far superior to congeneric optical switches in terms of their performance conversion,versatility,and fast response,were successfully designed and synthesized.The test of their third-order NLO properties proves that the metal complexes exhibit reverse saturable absorption and self-defocusing refraction.After light irradiation,the third-order NLO behavior turns quickly into self-focusing refraction.The relation between the molecular structures and the third-order NLO properties was investigated via1H nuclear magnetic resonance and ultraviolet-visible absorption.The results show that the metal ions have a significant influence on the NLO behavior and reveal the origin of third-order NLO properties via Z-scan determinations,pump-probe technology,and density functional theory calculations.These metal complexes can be used as third-order NLO switches with excellent fatigue resistance and broaden the application range of third-order NLO materials with adjustable performances.展开更多
基金Project(2009GJD20033) supported by the National Science and Technology Ministry of China
文摘The similarities of the non-linear chemical (NLC) fingerprints of Radix Glycyrrhizaes from four producing areas and eight other traditional Chinese medicines (TCMs) were calculated, using a systemic similarity calculation method proposed and three other main calculation ones (Euclidean distance, correlation coefficient and included angle cosine). All of the correlation coefficient similarities of different TCMs are higher than 0.952, and the included angle cosines are all higher than 0.962. So, both the conelation coefficient and included angle cosine similarities are unable to be used as the criteria for quantitatively evaluating the similarities of NLC fingerprints of TCMs. Although all of the Euclidean distance similarities of Berry Liquorices from four producing areas are less than 73, those of the other eight TCMs are all more than 180. The Euclidean distance cannot reflect the relative magnitudes of the feature differences in the NLC fingerprints very correctly. The systemic similarity method is the best among the four ones. All of the systemic similarities of Berry Liquorices from the four producing areas are higher than 0.962, while those of the other eight TCMs are all lower than 0.805, and the systemic similarity can reflect the differences between samples most faithfully, and can be used as a quantitative one evaluating the similarities of NLC fingerprints of TCMs, by which TCM could be distinguished and evaluated quickly, simply and exactly.
基金Supported by the National Natural Science Foundation of China under Grant No.(51079034).
文摘Mooring system plays an important role in station keeping of floating offshore structures. Coupled analysis on mooring-buoy interactions has been increasingly studied in recent years. At present, chains and wire ropes are widely used in offshore engineering practice. On the basis of mooring line statics, an explicit formulation of single mooring chain/wire rope stiffness coefficients and mooring stiffness matrix of the mooring system were derived in this article, taking into account the horizontal restoring force, vertical restoring force and their coupling terms. The nonlinearity of mooring stiffness was analyzed, and the influences of various parameters, such as material, displacement, pre-tension and water depth, were investigated. Finally some application cases of the mooring stiffness in hydrodynamic calculation were presented. Data shows that this kind of stiffness can reckon in linear and nonlinear forces of mooring system. Also, the stiffness can be used in hydrodynamic analysis to get the eieenfrequencv of slow drift motions.
基金supported by the National Natural Science Foundation of China (Grant Nos. 10672141, 10732020, and 11072008)
文摘In this paper, the incremental harmonic balance nonlinear identification (IHBNID) is presented for modelling and parametric identification of nonlinear systems. The effects of harmonic balance nonlinear identification (HBNID) and IHBNID are also studied and compared by using numerical simulation. The effectiveness of the IHBNID is verified through the Mathieu-Duffing equation as an example. With the aid of the new method, the derivation procedure of the incremental harmonic balance method is simplified. The system responses can be represented by the Fourier series expansion in complex form. By keeping several lower-order primary harmonic coefficients to be constant, some of the higher-order harmonic coefficients can be self-adaptive in accordance with the residual errors. The results show that the IHBNID is highly efficient for computation, and excels the HBNID in terms of computation accuracy and noise resistance.
基金the National Natural Science Foundation of China(21671174 and U1904172)the Zhongyuan Thousand Talents Project,the Natural Science Foundation of Henan Province(182300410008)the Open Foundation of Guangxi Key Laboratory of Processing for Nonferrous Metals and Featured Materials,Guangxi University(2019GXYSOF12).
文摘The third-order nonlinear optical(NLO)materials with stimuli-responsive properties have received extraordinary attention due to their controllable photophysical properties.In this work,two attractive metal complexes third-order NLO switches,which are far superior to congeneric optical switches in terms of their performance conversion,versatility,and fast response,were successfully designed and synthesized.The test of their third-order NLO properties proves that the metal complexes exhibit reverse saturable absorption and self-defocusing refraction.After light irradiation,the third-order NLO behavior turns quickly into self-focusing refraction.The relation between the molecular structures and the third-order NLO properties was investigated via1H nuclear magnetic resonance and ultraviolet-visible absorption.The results show that the metal ions have a significant influence on the NLO behavior and reveal the origin of third-order NLO properties via Z-scan determinations,pump-probe technology,and density functional theory calculations.These metal complexes can be used as third-order NLO switches with excellent fatigue resistance and broaden the application range of third-order NLO materials with adjustable performances.