Fe75Zr3Si13B9 magnetic amorphous powders were fabricated by mechanical alloying. Bulk amorphous and nanocrystalline alloys with 20 mm in diameter and 7 mm in height were fabricated by the spark plasma sintering techno...Fe75Zr3Si13B9 magnetic amorphous powders were fabricated by mechanical alloying. Bulk amorphous and nanocrystalline alloys with 20 mm in diameter and 7 mm in height were fabricated by the spark plasma sintering technology at different sintering temperatures. The phase composition, glass transition temperature (Tg), onset crystallization temperature (Tx), peak temperature (Tp) and super-cooled liquid region (ΔTx) of Fe75Zr3Si13B9 amorphous powders were analyzed by X-ray diffraction (XRD) and differential scanning calorimetry (DSC). The phase transition, microstructure, mechanical properties and magnetic performance of the bulk alloys were discussed with X-ray diffractometer, scanning electron microscope (SEM), Gleeble 3500 and vibration sample magnetometer (VSM), respectively. It is found that with the increase in the sintering temperature at the pressure of 500 MPa, the density, compressive strength, micro-hardness and saturation magnetization of the sintering samples improved significantly, the amorphous phase began to crystallize gradually. Finally, the desirable amorphous and nanocrystalline magnetic materials at the sintering temperature of 863.15 K and the pressure of 500 MPa have a density of 6.9325 g/cm3, a compressive strength of 1140.28 MPa and a saturation magnetization of 1.28 T.展开更多
BISHOP’s effective stress or two state stress variables are unsatisfactory for unsaturated soils where one of fluid phases is discontinuous, so new expressions of effective stress should be founded. The approach for ...BISHOP’s effective stress or two state stress variables are unsatisfactory for unsaturated soils where one of fluid phases is discontinuous, so new expressions of effective stress should be founded. The approach for derivation was according to the principle of equilibrium of forces (i.e., the stress-sharing principle), and it was firstly validated by demonstrating TERZAGHI’s principle of effective stress. And then, the derivations were subdivided into four parts according to different pore air states: 1) air bubbles were spherical and suspended in pore water; 2) air bubbles were bound on soil skeleton; 3) air bubbles held almost the single section of pore; 4) air phase was continuous. The different formulae of effective stress were presented. Conclusions are drawn as follows: 1) For nearly-saturated soils, the "real" effective stress would be a little smaller than TERZAGHI’s effective stress; 2) For soils in which air phase is discontinuous in the form of bubbles, a new concept of pore air elastic pressure is put forward, and the total stress can be constituted by effective stress, pore water pressure and pore air elastic pressure; 3) For soils in which air phase is continuous, effective stress is equal to the value of the total stress plus suction; 4) Suction can be divided into two parts: one is the effect caused by additional pressure, and the other is the contract action by the "skin".展开更多
For the calculation of non-linear magnetic fields, a simple program can be as effective as a large commercialized software package. If relaxation methods are used, they must include successive over-relaxation and unde...For the calculation of non-linear magnetic fields, a simple program can be as effective as a large commercialized software package. If relaxation methods are used, they must include successive over-relaxation and under-relaxation and much attention must be paid to the relaxation factor and the interpolation. In this paper some skills are proposed on the setting of an interpolation switch and the choosing of saturation point so as to assure satisfied convergence properties. The numerical results by using these methods conform well to the tests.展开更多
Homogeneity and heterogeneity are two totally different concepts in nature.At the particle length scale,rocks exhibit strong heterogeneity in their constituents and porosities.When the heterogeneity of porosity obeys ...Homogeneity and heterogeneity are two totally different concepts in nature.At the particle length scale,rocks exhibit strong heterogeneity in their constituents and porosities.When the heterogeneity of porosity obeys the random uniform distribution,both the mean value and the variance of porosities in the heterogeneous porosity field can be used to reflect the overall heterogeneous characteristics of the porosity field.The main purpose of this work is to investigate the effects of porosity heterogeneity on chemical dissolution front instability in fluid-saturated rocks by the computational simulation method.The related computational simulation results have demonstrated that:1) since the propagation speed of a chemical dissolution front is inversely proportional to the difference between the final porosity and the mean value of porosities in the initial porosity field,an increase in the extent of the porosity heterogeneity can cause an increase in the mean value of porosities in the initial porosity field and an increase in the propagation speed of the chemical dissolution front.2) An increase in the variance of porosities in the initial porosity field can cause an increase in the instability probability of the chemical dissolution front in the fluid-saturated rock.3) The greater the mean value of porosities in the initial porosity field,the quicker the irregular morphology of the chemical dissolution front changes in the supercritical chemical dissolution systems.This means that the irregular morphology of a chemical dissolution front grows quicker in a porosity field of heterogeneity than it does in that of homogeneity when the chemical dissolution system is at a supercritical stage.展开更多
In this study consecutive consolidated isotropically drained triaxial tests for the coefficient of earth pressure at rest(K_0) were carried out to investigate its rules of evolution as well as its strength characteris...In this study consecutive consolidated isotropically drained triaxial tests for the coefficient of earth pressure at rest(K_0) were carried out to investigate its rules of evolution as well as its strength characteristics for normal,consolidated saturated silt under high pressure.The tests results indicate that:1) for normal,consolidated saturated silt,K_0 values increase as the consolidation stress increases at high pressure levels,while the nonlinear characteristics of K_0 are inconspicuous compared to cohesive soils;2) the Jaky and Roscoe equations,used to calculate K_0,are only suitable for certain soils,but cannot represent these values for normal, consolidated saturated silt due to the variation in bilinear strength at high pressure;and 3) there are close relations between the nonlinear characteristics of K_0 and the void ratio,measured in the tests.Both share the same functional form while under pressure. Based on our experimental results,we developed an empirical linear model to interpret the rules of nonlinear variation for the coefficient of earth pressure at rest.展开更多
In order to observe CO_2 characteristics in the unsaturated zone of loess tableland and further understand the carbon cycle,a series of tubes for gas monitoring and sampling were installed in an approximately 90-m dee...In order to observe CO_2 characteristics in the unsaturated zone of loess tableland and further understand the carbon cycle,a series of tubes for gas monitoring and sampling were installed in an approximately 90-m deep Qiushe loess section of Lingtai County,Northwestern China.The results show that the concentration of CO_2 was higher in loess than in the atmosphere,reaching a maximum of 6970 lmol·mol^(-1).CO_2 concentrations in loess were higher in summer than in winter.The CO_2 in loess was related to organic carbon decomposed by microbes,and to the CaCO_3–H_2O–CO_2 system in the interface between the saturated and unsaturated zones.展开更多
The soil-water retention curve(SWRC)can be used to evaluate the ability of unsaturated soils to attract water at various water contents and suctions. In this study, drying SWRCs for a kind of sandy soil were obtained ...The soil-water retention curve(SWRC)can be used to evaluate the ability of unsaturated soils to attract water at various water contents and suctions. In this study, drying SWRCs for a kind of sandy soil were obtained in the laboratory by using self-modified SWRC apparatus. In addition, the porosity and the pore size distribution of the samples were investigated by a mercury porosimetry test in order to analyze the effect of dry density. Results showed that the soil-water retention of the soil specimens was strongly dependent on the dry density. Under zero suction, soil specimens with a higher dry density exhibited lower initial volumetric water content. The higher the dry density of soil, the more slowly the volumetric water content decreased with the increase of suction. There was a general and consistent trend for a soil specimen to possess a larger air-entry value and residual suction, while smaller slope of SWRC when it had a higher density. This was probably attributed to the presence of smaller interconnected pores in the soil specimen with a higher dry density. The proportion of large diameter pores decreased in comparison to pores with small diameters in the soil tested. The measured total pore volume of the soil specimen, which had a larger dry density, was lower than that of the relatively loose specimens.展开更多
Detrended fluctuation analysis (DFA) is fit for studies on the long-range exponential correlation of non-stationary time serial. In this paper, in order to find a hy- poxia adaptability evaluation criterion, the hea...Detrended fluctuation analysis (DFA) is fit for studies on the long-range exponential correlation of non-stationary time serial. In this paper, in order to find a hy- poxia adaptability evaluation criterion, the heart rate and SaO2 signals are analyzed by this method. The demarcate exponent about fit-good-group and fit-bad-group in hy- poxia and normal air are calculated and compared. The result shows a is different in different situation, the α in hypoxia is much higher than α of breath in normal air. And α of fit-good-group is higher than fit-bad-group. It shows that DFA could be a good criterion to analyze hypoxia adaptability, which is useful in the analysis of hypoxia phys- iology signal.展开更多
Most failures or instabilities of geotechnical structures commonly result from shear failure in soil. In addition, many infrastructures are constructed within the unsaturated zone. Therefore, the determination of shea...Most failures or instabilities of geotechnical structures commonly result from shear failure in soil. In addition, many infrastructures are constructed within the unsaturated zone. Therefore, the determination of shear strength of unsaturated soil is crucial in geotechnical design. The soil-water characteristic curve(SWCC) is commonly used to estimate the shear strength of unsaturated soil because the direct measurement is time-consuming and costly. However, the uncertainty associated with the determined SWCC is rarely considered in the estimation of the shear strength. In this paper, the uncertainties of SWCC resulted from different factors are reviewed and discussed. The variability of the estimated shear strength for the unsaturated soil due to the uncertainty of SWCC associated with the best fit process is quantified by using the upper and lower bounds of the determined SWCC. On the other hand, the uncertainties of the estimated shear strength due to different initial void ratios or different confining pressures are quantified by adopting different SWCCs. As a result, it is recommended that the measured SWCC from the conventional Tempe cell or pressure plate needs to be corrected by considering different stress levels in the estimation of the shear strength of unsaturated soil.展开更多
Internal magnetic gradient plays a significant role in Nuclear Magnetic Resonance(NMR)measurements of fluid saturated porous media.The quantitative characterization and application of this physical phenomenon could ef...Internal magnetic gradient plays a significant role in Nuclear Magnetic Resonance(NMR)measurements of fluid saturated porous media.The quantitative characterization and application of this physical phenomenon could effectively improve the accuracy of NMR measurements and interpretations.In this paper,by using the equivalent magnetic dipole method,the three-dimensional distribution of internal induced magnetic field and its gradients in the randomly packed water saturated glass beads are quantitatively characterized.By simulating the diffusive motion of water molecules in porous media with random walk method,the computational dephasing effects equation related to internal gradients is deduced.Thereafter,the echo amplitudes are obtained and the corresponding T2-G spectrum is also inverted.For the sake of verifying the simulation results,an experiment is carried out using the Halbach core analyzing system(B0=0.18 T,G=2.3 T/m)to detect the induced internal field and gradients.The simulation results indicate the equivalent internal gradient is a distribution of 0.1-0.3 T/m,which matched well with the experimental results.展开更多
It was well known that it was very difficult to prepare high performance Fe-based bulk amorphous alloys with both high Fe content and good glass-forming ability, especially for the Fe content (or total magnetic eleme...It was well known that it was very difficult to prepare high performance Fe-based bulk amorphous alloys with both high Fe content and good glass-forming ability, especially for the Fe content (or total magnetic elements content) higher than 80 at%. In this paper, a series of Fe81-xCoxMO1P7.5C5.5B2Si3 (x = 0, 5, 10, 15, 20) bulk amorphous alloys (BAAs) with high saturation magnetization have been developed by copper mold casting method with fluxed ingot. It has been found that using Co replacing Fe in the Fe-Mo-P-C-B-Si alloy could significantly enhance the glass-forming ability and magnetic property. For the BAA with Co content of 0 at%, 5 at%, 10 at%, 15 at% and 20 at%, its saturation magnetization Js(Js=μoMs) was 1.55, 1.60, 1.62, 1.65 and 1.59 T, respectively. Among these alloys, the Fe66Co15- Mo1P7.5C5.5B2Si3 BAA exhibited a critical size of 2 mm in diameter and a high Js of 1.65 T. It suggested that these alloys with high magnetic element content possessed great potential in application due to their high glass-forming ability and high magnetic property.展开更多
The classical planar Richtmyer–Meshkov instability(RMI) at a fluid interface supported by a constant pressure is investigated by a formal perturbation expansion up to the third order,and then according to definition ...The classical planar Richtmyer–Meshkov instability(RMI) at a fluid interface supported by a constant pressure is investigated by a formal perturbation expansion up to the third order,and then according to definition of nonlinear saturation amplitude(NSA) in Rayleigh–Taylor instability(RTI),the NSA in planar RMI is obtained explicitly.It is found that the NSA in planar RMI is affected by the initial perturbation wavelength and the initial amplitude of the interface,while the effect of the initial amplitude of the interface on the NSA is less than that of the initial perturbation wavelength.Without marginal influence of the initial amplitude,the NSA increases linearly with wavelength.The NSA normalized by the wavelength in planar RMI is about 0.11,larger than that corresponding to RTI.展开更多
Material functionalities strongly depend on the stoichiometry,crystal structure,and homogeneity.Here we demonstrate an approach of amorphous nonstoichiometric inhomogeneous oxides to realize tunable ferromagnetism and...Material functionalities strongly depend on the stoichiometry,crystal structure,and homogeneity.Here we demonstrate an approach of amorphous nonstoichiometric inhomogeneous oxides to realize tunable ferromagnetism and electrical transport at room temperature.In order to verify the origin of the ferromagnetism,we employed a series of structural,chemical,and electronic state characterizations.Combined with electron microscopy and transport measurements,synchrotron-based grazing incident wide angle X-ray scattering,soft X-ray absorption and circular dichroism clearly reveal that the roomtemperature ferromagnetism originates from the In0.23Co0.77O1-v,amorphous phase with a large tunable range of oxygen vacancies.The room-temperature ferromagnetism is tunable from a high saturation magnetization of 500 emu cm-3 to below 25 emu cm-3,with the evolving electrical resistivity from5×103μΩ cm to above 2.5×105 μΩ cm.Inhomogeneous nano-crystallization emerges with decreasing oxygen vacancies,driving the system towards non-ferromagnetism and insulating regime.Our work unfolds the novel functionalities of amorphous nonstoichiometric inhomogeneous oxides,which opens up new opportunities for developing spintronic materials with superior magnetic and transport properties.展开更多
基金Project(13961001D)supported by the Key Basic Research Project of Hebei Province,ChinaProject(2013BAE08B01)supported by the National Key Technology R&D Program of China
文摘Fe75Zr3Si13B9 magnetic amorphous powders were fabricated by mechanical alloying. Bulk amorphous and nanocrystalline alloys with 20 mm in diameter and 7 mm in height were fabricated by the spark plasma sintering technology at different sintering temperatures. The phase composition, glass transition temperature (Tg), onset crystallization temperature (Tx), peak temperature (Tp) and super-cooled liquid region (ΔTx) of Fe75Zr3Si13B9 amorphous powders were analyzed by X-ray diffraction (XRD) and differential scanning calorimetry (DSC). The phase transition, microstructure, mechanical properties and magnetic performance of the bulk alloys were discussed with X-ray diffractometer, scanning electron microscope (SEM), Gleeble 3500 and vibration sample magnetometer (VSM), respectively. It is found that with the increase in the sintering temperature at the pressure of 500 MPa, the density, compressive strength, micro-hardness and saturation magnetization of the sintering samples improved significantly, the amorphous phase began to crystallize gradually. Finally, the desirable amorphous and nanocrystalline magnetic materials at the sintering temperature of 863.15 K and the pressure of 500 MPa have a density of 6.9325 g/cm3, a compressive strength of 1140.28 MPa and a saturation magnetization of 1.28 T.
基金Project(50878191) supported by the National Natural Science Foundation of ChinaProject(Y12E090030) supported by Zhejiang Provincial Natural Science Foundation, China
文摘BISHOP’s effective stress or two state stress variables are unsatisfactory for unsaturated soils where one of fluid phases is discontinuous, so new expressions of effective stress should be founded. The approach for derivation was according to the principle of equilibrium of forces (i.e., the stress-sharing principle), and it was firstly validated by demonstrating TERZAGHI’s principle of effective stress. And then, the derivations were subdivided into four parts according to different pore air states: 1) air bubbles were spherical and suspended in pore water; 2) air bubbles were bound on soil skeleton; 3) air bubbles held almost the single section of pore; 4) air phase was continuous. The different formulae of effective stress were presented. Conclusions are drawn as follows: 1) For nearly-saturated soils, the "real" effective stress would be a little smaller than TERZAGHI’s effective stress; 2) For soils in which air phase is discontinuous in the form of bubbles, a new concept of pore air elastic pressure is put forward, and the total stress can be constituted by effective stress, pore water pressure and pore air elastic pressure; 3) For soils in which air phase is continuous, effective stress is equal to the value of the total stress plus suction; 4) Suction can be divided into two parts: one is the effect caused by additional pressure, and the other is the contract action by the "skin".
基金Supported by the National Natural Science Fundation of China(No.69881002)
文摘For the calculation of non-linear magnetic fields, a simple program can be as effective as a large commercialized software package. If relaxation methods are used, they must include successive over-relaxation and under-relaxation and much attention must be paid to the relaxation factor and the interpolation. In this paper some skills are proposed on the setting of an interpolation switch and the choosing of saturation point so as to assure satisfied convergence properties. The numerical results by using these methods conform well to the tests.
基金Project(11272359)supported by the National Natural Science Foundation of China
文摘Homogeneity and heterogeneity are two totally different concepts in nature.At the particle length scale,rocks exhibit strong heterogeneity in their constituents and porosities.When the heterogeneity of porosity obeys the random uniform distribution,both the mean value and the variance of porosities in the heterogeneous porosity field can be used to reflect the overall heterogeneous characteristics of the porosity field.The main purpose of this work is to investigate the effects of porosity heterogeneity on chemical dissolution front instability in fluid-saturated rocks by the computational simulation method.The related computational simulation results have demonstrated that:1) since the propagation speed of a chemical dissolution front is inversely proportional to the difference between the final porosity and the mean value of porosities in the initial porosity field,an increase in the extent of the porosity heterogeneity can cause an increase in the mean value of porosities in the initial porosity field and an increase in the propagation speed of the chemical dissolution front.2) An increase in the variance of porosities in the initial porosity field can cause an increase in the instability probability of the chemical dissolution front in the fluid-saturated rock.3) The greater the mean value of porosities in the initial porosity field,the quicker the irregular morphology of the chemical dissolution front changes in the supercritical chemical dissolution systems.This means that the irregular morphology of a chemical dissolution front grows quicker in a porosity field of heterogeneity than it does in that of homogeneity when the chemical dissolution system is at a supercritical stage.
基金Financial support for this work,provided by the National Natural Science Foundation of China (No.50534040)the Project of the Science and Technology Ministry of China(No.2006BAB16B01)the Post Graduate Research Project of Jiangsu Province (No.CX08B_103Z),
文摘In this study consecutive consolidated isotropically drained triaxial tests for the coefficient of earth pressure at rest(K_0) were carried out to investigate its rules of evolution as well as its strength characteristics for normal,consolidated saturated silt under high pressure.The tests results indicate that:1) for normal,consolidated saturated silt,K_0 values increase as the consolidation stress increases at high pressure levels,while the nonlinear characteristics of K_0 are inconspicuous compared to cohesive soils;2) the Jaky and Roscoe equations,used to calculate K_0,are only suitable for certain soils,but cannot represent these values for normal, consolidated saturated silt due to the variation in bilinear strength at high pressure;and 3) there are close relations between the nonlinear characteristics of K_0 and the void ratio,measured in the tests.Both share the same functional form while under pressure. Based on our experimental results,we developed an empirical linear model to interpret the rules of nonlinear variation for the coefficient of earth pressure at rest.
基金supported jointly by National Natural Science Foundation of China(41403107,41325010)the Basic Science Research Fund from the Institute of Hydrogeology and Environmental Geology(SK201208)and the China Geological Survey Projects(12120113005900)
文摘In order to observe CO_2 characteristics in the unsaturated zone of loess tableland and further understand the carbon cycle,a series of tubes for gas monitoring and sampling were installed in an approximately 90-m deep Qiushe loess section of Lingtai County,Northwestern China.The results show that the concentration of CO_2 was higher in loess than in the atmosphere,reaching a maximum of 6970 lmol·mol^(-1).CO_2 concentrations in loess were higher in summer than in winter.The CO_2 in loess was related to organic carbon decomposed by microbes,and to the CaCO_3–H_2O–CO_2 system in the interface between the saturated and unsaturated zones.
基金Supported by the National Natural Science Foundation of China(No.51409261)
文摘The soil-water retention curve(SWRC)can be used to evaluate the ability of unsaturated soils to attract water at various water contents and suctions. In this study, drying SWRCs for a kind of sandy soil were obtained in the laboratory by using self-modified SWRC apparatus. In addition, the porosity and the pore size distribution of the samples were investigated by a mercury porosimetry test in order to analyze the effect of dry density. Results showed that the soil-water retention of the soil specimens was strongly dependent on the dry density. Under zero suction, soil specimens with a higher dry density exhibited lower initial volumetric water content. The higher the dry density of soil, the more slowly the volumetric water content decreased with the increase of suction. There was a general and consistent trend for a soil specimen to possess a larger air-entry value and residual suction, while smaller slope of SWRC when it had a higher density. This was probably attributed to the presence of smaller interconnected pores in the soil specimen with a higher dry density. The proportion of large diameter pores decreased in comparison to pores with small diameters in the soil tested. The measured total pore volume of the soil specimen, which had a larger dry density, was lower than that of the relatively loose specimens.
文摘Detrended fluctuation analysis (DFA) is fit for studies on the long-range exponential correlation of non-stationary time serial. In this paper, in order to find a hy- poxia adaptability evaluation criterion, the heart rate and SaO2 signals are analyzed by this method. The demarcate exponent about fit-good-group and fit-bad-group in hy- poxia and normal air are calculated and compared. The result shows a is different in different situation, the α in hypoxia is much higher than α of breath in normal air. And α of fit-good-group is higher than fit-bad-group. It shows that DFA could be a good criterion to analyze hypoxia adaptability, which is useful in the analysis of hypoxia phys- iology signal.
基金Project supported by the National Natural Science Foundation of China(No.51878160)the National Key Research and Development Program of China(No.2017YFC00703408)the Research Funding from China Huaneng Group Co.Ltd.(No.HNKJ19-H17)。
文摘Most failures or instabilities of geotechnical structures commonly result from shear failure in soil. In addition, many infrastructures are constructed within the unsaturated zone. Therefore, the determination of shear strength of unsaturated soil is crucial in geotechnical design. The soil-water characteristic curve(SWCC) is commonly used to estimate the shear strength of unsaturated soil because the direct measurement is time-consuming and costly. However, the uncertainty associated with the determined SWCC is rarely considered in the estimation of the shear strength. In this paper, the uncertainties of SWCC resulted from different factors are reviewed and discussed. The variability of the estimated shear strength for the unsaturated soil due to the uncertainty of SWCC associated with the best fit process is quantified by using the upper and lower bounds of the determined SWCC. On the other hand, the uncertainties of the estimated shear strength due to different initial void ratios or different confining pressures are quantified by adopting different SWCCs. As a result, it is recommended that the measured SWCC from the conventional Tempe cell or pressure plate needs to be corrected by considering different stress levels in the estimation of the shear strength of unsaturated soil.
基金supported by the National Natural Science Foundation of China(Grant Nos.41074102 and 41130417)"111 Program"(Grant No.B13010)Program for Changjiang Scholars and Innovative Research Team in University
文摘Internal magnetic gradient plays a significant role in Nuclear Magnetic Resonance(NMR)measurements of fluid saturated porous media.The quantitative characterization and application of this physical phenomenon could effectively improve the accuracy of NMR measurements and interpretations.In this paper,by using the equivalent magnetic dipole method,the three-dimensional distribution of internal induced magnetic field and its gradients in the randomly packed water saturated glass beads are quantitatively characterized.By simulating the diffusive motion of water molecules in porous media with random walk method,the computational dephasing effects equation related to internal gradients is deduced.Thereafter,the echo amplitudes are obtained and the corresponding T2-G spectrum is also inverted.For the sake of verifying the simulation results,an experiment is carried out using the Halbach core analyzing system(B0=0.18 T,G=2.3 T/m)to detect the induced internal field and gradients.The simulation results indicate the equivalent internal gradient is a distribution of 0.1-0.3 T/m,which matched well with the experimental results.
基金supported by the National Natural Science Foundation of China (51271097)
文摘It was well known that it was very difficult to prepare high performance Fe-based bulk amorphous alloys with both high Fe content and good glass-forming ability, especially for the Fe content (or total magnetic elements content) higher than 80 at%. In this paper, a series of Fe81-xCoxMO1P7.5C5.5B2Si3 (x = 0, 5, 10, 15, 20) bulk amorphous alloys (BAAs) with high saturation magnetization have been developed by copper mold casting method with fluxed ingot. It has been found that using Co replacing Fe in the Fe-Mo-P-C-B-Si alloy could significantly enhance the glass-forming ability and magnetic property. For the BAA with Co content of 0 at%, 5 at%, 10 at%, 15 at% and 20 at%, its saturation magnetization Js(Js=μoMs) was 1.55, 1.60, 1.62, 1.65 and 1.59 T, respectively. Among these alloys, the Fe66Co15- Mo1P7.5C5.5B2Si3 BAA exhibited a critical size of 2 mm in diameter and a high Js of 1.65 T. It suggested that these alloys with high magnetic element content possessed great potential in application due to their high glass-forming ability and high magnetic property.
基金Supported by the National Natural Science Foundation of China under Grant Nos.11472278 and 11372330the Scientific Research Foundation of Education Department of Sichuan Province under Grant No.15ZA0296+1 种基金the Scientific Research Foundation of Mianyang Normal University under Grant Nos.QD2014A009 and 2014A02the National High-Tech ICF Committee
文摘The classical planar Richtmyer–Meshkov instability(RMI) at a fluid interface supported by a constant pressure is investigated by a formal perturbation expansion up to the third order,and then according to definition of nonlinear saturation amplitude(NSA) in Rayleigh–Taylor instability(RTI),the NSA in planar RMI is obtained explicitly.It is found that the NSA in planar RMI is affected by the initial perturbation wavelength and the initial amplitude of the interface,while the effect of the initial amplitude of the interface on the NSA is less than that of the initial perturbation wavelength.Without marginal influence of the initial amplitude,the NSA increases linearly with wavelength.The NSA normalized by the wavelength in planar RMI is about 0.11,larger than that corresponding to RTI.
基金supported by the National Natural Science Foundation of China (11434006, 11774199, and 51871112)the National Basic Research Program of China (2015CB921502)+1 种基金the 111 Project B13029supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Contract No. DEAC02-76SF00515。
文摘Material functionalities strongly depend on the stoichiometry,crystal structure,and homogeneity.Here we demonstrate an approach of amorphous nonstoichiometric inhomogeneous oxides to realize tunable ferromagnetism and electrical transport at room temperature.In order to verify the origin of the ferromagnetism,we employed a series of structural,chemical,and electronic state characterizations.Combined with electron microscopy and transport measurements,synchrotron-based grazing incident wide angle X-ray scattering,soft X-ray absorption and circular dichroism clearly reveal that the roomtemperature ferromagnetism originates from the In0.23Co0.77O1-v,amorphous phase with a large tunable range of oxygen vacancies.The room-temperature ferromagnetism is tunable from a high saturation magnetization of 500 emu cm-3 to below 25 emu cm-3,with the evolving electrical resistivity from5×103μΩ cm to above 2.5×105 μΩ cm.Inhomogeneous nano-crystallization emerges with decreasing oxygen vacancies,driving the system towards non-ferromagnetism and insulating regime.Our work unfolds the novel functionalities of amorphous nonstoichiometric inhomogeneous oxides,which opens up new opportunities for developing spintronic materials with superior magnetic and transport properties.