The non-isothermal heating process of Mg-Sn powder mixture was studied by differential scanning calorimetry(DSC) technique and the synthesis kinetics of Mg2Sn was evaluated by the model-free and model-fitting methods....The non-isothermal heating process of Mg-Sn powder mixture was studied by differential scanning calorimetry(DSC) technique and the synthesis kinetics of Mg2Sn was evaluated by the model-free and model-fitting methods.The activation energy and conversion function of Mg2Sn synthesis reaction are calculated to be 281.7 kJ/mol and g(α)=[-ln(1-α)] 1/4,respectively.The reaction mechanism of 2Mg+Sn→Mg2Sn under non-isothermal condition is regarded as "nucleation and growth" .During the non-isothermal heating process,the phase transformation occurred in the Mg-Sn powder mixture was analyzed by XRD and the microstructure evolution of Mg2Sn was observed by optical microscopy,which is in good agreement with the reaction mechanism of 2Mg+Sn→ Mg2Sn deduced from the kinetic evaluation.展开更多
Through simulating one-and two-dimensional non-Fourier heat conduction problems under different pulsed inlet conditions, this paper numerically predicts some different non-Fourier heat conduction characters arose from...Through simulating one-and two-dimensional non-Fourier heat conduction problems under different pulsed inlet conditions, this paper numerically predicts some different non-Fourier heat conduction characters arose from different pulse types and different pulse frequencies. Meanwhile, the differences among thermal wave, non-Fourier and Fourier heat conduction are also showed.展开更多
基金Project(2007CB613706)supported by the National Basic Research Program of ChinaProject(0330005412901)supported the Key Disciplines Development of Beijing Municipality("Resources,Environment and Recycling Economy"Interdisciplinary),ChinaProject(X0104001200905)supported by the Scientific Research Foundation for the New Doctoral Teachers,Beijing University of Technology,China
文摘The non-isothermal heating process of Mg-Sn powder mixture was studied by differential scanning calorimetry(DSC) technique and the synthesis kinetics of Mg2Sn was evaluated by the model-free and model-fitting methods.The activation energy and conversion function of Mg2Sn synthesis reaction are calculated to be 281.7 kJ/mol and g(α)=[-ln(1-α)] 1/4,respectively.The reaction mechanism of 2Mg+Sn→Mg2Sn under non-isothermal condition is regarded as "nucleation and growth" .During the non-isothermal heating process,the phase transformation occurred in the Mg-Sn powder mixture was analyzed by XRD and the microstructure evolution of Mg2Sn was observed by optical microscopy,which is in good agreement with the reaction mechanism of 2Mg+Sn→ Mg2Sn deduced from the kinetic evaluation.
文摘Through simulating one-and two-dimensional non-Fourier heat conduction problems under different pulsed inlet conditions, this paper numerically predicts some different non-Fourier heat conduction characters arose from different pulse types and different pulse frequencies. Meanwhile, the differences among thermal wave, non-Fourier and Fourier heat conduction are also showed.
