Density functional theory calculations corrected by on-site Coulomb interactions were carried out o study the structures of polar CeO2 （100） surfaces as well as activities during catalytic CO oxidation. The stabilit...Density functional theory calculations corrected by on-site Coulomb interactions were carried out o study the structures of polar CeO2 （100） surfaces as well as activities during catalytic CO oxidation. The stabilities of various CeO2 （100） termination structures are discussed, and calculated energetics are presented. The most stable Ce〇2 （100） surface was obtained by removing half the outermost full layer of oxygen and the surface stability was found to decrease as the exposed oxygen concentration was increased. Assessing the reaction pathways leading to different final products during CO oxidation over the most stable CeO2 （100） surface, we determined that the formation of carbonate species competed with CO2 desorption. However, during CO oxidation on the less stable CeO2 （100） surfaces having more exposed oxygen, the CO is evidently able to react with surface oxygen, leading to CO2 formation and desorption. The calculation results and electronic analyses reported herein also indicate that the characteristic Ce 4/ orbitals are directly involved in deter-mining the surface stabilities and reactivities.展开更多
Based on seismic wave records of the Chengdu digital seismic network and Zipingpu reservoir digital seismic network from August 16,2004 to May 12,2008 when the Wenchuan MS8.0 earthquake occurred,the parameters of foca...Based on seismic wave records of the Chengdu digital seismic network and Zipingpu reservoir digital seismic network from August 16,2004 to May 12,2008 when the Wenchuan MS8.0 earthquake occurred,the parameters of focal mechanisms of 486 earthquakes with magnitude larger than M1.6 in the Zipingpu reservoir area were calculated using amplitude ratio method,meanwhile the temporal-spatial variation characteristics of mechanisms and stress field were analyzed based on these parameters.Results show a low ratio of thrust earthquakes and an increased number of strike-slip earthquakes in the reservoir water area in the period from 2006 to 2008.While in the areas far from the reservoir waterfront,the thrust earthquakes took up a high proportion and the strike-slip ones did not increase.The direction of mean principal compressive stress field was deflected and disturbed differently in each area before the Wenchuan MS8.0 earthquake.展开更多
In this paper, we construct two models for the searching task for a lost plane. Model 1 determines the searching area. We predict the trajectory of floats generated after the disintegration of the plane by using RBF n...In this paper, we construct two models for the searching task for a lost plane. Model 1 determines the searching area. We predict the trajectory of floats generated after the disintegration of the plane by using RBF neural network model, and then determine the searching area according to the trajectory. With the pass of time, the searching area will also be constantly moving along the trajectory. Model 2 develops a maritime search plan to achieve the purpose of completing the search in the shortest time. We optimize the searching time and transform the problem into the 0-1 knapsack problem. Solving this problem by improved genetic algorithm, we can get the shortest searching time and the best choice for the search power.展开更多
Au nanoparticles have been used in biomedical applications since ancient times. However, the rapid development of nanotechnology over the past century has led to recognition of the great potential of Au nanoparticles ...Au nanoparticles have been used in biomedical applications since ancient times. However, the rapid development of nanotechnology over the past century has led to recognition of the great potential of Au nanoparticles in a wide range of applications. Advanced fabrication techniques allow us to synthesize a variety of Au nanostructures possessing physiochemical properties that can be exploited for different purposes. Functionalization of the surface of Au nanoparticles further eases their application in various roles. These advantages of Au nanoparticles make them particularly suited for cancer treatment and diagnosis. The small size of Au particles enables them to preferentially accumulate at tumor sites to achieve in vivo targeting after systemic administration. Efficient light absorption followed by rapid heat conversion makes them very promising in photothermal therapy. The facile surface chemistry of Au nanoparticles eases delivery of drugs, ligands or imaging contrast agents in vivo. In this review, we summarize recent development of Au nanoparticles in cancer theranostics including imaging-based detection, photothermal therapy, chemical therapy and drug delivery. The multifunctional nature of Au nanoparticles means they hold great promise as novel anti-cancer therapeutics.展开更多
Ferromagnetic quantum critical points were predicted to be prohibited in clean itinerant ferromagnetic systems,yet such a phenomenon was recently revealed in CeRh_(6)Ge_(4),where the Curie temperature can be continuou...Ferromagnetic quantum critical points were predicted to be prohibited in clean itinerant ferromagnetic systems,yet such a phenomenon was recently revealed in CeRh_(6)Ge_(4),where the Curie temperature can be continuously suppressed to zero under a moderate hydrostatic pressure.Here we report the observation of quantum oscillations in CeRh_(6)Ge_(4)from measurements using the cantilever and tunnel-diode oscillator methods in fields up to 45 T,clearly demonstrating that the ferromagnetic quantum criticality occurs in a clean system.In order to map the Fermi surface of CeRh_(6)Ge_(4),we performed angle-dependent measurements of quantum oscillations at ambient pressure,and compared the results to density functional theory calculations.The results are consistent with the Ce 4f electrons remaining localized and not contributing to the Fermi surface,suggesting that localized ferromagnetism is a key factor for the occurrence of a ferromagnetic quantum critical point in CeRh_(6)Ge_(4).展开更多
Noble metals are downsized to nano-/subnanoscale to improve their catalytic activity and atom-economy.However,the stabilities in chemical state and catalytic performance of these nanocatalysts often suffer during hars...Noble metals are downsized to nano-/subnanoscale to improve their catalytic activity and atom-economy.However,the stabilities in chemical state and catalytic performance of these nanocatalysts often suffer during harsh conditions.For Pt nanoparticles(NPs)supported on CeO2,activated oxygen diffused from the support over-stabilizes the active sites of Pt,degrading its performance at mild temperature.In this work,Pt nanocatalysts with unique structure of triple-junction are synthesized by selectively growing Pt NPs on the carbon-CeO2 interface.Impressively,the Pt NPs exhibit much enhanced catalytic stability and high activity for CO oxidation at mild temperature.The enhancement is attributed to electron donation from graphitized carbon and the confinement effect from the high-density nanopores of the CeO2 support.The triple-junction of Pt-C-CeO2,combining the merits of CeO2 for activating O2 and electron donating capability of carbon,provides new inspiration to the fabrication of high-performance nanocatalysts.展开更多
基金supported the National Natural Science Foundation of China(21421004,21573067)~~
文摘Density functional theory calculations corrected by on-site Coulomb interactions were carried out o study the structures of polar CeO2 （100） surfaces as well as activities during catalytic CO oxidation. The stabilities of various CeO2 （100） termination structures are discussed, and calculated energetics are presented. The most stable Ce〇2 （100） surface was obtained by removing half the outermost full layer of oxygen and the surface stability was found to decrease as the exposed oxygen concentration was increased. Assessing the reaction pathways leading to different final products during CO oxidation over the most stable CeO2 （100） surface, we determined that the formation of carbonate species competed with CO2 desorption. However, during CO oxidation on the less stable CeO2 （100） surfaces having more exposed oxygen, the CO is evidently able to react with surface oxygen, leading to CO2 formation and desorption. The calculation results and electronic analyses reported herein also indicate that the characteristic Ce 4/ orbitals are directly involved in deter-mining the surface stabilities and reactivities.
基金sponsored by the National Key Technology R&D Program on Reservoir Earthquake Monitoring and Prediction Technique(2008BAC38B03-0202),China
文摘Based on seismic wave records of the Chengdu digital seismic network and Zipingpu reservoir digital seismic network from August 16,2004 to May 12,2008 when the Wenchuan MS8.0 earthquake occurred,the parameters of focal mechanisms of 486 earthquakes with magnitude larger than M1.6 in the Zipingpu reservoir area were calculated using amplitude ratio method,meanwhile the temporal-spatial variation characteristics of mechanisms and stress field were analyzed based on these parameters.Results show a low ratio of thrust earthquakes and an increased number of strike-slip earthquakes in the reservoir water area in the period from 2006 to 2008.While in the areas far from the reservoir waterfront,the thrust earthquakes took up a high proportion and the strike-slip ones did not increase.The direction of mean principal compressive stress field was deflected and disturbed differently in each area before the Wenchuan MS8.0 earthquake.
文摘In this paper, we construct two models for the searching task for a lost plane. Model 1 determines the searching area. We predict the trajectory of floats generated after the disintegration of the plane by using RBF neural network model, and then determine the searching area according to the trajectory. With the pass of time, the searching area will also be constantly moving along the trajectory. Model 2 develops a maritime search plan to achieve the purpose of completing the search in the shortest time. We optimize the searching time and transform the problem into the 0-1 knapsack problem. Solving this problem by improved genetic algorithm, we can get the shortest searching time and the best choice for the search power.
基金supported by the National Basic Research Program of China(Grant Nos.2011CB933401 and 2012CB934003)the National Natural Science Foundation of China(Grant No.31070854)National Major Scientific Instruments Development Project(Grant No.2011YQ03013406)
文摘Au nanoparticles have been used in biomedical applications since ancient times. However, the rapid development of nanotechnology over the past century has led to recognition of the great potential of Au nanoparticles in a wide range of applications. Advanced fabrication techniques allow us to synthesize a variety of Au nanostructures possessing physiochemical properties that can be exploited for different purposes. Functionalization of the surface of Au nanoparticles further eases their application in various roles. These advantages of Au nanoparticles make them particularly suited for cancer treatment and diagnosis. The small size of Au particles enables them to preferentially accumulate at tumor sites to achieve in vivo targeting after systemic administration. Efficient light absorption followed by rapid heat conversion makes them very promising in photothermal therapy. The facile surface chemistry of Au nanoparticles eases delivery of drugs, ligands or imaging contrast agents in vivo. In this review, we summarize recent development of Au nanoparticles in cancer theranostics including imaging-based detection, photothermal therapy, chemical therapy and drug delivery. The multifunctional nature of Au nanoparticles means they hold great promise as novel anti-cancer therapeutics.
基金the National Key R&D Program of China(2017YFA0303100,and 2016YFA0300202)the National Natural Science Foundation of China(12034017,U1632275,and 11974306)+2 种基金the Science Challenge Project of China(TZ2016004)the Key R&D Program of Zhejiang Province(2021C01002)supported by the National Science Foundation Cooperative Agreement No.DMR-1644779 and the State of Florida。
文摘Ferromagnetic quantum critical points were predicted to be prohibited in clean itinerant ferromagnetic systems,yet such a phenomenon was recently revealed in CeRh_(6)Ge_(4),where the Curie temperature can be continuously suppressed to zero under a moderate hydrostatic pressure.Here we report the observation of quantum oscillations in CeRh_(6)Ge_(4)from measurements using the cantilever and tunnel-diode oscillator methods in fields up to 45 T,clearly demonstrating that the ferromagnetic quantum criticality occurs in a clean system.In order to map the Fermi surface of CeRh_(6)Ge_(4),we performed angle-dependent measurements of quantum oscillations at ambient pressure,and compared the results to density functional theory calculations.The results are consistent with the Ce 4f electrons remaining localized and not contributing to the Fermi surface,suggesting that localized ferromagnetism is a key factor for the occurrence of a ferromagnetic quantum critical point in CeRh_(6)Ge_(4).
基金supported by the National Key Research and Development Program of China(2016YFB0701100)the National Natural Science Foundation of China(51771047,51525101 and 51971059)the Fundamental Research Funds for the Central Universities(N180204014)。
文摘Noble metals are downsized to nano-/subnanoscale to improve their catalytic activity and atom-economy.However,the stabilities in chemical state and catalytic performance of these nanocatalysts often suffer during harsh conditions.For Pt nanoparticles(NPs)supported on CeO2,activated oxygen diffused from the support over-stabilizes the active sites of Pt,degrading its performance at mild temperature.In this work,Pt nanocatalysts with unique structure of triple-junction are synthesized by selectively growing Pt NPs on the carbon-CeO2 interface.Impressively,the Pt NPs exhibit much enhanced catalytic stability and high activity for CO oxidation at mild temperature.The enhancement is attributed to electron donation from graphitized carbon and the confinement effect from the high-density nanopores of the CeO2 support.The triple-junction of Pt-C-CeO2,combining the merits of CeO2 for activating O2 and electron donating capability of carbon,provides new inspiration to the fabrication of high-performance nanocatalysts.
