Low pore sedimentary rocks(from Guangxi, China) were subjected to uniaxial compression loading experiment under different initial stresses. The rock samples were investigated by nuclear magnetic resonance before and a...Low pore sedimentary rocks(from Guangxi, China) were subjected to uniaxial compression loading experiment under different initial stresses. The rock samples were investigated by nuclear magnetic resonance before and after the loading. The relationships between the mesoscopic rock damage and macroscopic mechanical parameters were established, and the initial damage stress of the low-porosity sedimentary rock was determined. The results showed that this type of rock has the initial stress of damage. When the initial loading stress is lower than the initial stress of damage, the T2 spectrum area of the rock sample gradually decreases, and the primary pores of the rock are further closed under the stress. The range of the initial stress of damage for this type of rock is 8-16 MPa. When the loading stress exceeds the initial stress of damage, the T2 spectrum area gradually increases, indicating that the porosity of the rock increases and microscopic damage of the rock appears. The rock damage degree is defined, and the nonlinear function between the rock damage degree and the initial loading stress is established.展开更多
Soils in the Knersvlakte are particularly prone to crusting and have lower inherent infiltrability than other soils across western southern Africa. Micromorphological techniques were used to examine the structure and ...Soils in the Knersvlakte are particularly prone to crusting and have lower inherent infiltrability than other soils across western southern Africa. Micromorphological techniques were used to examine the structure and porosity of soil crusts in the Knersvlakte to ascertain why crusting is so intense in this region. Quantile regression using boundary lines was employed to examine the relationships between infiltrability and soil properties for all samples (n = 67). This analysis showed that infiltrability is potentially maximal at low water- dispersible 'clay plus silt' content and low silt content (r^2 = 0.72 and 0.64; respectively, n = 67) (Figure 2). The strength of crusts, pH, EC, clay mineralogy, and water-dispersible clay, silt and 'clay plus silt' content were compared, and a pore analysis using optical microscopy was undertaken on images of six soil thin sections (n = 6) (circular and parallel polarizers). Pore analysis was further undertaken on five horizontal slices of equal dimensions taken through each soil thin section. The porosity samples with low infiltrability (〈 100 mm·hr^-1, n = 4) had greater crust strength, lower porosity (both total and in the least porous slice) and greater water-dispersible 'day plus silt' and silt content than the porosity samples with high infiltrability (〉 100mm·hr^-1, n = 2). The porosity samples with low infiltrability showed a trend of lower pH and greater water dispersible clay percentage. Porosity varied within the porosity samples due to the presence of dense clay/silt bands (〈 0.5 mm in width) with relatively few air vesicles. The porosity samples with horizontal slices of low porosity (but large numbers of air vesicles) had low infiltrability, while those without slices of low porosity (and relatively few air vesicles) had high infiltrability. We conclude that the intense crusting and resultant low infiltrability of soils in the Knersvlakte appears to be related to the formation of thin, dense clay/silt bands in the pedoderm.展开更多
The spatial structure characteristics of landform are the foundation of geomorphologic classification and recognition.This paper proposed a new method on quantifying spatial structure characteristics of terrain surfac...The spatial structure characteristics of landform are the foundation of geomorphologic classification and recognition.This paper proposed a new method on quantifying spatial structure characteristics of terrain surface based on improved 3D Lacunarity model.Lacunarity curve and its numerical integration are used in this model to improve traditional classification result that different morphological types may share the close value of indexes based on global statistical analysis.Experiments at four test areas with different landform types show that improved 3D Lacunarity model can effectively distinguish different morphological types per texture analysis.Higher sensitivity in distinguishing the tiny differences of texture characteristics of terrain surface shows that the quantification method by 3D Lacu-narity model and its numerical integration presented in this paper could contribute to improving the accuracy of land-form classifications and relative studies.展开更多
The issue of the building materials biocorrosion has a significant economic dimension because it results in the costly repair. The start and the course of corrosion are conditioned by many factors which undoubtedly in...The issue of the building materials biocorrosion has a significant economic dimension because it results in the costly repair. The start and the course of corrosion are conditioned by many factors which undoubtedly include biological effects like the influence of vegetation and microorganisms causing the so called microbial corrosion. Microorganisms have also a considerable share in the decay and degradation of different building materials. The activity of sulphuratum is the keystone of many processes in nature and in industry. The sulphuric bacteria oxidize hydrogen sulphide produced by sulphate-reducing bacteria into sulphuric acid resulting in the acid or sulphate corrosion of cement stone. The paper is aimed on evaluation of porosity and roughness of concrete samples surface as elementary characteristics of microbial corrosion. After 4 months exposure to the real conditions in sewers deposition the changes were observed by confocal laser microscopy and consequently analyzed and interpreted.展开更多
Polyethersulfone(PES)film with regular microporous structure was formed using dichloromethane as the solvent via water vapor induced phase separation(VIPS).The effects of solution concentration,atmospheric humidity an...Polyethersulfone(PES)film with regular microporous structure was formed using dichloromethane as the solvent via water vapor induced phase separation(VIPS).The effects of solution concentration,atmospheric humidity and temperature,as well as molecular weight of PES on the surface morphology of the polymer film were investigated.The surface morphology characterized by SEM showed that the pore size reduced as the solution concentration increased.There was an optimum range of relative humidity for the formation of regular pore structure, which was from 60%to 90%at concentration of 20 g·L-1 and 20°C.With the atmospheric temperature varied from 20 to 30°C,the pore became larger and the space between pores increased.The pore size in the PES film with low molecular weight was smaller than that with high molecular weight.展开更多
On the basis of upper bound theorem, non-associated flow rule and non-linear failure criterion were considered together.The modified shear strength parameters of materials were obtained with the help of the tangent me...On the basis of upper bound theorem, non-associated flow rule and non-linear failure criterion were considered together.The modified shear strength parameters of materials were obtained with the help of the tangent method. Employing the virtual power principle and strength reduction technique, the effects of dilatancy of materials, non-linear failure criterion, pore water pressure,surface loads and buried depth, on the stability of shallow tunnel were studied. In order to validate the effectiveness of the proposed approach, the solutions in the present work agree well with the existing results when the non-associated flow rule is reduced to the associated flow rule and the non-linear failure criterion is degenerated to the linear failure criterion. Compared with dilatancy of materials, the non-linear failure criterion exerts greater impact on the stability of shallow tunnels. The safety factor of shallow tunnels decreases and the failure surface expands outward when the dilatancy coefficient decreases. While the increase of nonlinear coefficient, the pore water pressure coefficient, the surface load and the buried depth results in the small safety factor. Therefore, the dilatancy as well as non-linear failure criterion should be taken into account in the design of shallow tunnel supporting structure. The supporting structure must be reinforced promptly to prevent potential mud from gushing or collapse accident in the areas with abundant pore water, large surface load or buried depth.展开更多
Saline aquifers are chosen for geological storage of greenhouse gas CO_2 because of their storage potential.In almost all cases of practical interest,CO_2 is present on top of the liquid and CO_2 dissolution leads to ...Saline aquifers are chosen for geological storage of greenhouse gas CO_2 because of their storage potential.In almost all cases of practical interest,CO_2 is present on top of the liquid and CO_2 dissolution leads to a small increase in the density of the aqueous phase.This situation results in the creation of negative buoyancy force for downward density-driven natural convection and consequently enhances CO_2 sequestration.In order to study CO_2 injection at pore-level,an isothermal Lattice Boltzmann Model(LBM) with two distribution functions is adopted to simulate density-driven natural convection in porous media with irregular geometry obtained by image treatment.The present analysis showed that after the onset of natural convection instability,the brine with a high CO_2 concentration infringed into the underlying unaffected brine,in favor of the migration of CO_2 into the pore structure.With low Rayleigh numbers,the instantaneous mass flux and total dissolved CO_2 mass are very close to that derived from penetration theory(diffusion only),but the fluxes are significantly enhanced with high Ra number.The simulated results show that as the time increases,some chaotic and recirculation zones in the flow appear obviously,which promotes the renewal of interfacial liquid,and hence enhances dissolution of CO_2 into brine.This study is focused on the scale of a few pores,but shows implications in enhanced oil/gas recovery with CO_2 sequestration in aquifers.展开更多
基金Project(41672298)supported by the National Natural Science Foundation of China。
文摘Low pore sedimentary rocks(from Guangxi, China) were subjected to uniaxial compression loading experiment under different initial stresses. The rock samples were investigated by nuclear magnetic resonance before and after the loading. The relationships between the mesoscopic rock damage and macroscopic mechanical parameters were established, and the initial damage stress of the low-porosity sedimentary rock was determined. The results showed that this type of rock has the initial stress of damage. When the initial loading stress is lower than the initial stress of damage, the T2 spectrum area of the rock sample gradually decreases, and the primary pores of the rock are further closed under the stress. The range of the initial stress of damage for this type of rock is 8-16 MPa. When the loading stress exceeds the initial stress of damage, the T2 spectrum area gradually increases, indicating that the porosity of the rock increases and microscopic damage of the rock appears. The rock damage degree is defined, and the nonlinear function between the rock damage degree and the initial loading stress is established.
基金BIOTA Southern Africa (sponsored by the German Federal Ministry of Education and Research under promotion number 01 LC 0024A)the South African government (National Research Foundation, Mobility and Training Grant 2005/ GUN No: 2072287/ PUN No: 212778) for financial support
文摘Soils in the Knersvlakte are particularly prone to crusting and have lower inherent infiltrability than other soils across western southern Africa. Micromorphological techniques were used to examine the structure and porosity of soil crusts in the Knersvlakte to ascertain why crusting is so intense in this region. Quantile regression using boundary lines was employed to examine the relationships between infiltrability and soil properties for all samples (n = 67). This analysis showed that infiltrability is potentially maximal at low water- dispersible 'clay plus silt' content and low silt content (r^2 = 0.72 and 0.64; respectively, n = 67) (Figure 2). The strength of crusts, pH, EC, clay mineralogy, and water-dispersible clay, silt and 'clay plus silt' content were compared, and a pore analysis using optical microscopy was undertaken on images of six soil thin sections (n = 6) (circular and parallel polarizers). Pore analysis was further undertaken on five horizontal slices of equal dimensions taken through each soil thin section. The porosity samples with low infiltrability (〈 100 mm·hr^-1, n = 4) had greater crust strength, lower porosity (both total and in the least porous slice) and greater water-dispersible 'day plus silt' and silt content than the porosity samples with high infiltrability (〉 100mm·hr^-1, n = 2). The porosity samples with low infiltrability showed a trend of lower pH and greater water dispersible clay percentage. Porosity varied within the porosity samples due to the presence of dense clay/silt bands (〈 0.5 mm in width) with relatively few air vesicles. The porosity samples with horizontal slices of low porosity (but large numbers of air vesicles) had low infiltrability, while those without slices of low porosity (and relatively few air vesicles) had high infiltrability. We conclude that the intense crusting and resultant low infiltrability of soils in the Knersvlakte appears to be related to the formation of thin, dense clay/silt bands in the pedoderm.
基金Under the auspices of National Natural Science Foundation of China (No.40930531,41171320,41001301)
文摘The spatial structure characteristics of landform are the foundation of geomorphologic classification and recognition.This paper proposed a new method on quantifying spatial structure characteristics of terrain surface based on improved 3D Lacunarity model.Lacunarity curve and its numerical integration are used in this model to improve traditional classification result that different morphological types may share the close value of indexes based on global statistical analysis.Experiments at four test areas with different landform types show that improved 3D Lacunarity model can effectively distinguish different morphological types per texture analysis.Higher sensitivity in distinguishing the tiny differences of texture characteristics of terrain surface shows that the quantification method by 3D Lacu-narity model and its numerical integration presented in this paper could contribute to improving the accuracy of land-form classifications and relative studies.
文摘The issue of the building materials biocorrosion has a significant economic dimension because it results in the costly repair. The start and the course of corrosion are conditioned by many factors which undoubtedly include biological effects like the influence of vegetation and microorganisms causing the so called microbial corrosion. Microorganisms have also a considerable share in the decay and degradation of different building materials. The activity of sulphuratum is the keystone of many processes in nature and in industry. The sulphuric bacteria oxidize hydrogen sulphide produced by sulphate-reducing bacteria into sulphuric acid resulting in the acid or sulphate corrosion of cement stone. The paper is aimed on evaluation of porosity and roughness of concrete samples surface as elementary characteristics of microbial corrosion. After 4 months exposure to the real conditions in sewers deposition the changes were observed by confocal laser microscopy and consequently analyzed and interpreted.
基金Supported by the National Natural Science Foundation of China (20676015, 20806009), and the Specialized Research Fund for the Doctoral Program of Higher Education of China (20070007055).
文摘Polyethersulfone(PES)film with regular microporous structure was formed using dichloromethane as the solvent via water vapor induced phase separation(VIPS).The effects of solution concentration,atmospheric humidity and temperature,as well as molecular weight of PES on the surface morphology of the polymer film were investigated.The surface morphology characterized by SEM showed that the pore size reduced as the solution concentration increased.There was an optimum range of relative humidity for the formation of regular pore structure, which was from 60%to 90%at concentration of 20 g·L-1 and 20°C.With the atmospheric temperature varied from 20 to 30°C,the pore became larger and the space between pores increased.The pore size in the PES film with low molecular weight was smaller than that with high molecular weight.
基金Project(2013CB036004) supported by the National Basic Research Program of ChinaProjects(51178468,51378510) supported by the National Natural Science Foundation of ChinaProject(CX2013B077) supported by Hunan Provincial Innovation Foundation for Postgraduate,China
文摘On the basis of upper bound theorem, non-associated flow rule and non-linear failure criterion were considered together.The modified shear strength parameters of materials were obtained with the help of the tangent method. Employing the virtual power principle and strength reduction technique, the effects of dilatancy of materials, non-linear failure criterion, pore water pressure,surface loads and buried depth, on the stability of shallow tunnel were studied. In order to validate the effectiveness of the proposed approach, the solutions in the present work agree well with the existing results when the non-associated flow rule is reduced to the associated flow rule and the non-linear failure criterion is degenerated to the linear failure criterion. Compared with dilatancy of materials, the non-linear failure criterion exerts greater impact on the stability of shallow tunnels. The safety factor of shallow tunnels decreases and the failure surface expands outward when the dilatancy coefficient decreases. While the increase of nonlinear coefficient, the pore water pressure coefficient, the surface load and the buried depth results in the small safety factor. Therefore, the dilatancy as well as non-linear failure criterion should be taken into account in the design of shallow tunnel supporting structure. The supporting structure must be reinforced promptly to prevent potential mud from gushing or collapse accident in the areas with abundant pore water, large surface load or buried depth.
文摘Saline aquifers are chosen for geological storage of greenhouse gas CO_2 because of their storage potential.In almost all cases of practical interest,CO_2 is present on top of the liquid and CO_2 dissolution leads to a small increase in the density of the aqueous phase.This situation results in the creation of negative buoyancy force for downward density-driven natural convection and consequently enhances CO_2 sequestration.In order to study CO_2 injection at pore-level,an isothermal Lattice Boltzmann Model(LBM) with two distribution functions is adopted to simulate density-driven natural convection in porous media with irregular geometry obtained by image treatment.The present analysis showed that after the onset of natural convection instability,the brine with a high CO_2 concentration infringed into the underlying unaffected brine,in favor of the migration of CO_2 into the pore structure.With low Rayleigh numbers,the instantaneous mass flux and total dissolved CO_2 mass are very close to that derived from penetration theory(diffusion only),but the fluxes are significantly enhanced with high Ra number.The simulated results show that as the time increases,some chaotic and recirculation zones in the flow appear obviously,which promotes the renewal of interfacial liquid,and hence enhances dissolution of CO_2 into brine.This study is focused on the scale of a few pores,but shows implications in enhanced oil/gas recovery with CO_2 sequestration in aquifers.