岩石变形中三种方式的外力

外力是由外部施加于物体上的作用力,由点向外不断发出的力组成一束力,称为线状力;由一束束线状力集中成面状作用力,称为面状力;再由一个个面状力集中成较大规模的力,称为体状力。在中深变质岩区线状力形成L构造岩,面状力形成S构造岩,体状力形成大型的杆状构造和窗棱构造等。力是通过波的方式进行传导的,波分纵波和横波。纵波传播时,岩石的密度会加密和变疏,体积的大小发生变化,这样就有空间利于矿物生长和滑移。

Growth kinetics for intermetallic compound layer between molten In-Sn alloy and CuZr-based bulk metallic glass

The growth kinetics of intermetallic compound layer between molten In-Sn alloy and Cu40Zr44Al8Ag8 bulk metallic glass substrate was examined by solid state isothermal aging at the temperature range between 333 and 393 K.The aged samples were characterized by scanning electron microscopy and energy dispersive spectrometry.It is found that the intermetallic compound layer is composed of Zr,Cu and Sn.The layer growth of the intermetallic compound is mainly controlled by a diffusion mechanism over the temperature range and the value of the time exponent is approximately 0.5.The apparent activation energy for the growth of total intermetallic compound layers is 98.35 kJ /mol calculated by the Arrhenius equation.

Stress analytical solution for plane problem of a double-layered thick-walled cylinder subjected to a type of non-uniform distributed pressure

The stress state around circular openings,such as boreholes,shafts,and tunnels,is usually needed to be evaluated.Solutions for stresses,strains and ultimate bearing capacities of pressurized hollow cylinder are common cases.Stress analytical method for plane problem of a double-layered thick-walled cylinder subjected to a type of non-uniform pressure on the outer surface and uniform radial pressure on the inner surface is given.The power series method of complex function is used.The stress analytical solution is obtained with the assumption that two layers of a cylinder are fully contacted.The distributions of normal and tangential contact stress along the interface,tangential stress on the inner boundary and stresses in the radial direction at θ=0°,45° and 90°,are obtained.An example indicates that,when the elastic modulus of the inner layer of a double-layered thick-walled cylinder is smaller than that of the outer layer,the tangential stress is smaller than that in the corresponding point for a traditional cylinder composed of homogeneous materials.In that way,stress concentration at the inner surface can be alleviated and the stress distribution is more uniform.This is a capable way to enhance the elastic ultimate bearing capacity of thick-walled cylinder.

An automatic grid generation approach over free-form surface for architectural design

An essential step for the realization of free-form surface structures is to create an efficient structural gird that satisfies not only the architectural aesthetics,but also the structural performance.Employing the main stress trajectories as the representation of force flows on a free-form surface,an automatic grid generation approach is proposed for the architectural design.The algorithm automatically plots the main stress trajectories on a 3D free-form surface,and adopts a modified advancing front meshing technique to generate the structural grid.Based on the proposed algorithm,an automatic grid generator named "St-Surmesh" is developed for the practical architectural design of free-form surface structure.The surface geometry of one of the Sun Valleys in Expo Axis for the Expo Shanghai 2010 is selected as a numerical example for validating the proposed approach.Comparative studies are performed to demonstrate how different structural grids affect the design of a free-form surface structure.

Preparation and shape memory properties of TiO_2/PLCL biodegradable polymer nanocomposites

The preparation of TiO2/poly（L-lactide-co-ε-caprolactone）（PLCL） nanocomposites and their properties were reported.TiO2nanoparticles were surface modified by ring-opening polymerization of ε-caprolactone（ε-CL）.The resulting poly（ε-caprolactone）-grafted TiO2（g-TiO2） was characterized by Fourier transform infrared spectroscopy（FTIR）,thermogravimetric analysis（TGA） and transmission electron microscopy（TEM）.The g-TiO2can be uniformly dispersed in chloroform and the g-TiO2/PLCL nanocomposites were successfully fabricated through solvent-casting method.The effects of the content of g-TiO2nanoparticles on tensile properties and shape memory properties were investigated.A significant improvement in the tensile properties of the 5% g-TiO2/PLCL mass fraction nanocomposite is obtained：an increase of 113% in the tensile strength and an increase of 11% in the elongation at break over pure PLCL polymer.The g-TiO2/PLCL nanocomposites with a certain amount of g-TiO2content have better shape memory properties than pure PLCL polymer.The g-TiO2nanoparticles play an additional physical crosslinks which are contributed to improvement of the shape memory properties.

Study of Oil/Water Interfacial Tension of Vacuum Residual Fractions from Iranian Light Crude Oil

The vacuum residual from Iranian Light crude oil are separated into a series of 16 narrow fractions according to the molecular weight by the supercritical fluid extraction and fractional (SFEF) technology. The chemical element and the UV spectrum of each fraction are analyzed. The effects of several factors on the interfacial tension are investigated, which are the fraction concentration in oil phase, the ratio of oil component, the salts dissolved in the water phase and the pH value. The interfacial tension decreases rapidly as the concentration of the residual fraction in the oil increases, showing a higher interfacial activity of the fraction. The interfacial tension changes, as the amount of absorption or the state of the fractions in the interface changes resulting from different ratios of oil, different kinds or concentrations of salts in water, and different pH values. It is concluded that the interfacial tension changes regularly, corresponding to the regular molecular parameters of the vacuum residual fractions.

Effect of Petroleum Sulphonate on Interfacial Property and Stability of Crude Oil Emulsions

The influence of petroleum sulphonate (TRS) on interfacial properties and stability of the emulsions formed by formation water and asphaltene, resin and crude model oils from Gudong crude oil was investigated by measurement of interfacial shear viscosity, interfacial tension (IFT) and emulsion stability. With increasing petroleum sulphonate concentration, IFT between the formation water and the asphaltene, resin and crude model oils decreases significantly. The interfacial shear viscosity and emulsion stability of asphaltene and crude model oil system increase for the petroleum sulphonate concentration in the range 0.1% to 0.3%, and decrease slightly when the concentration of the surfactant is 0.5%. There exists a close correlation between the interfacial shear viscosity and the stability of the emulsions formed by asphaltene or crude model oils and petroleum sulphonate solution.The stability of the emulsions is determined by the strength of the interfacial film formed of petroleum sulphonate molecules and the natural interfacial active components in the asphaltene fraction and the crude oil. The asphaltene in the crude oil plays a major role in determining the interfacial properties and the stability of the emulsions.

Modeling of Surface Tension and Viscosity for Non-electrolyte Systems by Means of the Equation of State for Square-well Chain Fluids with Variable Interaction Range

The equation of state(EOS)for square-well chain fluid with variable range(SWCF-VR) developed in our previous work based on statistical mechanical theory for chemical association is employed for the correlations of surface tension and viscosity of common fluids and ionic liquids(ILs).A model of surface tension for multi-component mixtures is presented by combining the SWCF-VR EOS and the scaled particle theory and used to produce the surface tension of binary and ternary mixtures.The predicted surface tensions are in excellent agreement with the experimental data with an overall average absolute relative deviation(AAD)of 0.36%.A method for the calculation of dynamic viscosity of common fluids and ILs at high pressure is presented by combining Eyring’s rate theory of viscosity and the SWCF-VR EOS.The calculated viscosities are in good agreement with the experimental data with the overall AAD of 1.44% for 14 fluids in 84 cases.The salient feature is that the molecular parameters used in these models are self-consistent and can be applied to calculate different thermodynamic properties such as pVT,vapor-liquid equilibrium,caloric properties,surface tension,and viscosity.

A plasticity model for sand-structure interfaces

The predictive capacity of numerical analyses in geotechnical engineering depends strongly on the efficiency of constitutive models used for modeling of interfaces behavior.Interfaces are considered as thin layers of the soil adjacent to structures boundary whose major role is transferring loads from structures to soil masses.An interface model within the bounding surface plasticity framework and the critical state soil mechanics is presented.To this aim,general formulation of the interface model according to the bounding surface plasticity theory is described first.Similar to granular soils,it has been shown that the mechanical behavior of sand-structure interfaces is highly affected by the interface state that is the combined influences of density and applied normal stress.Therefore,several ingredients of the model are directly related to the interface state.As a result of this feature,the model is enabled to distinguish interfaces in dense state from those in loose state and to provide realistic predictions over wide ranges of density and normal stress values.In evaluation of the model,a reasonable correspondence between the model predictions and the experimental data of various research teams is found.

Evaluation of Effective Stresses and State Surfaces for Unsaturated Clayey Silt

Terzaghi had established soil mechanics as an academic scholarship due to the discovery of the principal of effective stress for saturated soils when he considered the consolidation theory of saturated clay. The reason of the existence of the effective stress is that soil particles and water are composited by incompressible solid and liquid. Although air is very compressible fluid, the principle of effective stress is also used in unsaturated soils in the resent developed numerical analyses. Schrefler＇s equation is most frequently used, but the effective stress is not verified by the experimental results. In this study, the equations for unsaturated soils proposed by Schrefler, Aitchison, Khalili and Khabbaz and Kohgo are compared with using the results of suction controlled consolidometer tests. As a result, the effective stress for unsaturated soils calculated by Schrefler＇s equation was average of them.

Influence of bluff body shape on wall pressure distribution in vortex flowmeter

To investigate the influence of bluff body shape on wall pressure distribution in a vortex flowmeter,experiments were conducted on a specially designed test section in a closed water rig at Reynolds numbers of 6.2×10 4-9.3×10 4.The cross sections of the bluff bodies were semicircular,square,and triangular shaped,and there were totally 21 pressure tappings along the conduit to acquire the wall pressures.It is found that the variation trends of wall pressures are basically identical regardless of the bluff body shapes.The wall pressures begin to diverge from 0.3D(D is the inner diameter of the vortex flowmeter) in front of the bluff body due to the diversity in shape,and all reach the minimum values at 0.3D behind the bluff body.A discrepancy between the triangular or square cylinder and the semicircular cylinder in wall pressure change is observed at 0-0.1D behind the bluff body.It is also found that the wall pressures and irrecoverable pressure loss coefficients increase with flow rates,and the triangular cylinder causes the smallest irrecoverable pressure loss at a fixed flow rate.

Force-finding analysis of cable-net deployable antenna considering shape constraints

The force-finding process of the cable-net in the deployable mesh reflector antenna,AstroMesh,is investigated to optimize the pretension distribution and satisfy surface accuracy.Since the geometry and topology of the mesh reflector antennas are given as a constraint with the boundary condition assumed to be fixed,the force-finding process can be performed on a constant equilibrium matrix to obtain a feasible set of forces.Then,the equilibrium matrix can be rewritten in terms of force modes after the singular value decomposition.The object of force design is to minimize the deviation of member forces and,therefore,the surface accuracy can be guaranteed by transforming an optimization of the distribution of prestresses into an optimization with multiple prestress modes.Finally,numerical examples solved by the sequential quadratic programming(SQP)algorithm and the genetic algorithm are given to validate the efficiency of the proposed method.The comparison results show that the genetic method can converge to the optimized point after approximately 50 iterations while the converging process of the sequential quadratic programming method depends largely on the initial points.

The Influence of Wave State and Sea Spray on Drag Coefficient from Low to High Wind Speeds

Ocean waves alter the roughness of sea surface,and sea spray droplets redistribute the momentum flux at the air-sea interface.Hence,both wave state and sea spray influence sea surface drag coefficient.Based on the new sea spray generation function which depends on sea surface wave,a wave-dependent sea spray stress is obtained.According to the relationship between sea spray stress and the total wind stress on the sea surface,a new formula of drag coefficient at high wind speed is acquired.With the analysis of the new drag coefficient,it is shown that the drag coefficient reduces at high wind speed,indicating that the sea spray droplets can limit the increase of drag coefficient.However,the value of high wind speed corresponding to the initial reduced drag coefficient is not fixed,and it depends on the wave state,which means the influence of wave cannot be ignored.Comparisons between the theoretical and measured sea surface drag coefficients in field and laboratory show that under different wave ages,the theoretical result of drag coefficient could include the measured data,and it means that the new drag coefficient can be used properly from low to high wind speeds under any wave state condition.

Mechanical Properties of Small-diameter Superfine Silk Powder/Polyurethane Vascular Graft Reinforced by Tubular Knitted Fabric

In this paper,a kind of composite microtube,which is made from superfine silk powder and polyurethane,reinforced by polyster and spandex tubular fabrics,was examined.The cross-section of composite microtubes were microporous,and micropores were uniform distributed,the inner surface was relatively smooth.The results showed that the wall thickness of composite microtubes increased,which led to the strength,the breaking work and the initial modulus incresead;that the spandex content increased brought about the initial modulus and the breaking work decreased,but the breaking extension and the breaking load were firstly increased and then decreased;and all the mechanical properties decreased as the SFSP content increased.

Modeling and Parametric Study of the Heat Transfer Inside a Lithium Bromide Flow Confined by Wire Screen

The present study deals with the numerical analysis of heat transfer inside a lithium bromide-water solution flowing down between finely meshed plastic wire screens. These screens confine the flow through capillary action while allowing the water vapour transfer inside an innovative absorber technology. The complex menisci shape formed on the confinement grid level, where the surface tension forces are of first importance, are reconstructed by a volume-of-fluid model. A continuum surface force model is used to account for the surface tension force. A static contact angle is used to define the wall adhesion. A new algorithm, consisting to set an unique constant temperature at the liquid/vapour interface and to determine the evolution of heat transfer characteristics over the simulation domain, has been implemented and validated by analytical solution. A parametric study has been conducted to determine the effect of the geometry, the contact angle and the shape of the wire on the heat transfer.

Effects of Hydroxyl Groups in Organic Ammonium Counterions on the Properties of Fluorinated Surfactants

The surface tension, foaming and viscosity for C7F15COO^-N^＋H（C2H4OH）χ（C2Hs）3-x and C8F17SO3- N^＋H（C2H4OH）χ（C2H5）3-χ （x = 0, 1, 2, 3） were measured to systematically study the effects of hydroxyl groups in organic ammonium counterions on the properties of perfluorooctanoates and perfluorooctanesulfonates. The results showed that the critical micelle concentration （cmc） and the surface tension at cmc （γcmc） were both increased with the increase of number of hydroxyl groups （χ） in the two series. The perfluorooctanesulfonate had smaller cmc but higher γ=cmc than perfluorooctanoate with the same counterion. The minimum molecular area of surface adsorption （Amin） of C8F17zSO3^-N^＋H（C2H4OH）χ（C2H5）3-χ were 0.64, 0.57, 0.63 and 0.72 nm^2 while the Amin values of C7F15COO^-N^＋H（C2H4OH）χ（C2H5）3-χ were 0.61, 0.62, 0.61 and 0.71 nm^2 when χ = 0, 1, 2 and 3, respectively. For the investigated systems of surfactants, the results of foam expansion ratio agreed with those of surface activity, while the 25% drainage time were consistent with the results of viscosity.

The analysis for stress-strain characteristics of concrete cutoff wall built in deep cladding foundation

Combined with a proposed homogeneous earth dam in deep cladding foundation, Duncan E-B model is applied to simulate dam-filled material, apply to three-dimensional nonlinear finite element method, attain the stress-strain distribution and alteration in concrete cutoff wall in completion and water storage periods, analysis the stress state in the contact element between concrete cutoff wall and cladding foundation, provide the corresponding measures. The calculation results show that the design of concrete cutoff wall and homogeneous earth dam is reasonable.

Investigation of pyrite surface state by DFT and AFM

The surface states of pyrite(Fe S2) were theoretically investigated using first principle calculation based on the density functional theory(DFT). The results indicate that both the(200) and(311) surfaces of pyrite undergo significant surface atom relaxation after geometry optimization, which results in a considerable distortion of the surface region. In the normal direction, i.e., perpendicular to the surface, S atoms in the first surface layer move outward from the bulk, while Fe atoms move toward the bulk, forming an S-rich surface. The surface relaxation processes are driven by electrostatic interaction, which is evidenced by a relative decrease in the surface energy after surface relaxation. Such a relaxation process is visually interpreted through the qualitative analysis of molecular mechanics. Atomic force microscopy(AFM) analysis reveals that only sulfur atom is visible on the pyrite surface. This result is consistent with the DFT data. Such S-rich surface has important influence on the flotation properties of pyrite.

Fluid Flow Optimization on Semiautomatic Code Marker Base

This paper describes optimization process of nozzle cup based on a device for contactless code marking to rough and contaminated surfaces--semiautomatic code marker. During tests using the CFD （computational fluid dynamics） software different geometry of nozzle cups were compared by such parameters as pressure, velocity and direction of flow. Goal of digital experiments was to find sprayer nozzle geometry that can keep stream of paint in diameter of 10 mm on 10-20 mm distance. Main problem is to avoid low-pressure regions around the stream. The optimal geometry of nozzle cup is designed to get adjusted code dimensions on given distance

Low-energy electronic properties of a Weyl semimetal quantum dot

We investigate the low-energy electronic structure ofa Weyl semimetal quantum dot （QD） with a simple model Hamiltonian with only two Weyl points. Distinguished from the semiconductor and topological insulator QDs, there exist both surface and bulk states near the Fermi level in Weyl semimetal QDs. The surface state, distributed near the side surface of the QD, contributes a circular persistent current, an orbital magnetic moment, and a chiral spin polarization with spin-current locking. There are always surface states even for a strong magnetic field, even though a given surface state gradually evolves into a Landau level with increasing magnetic field. It indicates that these unique properties can be tuned via the QD size. In addition, we show the correspondence to the electronic structures of a three-dimensional Weyl semimetal, such as Wey[ point and Fermi arc. Because a QD has the largest surface-to-volume ratio, it provides a new platform to verify Weyl semimetal by separating and detecting the signals of surface states. Besides, the study of Weyl QDs is also necessary for potential applications in nanoelectronics.