导体表面电场强度的分析

本文利用特殊的曲面积分方法，讨论了筹电场中带电导体表面的电场强度，得到了满意的结果．

电磁场变换的特性分析

本文指出电磁场变换是指一个时空点上的电磁场在两惯性系中的变换,与此点邻域内其它时空点上的电磁场量值无关。在一个时空点上,只要场的数值相同,交变电磁场的变换与均匀静电场均匀稳恒磁场的变换一样。均匀电场均匀磁场的变换可通过均匀面电荷密度和均匀面电流线密度的变换来得到。本文讨论了电磁场变换与电荷不变性、运动尺度收缩之间的联系,并由此导出一般情形的电磁场变换公式。

An effective CdS/Ti-Fe_(2)O_(3)heterojunction photoanode:Analyzing Z-scheme charge-transfer mechanism for enhanced photoelectrochemical water-oxidation activity

Z-scheme photocatalytic system has been regarded as a popular field of research in photoelectrochemical(PEC)water splitting.Among the many obstacles facing a Z-scheme photocatalytic system,the analysis methods of interfacial Z-scheme charge transfer still remain a significant challenge.Hence,in this study,CdS/Ti-Fe_(2)O_(3)heterojunction photoanodes are elaborately designed to explore the charge-transfer behavior in PEC water splitting.In this study,photophysical measurements,including the Kelvin probe measurement,surface photovoltage spectroscopy(SPV),and transient photovoltage spectroscopy(TPV),are used to monitor the migration behavior of photogenerated charges at the interface electric field of CdS/Ti-Fe_(2)O_(3)Z-scheme heterojunction photoanodes.The Kelvin probe and SPV measurements demonstrate that CdS/Ti-Fe_(2)O_(3)interfacial driving force favors the rapid transfer of photoexcited electrons to CdS.The double-beam strategy based on TPV indicates that more electrons of Ti-Fe_(2)O_(3)are combined with the holes of CdS owing to the intensive interface electric field.The results of these measurements successfully prove the Z-scheme migration mechanism of CdS/Ti-Fe_(2)O_(3)photoanodes.Benefiting from the desirable charge transfer at the interface electric field,CdS/Ti-Fe_(2)O_(3)photoanodes exhibit superior photocatalytic oxygen evolution reaction performance compared with that of pure Ti-Fe_(2)O_(3).The photocurrent density of the 25CdS/Ti-Fe_(2)O_(3)photoanode reaches 1.94 mA/cm^(2) at 1.23 V versus reversible hydrogen electrode without excess cocatalyst,and it is two times higher than that of pure Ti-Fe_(2)O_(3)photoanode.Therefore,an outstanding strategy is provided in this study to prove the Z-scheme charge-transfer mechanism of photocatalytic systems in PEC water splitting.

Effect of Surface Charge on Flashover for Oil-Pressboard Insulation under AC-DC Combined Electric Field

For converter transformer, AC-DC combined electric field can trigger space charge accumulation on oil-impregnated pressboard interface. The accumulation of space charge on oil-pressboard interface can result in electric field distortion, trend to trigger surface discharge of barriers. This paper studied the influence of surface charge on flashover voltage of oil-impregnated pressboard under AC-DC combined electric field. The study finds that the flashover voltage of oil-pressboard interface under negative polarity DC superimposed AC electric field is higher than that.of positive DC superimposed AC voltage to form composite electric field. It was found that homopolar surface charge has been accumulated on the interface of oil-pressboard with positive or negative DC voltage through measuring surface potential by the electrostatic capacitive probe. The surface charge produced electric field in the opposite direction, which weakening the synthetic electric field strength. What＇s more, under the same conditions, the negative surface charge density oil-pressboard is much larger than the positive.

Effect of the interfacial electric field on the HER on Pt(111)modified with iron adatoms in alkaline media

The study of the hydrogen evolution reaction(HER)aimed to reach a deeper understanding of the parameters that control the rate of this reaction is of great importance given the technical relevance of hydrogen production as an energy vector in the so-called hydrogen economy.In previous works,laser-induced temperature jump(LITJ)experiments on Pt(111)modified with Ni(OH)_(2)in alkaline media have revealed the importance of the interfacial electric field in the rate of the HER.It was hypothesised that small amounts of Ni(OH)_(2)cause a decrease of the electric field because of a negative shift of the pzfc toward the onset of the hydrogen evolution.In this work,to test the validity of this hypothesis,the study has been extended to Pt(111)surfaces modified with Fe(OH)_(2).The modified surfaces have been studied voltammetrically,and the voltammetric charges have been analysed.The voltammograms show a peak in the hydrogen evolution region that suggest the transformation in the adlayer from Fe(II)to Fe(0).In agreement with the coulometric analysis,the voltammetric features in the OH adsorption region would be related with the oxidation to the+3 valence state.The results obtained with LITJ method reflect the existence of a strong interaction of the Fe oxophilic species with the water molecules,shifting the potential of maximum entropy away from the onset of the HER.Hence,the most catalytic surface is the one with the lowest Fe coverage.