Four methods, including voltammetric measurement of double layer capacitance, surface oxides reduction, under potential deposition of Cu and carbon monoxide （CO） stripping have been applied to evaluate the real surf...Four methods, including voltammetric measurement of double layer capacitance, surface oxides reduction, under potential deposition of Cu and carbon monoxide （CO） stripping have been applied to evaluate the real surface area of a polycrystalline Pd （pc-Pd） electrode. The results reveal that the second and third methods lead to consistent results with deviations below 5%. And from the determined double layer capacitance and CO stripping charge, it is deduced that the double layer capacity unit area is 23.1±0.4μF/cm2 and the saturated CO adlayer should be ca. 0.66 ML in order to ensure that the real surface area as determined is consistent with the other two techniques. The applicability as well as the attentions when applying these techniques for the determination of the real surface area of pc-Pd electrodes have been discussed.展开更多
In this research paper,we have presented variable area type capacitive sensor signal conditioning system for angular displacement measurement and for this purpose we have used timer LM555 based astable multivibrator a...In this research paper,we have presented variable area type capacitive sensor signal conditioning system for angular displacement measurement and for this purpose we have used timer LM555 based astable multivibrator and universal frequency to digital converter (UFDC). Due to variation in angular displacement in the variable area type capacitor which is connected in the timer based astable circuit,capacitance changes which in turn changes the time period of the timer circuit output. The time period of the timer output waveform is linear with the capacitance and hence linear with angular displacement. The timer output is further processed with UFDC for the measurement. The experimental results show that the time period is linear with the angular displacement in the range of 0- 180° and the uncertainty we should associate it with this average time period value is the standard deviation of the mean,often called the standard error (SE),which is ± 0.023 μs. Because of the simplicity,this measurement system can be used in both electronic and industrial instrumentation.展开更多
On May 12, 2008, an earthquake of 8.0 magnitude on the Richter scale and its numerous aftershocks devastatingly hit Wenchuan County and its nearby region along the Longman Mountains in Sichuan Province, China. The hea...On May 12, 2008, an earthquake of 8.0 magnitude on the Richter scale and its numerous aftershocks devastatingly hit Wenchuan County and its nearby region along the Longman Mountains in Sichuan Province, China. The heavy ruined area was up to 30,000km2 and 13% of its land surface was denuded by the extremely terrible quakes. The mountain collapses, landslides and debris flows induced by the earthquake not only scared the landscape at the immense scale, but also poured L66-billion-m3 sediment combined with offscourings and rubble into the Yangtze River and its breaches. This amount of sediments is 3 times more than the normal amount discharged into the Yangtze River, and will significantly increase sediment transportation of rivers and decrease storage capacities of reservoirs downstream. The dramatic increase in sediment load will imperil the engineering safety and impact the operation of the giant Three-Gorge Hydro-power Station if no proper prevention measures are taken.展开更多
A series of porous carbon materials with wide range of specific surface areas and different heteroatom contents had been prepared using polyaniline as carbon precursor and KOH as an activating agent. Effect of surface...A series of porous carbon materials with wide range of specific surface areas and different heteroatom contents had been prepared using polyaniline as carbon precursor and KOH as an activating agent. Effect of surface area and heteroatom of porous carbon materials on specific capacitance was investigated thoroughly in two typical aqueous KOH and organic 1-butyl-3- methylimidazolium tetrafluoroborate/acetonitirle electrolytes. The different trends of capacitance performance were observed in these two electrolytes. Electrochemical analyses suggested that the presence of faradaic interactions on heteroatom-enriched carbon materials in organic environment is less significant than that observed in aqueous electrolytes. Thus, in aqueous electrolyte, a balance between surface area and heteroatom content of activated porous carbon would be found to develop a supercapacitor with high energy density. In organic electrolyte, the capacitance performance of porous carbon is strongly dependent on the surface area. The results may be useful for the design of porous carbon-based supercapacitor with the desired capacitive performance in aqueous and organic electrolytes.展开更多
In this paper, the bacterial celluloses(BCs) were pyrolysed in nitrogen and then activated by KOH to form a porous three- dimension-network electrode material for supercapacitor applications. Activated pyrolysed bacte...In this paper, the bacterial celluloses(BCs) were pyrolysed in nitrogen and then activated by KOH to form a porous three- dimension-network electrode material for supercapacitor applications. Activated pyrolysed bacterial cellulose(APBC) samples with enlarged specific surface area and enhanced specific capacitances were obtained. In order to optimize electrochemical properties, APBC samples with different alkali-to-carbon ratios of 1, 2 and 3 were tested in two electrodes symmetrical capacitors. The optimized APBC sample holds the highest specific capacitance of 241.8 F/g, and the energy density of which is 5 times higher than that of PBC even at a current density of 5 A/g. This work presents a successful practice of preparing electrode material from environment-friendly biomass, bacterial cellulose.展开更多
基金Shanxi Province Science Foundation for Youths(2013021011-3)Shanxi Scholarship Council of China(2013-041)Project for Importing Talent of Taiyuan University of Technology(tyut-rc201110a)~~
文摘Four methods, including voltammetric measurement of double layer capacitance, surface oxides reduction, under potential deposition of Cu and carbon monoxide （CO） stripping have been applied to evaluate the real surface area of a polycrystalline Pd （pc-Pd） electrode. The results reveal that the second and third methods lead to consistent results with deviations below 5%. And from the determined double layer capacitance and CO stripping charge, it is deduced that the double layer capacity unit area is 23.1±0.4μF/cm2 and the saturated CO adlayer should be ca. 0.66 ML in order to ensure that the real surface area as determined is consistent with the other two techniques. The applicability as well as the attentions when applying these techniques for the determination of the real surface area of pc-Pd electrodes have been discussed.
文摘In this research paper,we have presented variable area type capacitive sensor signal conditioning system for angular displacement measurement and for this purpose we have used timer LM555 based astable multivibrator and universal frequency to digital converter (UFDC). Due to variation in angular displacement in the variable area type capacitor which is connected in the timer based astable circuit,capacitance changes which in turn changes the time period of the timer circuit output. The time period of the timer output waveform is linear with the capacitance and hence linear with angular displacement. The timer output is further processed with UFDC for the measurement. The experimental results show that the time period is linear with the angular displacement in the range of 0- 180° and the uncertainty we should associate it with this average time period value is the standard deviation of the mean,often called the standard error (SE),which is ± 0.023 μs. Because of the simplicity,this measurement system can be used in both electronic and industrial instrumentation.
基金carried out under the auspices of the public project of the Ministry of Water Conservancy of China (200801073, 2007SHZ0901034)the Knowledge Innovation Project of the Chinese Academy of Science (KZCX1-YW-08)
文摘On May 12, 2008, an earthquake of 8.0 magnitude on the Richter scale and its numerous aftershocks devastatingly hit Wenchuan County and its nearby region along the Longman Mountains in Sichuan Province, China. The heavy ruined area was up to 30,000km2 and 13% of its land surface was denuded by the extremely terrible quakes. The mountain collapses, landslides and debris flows induced by the earthquake not only scared the landscape at the immense scale, but also poured L66-billion-m3 sediment combined with offscourings and rubble into the Yangtze River and its breaches. This amount of sediments is 3 times more than the normal amount discharged into the Yangtze River, and will significantly increase sediment transportation of rivers and decrease storage capacities of reservoirs downstream. The dramatic increase in sediment load will imperil the engineering safety and impact the operation of the giant Three-Gorge Hydro-power Station if no proper prevention measures are taken.
基金supported by the Top Hundred Talents Program of Chinese Academy of Sciencesthe National Natural Science Foundation of China(21203223)the Youth Science Foundation of Gansu Province(1107RJYA274)
文摘A series of porous carbon materials with wide range of specific surface areas and different heteroatom contents had been prepared using polyaniline as carbon precursor and KOH as an activating agent. Effect of surface area and heteroatom of porous carbon materials on specific capacitance was investigated thoroughly in two typical aqueous KOH and organic 1-butyl-3- methylimidazolium tetrafluoroborate/acetonitirle electrolytes. The different trends of capacitance performance were observed in these two electrolytes. Electrochemical analyses suggested that the presence of faradaic interactions on heteroatom-enriched carbon materials in organic environment is less significant than that observed in aqueous electrolytes. Thus, in aqueous electrolyte, a balance between surface area and heteroatom content of activated porous carbon would be found to develop a supercapacitor with high energy density. In organic electrolyte, the capacitance performance of porous carbon is strongly dependent on the surface area. The results may be useful for the design of porous carbon-based supercapacitor with the desired capacitive performance in aqueous and organic electrolytes.
基金supported by the Ministry of Science and Technology of China (2012CB933403)the National Natural Science Foundation of China (21173057, 51425302)the Chinese Academy of Sciences.
文摘In this paper, the bacterial celluloses(BCs) were pyrolysed in nitrogen and then activated by KOH to form a porous three- dimension-network electrode material for supercapacitor applications. Activated pyrolysed bacterial cellulose(APBC) samples with enlarged specific surface area and enhanced specific capacitances were obtained. In order to optimize electrochemical properties, APBC samples with different alkali-to-carbon ratios of 1, 2 and 3 were tested in two electrodes symmetrical capacitors. The optimized APBC sample holds the highest specific capacitance of 241.8 F/g, and the energy density of which is 5 times higher than that of PBC even at a current density of 5 A/g. This work presents a successful practice of preparing electrode material from environment-friendly biomass, bacterial cellulose.
