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Zr-MMT纳米材料吸附铬鞣废水中Cr(Ⅲ)的研究 被引量:7
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作者 黑亚妮 马宏瑞 +1 位作者 郭颖艳 鄂涛 《功能材料》 EI CAS CSCD 北大核心 2016年第3期51-55,63,共6页
以纳米蒙脱土(MMT)为原料,Zr(SO4)2为改性剂,采用浸渍法制备Zr-MMT用于处理低浓度含Cr(Ⅲ)废水,并研究了Zr-MMT纳米材料的吸附机理。采用X射线衍射(XRD)和扫描电子显微镜(SEM)对Zr-MMT纳米材料进行表征。结果表明,吸附后的Zr-MMT表面有... 以纳米蒙脱土(MMT)为原料,Zr(SO4)2为改性剂,采用浸渍法制备Zr-MMT用于处理低浓度含Cr(Ⅲ)废水,并研究了Zr-MMT纳米材料的吸附机理。采用X射线衍射(XRD)和扫描电子显微镜(SEM)对Zr-MMT纳米材料进行表征。结果表明,吸附后的Zr-MMT表面有Cr(Ⅲ)存在;Zr-MMT对Cr(Ⅲ)的吸附方式主要有离子交换、静电吸附和表面吸附,并且该吸附过程可以用二级动力学方程和Langmuir方程进行很好的拟合。解决了鞣制废物资源化利用中Zr(OH)4和ZrO2在强酸强碱性条件下不稳定的问题,制得了一种稳定性好的纳米吸附材料。 展开更多
关键词 鞣制废物 Zr-MMT 吸附 制革废水 Cr(Ⅲ)
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A Novel Approach to Clean Tanning Technology 被引量:5
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作者 Jing Li Lan Yan +1 位作者 Bi Shi Jing Zhang 《Journal of Chemistry and Chemical Engineering》 2013年第12期1203-1212,共10页
Traditional chrome tanning technology is still widely used today. In this technology, chrome shaving as well as chrome contained effluent in tanning and retanning processes is a big issue in the industry. Wet white ta... Traditional chrome tanning technology is still widely used today. In this technology, chrome shaving as well as chrome contained effluent in tanning and retanning processes is a big issue in the industry. Wet white tanning technology has been gaining in importance in recent years, but in general, the comprehensive performance of chrome-free tanned leather is not comparable with that of chrome tanned leather. In the present work, chrome-free tanning and chrome tanning are combined in a reversed procedure, which produces leather with chrome tanned leather quality without chrome tanned leather waste problems. In this procedure, a special amphoteric organic compound, no pickle, no salt chrome-free tanning agent TWT was used to tan delimed hides (no pickle) making wet white with shrinking temperature at 80-85 ~C. Then, new method called reversed tanning further process the wet white into chrome-tanned crust. In this reversed method, retanning, fatliquoring and coloring processes were carried out before chrome tanning. This technology eliminates chrome waste issue in tanning, shaving, post tanning processes. The chrome contained effluent is only concentrated in the last chrome tanning process. The leather made with this technology has complete conventional chrome-tanned leather quality. In this way, chrome leather quality without chrome waste problems was achieved. So, it is a new clean tanning technology. 展开更多
关键词 Chrome-free tanning wet-white reversed tanning process chrome tanning post tanning.
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