The formation and qualification of redox sites in transition metal oxides are always the active fields related to electronics, catalysis, sensors, and energy-storage units. In the present study, the temperature depend...The formation and qualification of redox sites in transition metal oxides are always the active fields related to electronics, catalysis, sensors, and energy-storage units. In the present study, the temperature dependence of thermal reduction of MoO3 was surveyed at the range of 350℃ to 750℃. Upon reduction, the formed redox species characterized by EPR spectroscopy are the MoVion and superoxide anion radical (O2-) when the reduction was induced at the optimal temperature of 300-350℃. When heating-up from 350℃, the EPR signals started to decline in amplitude. The signals in the range of 400-450℃ decreased to half of that at 350℃, and then to zero at ~600℃. Further treatment at even higher temperature or prolonged heating time at 500℃ caused more reduction and more free electrons were released to the MoO3 bulk, which results in a delocalized means similar to the antiferromagnetic coupling. These data herein are helpful to prepare and study the metal-oxide catalysts.展开更多
ZL205 A alloys with large thin-walled shape were continuously processed by coupling travelling magnetic fields(TMF)with sequential solidification,to eliminate the shrinkage defects and optimize the mechanical performa...ZL205 A alloys with large thin-walled shape were continuously processed by coupling travelling magnetic fields(TMF)with sequential solidification,to eliminate the shrinkage defects and optimize the mechanical performance.Through experiments and simulations,the parameter optimization of TMF and the influence on feeding behavior,microstructure and properties were systematically studied.The results indicate that the magnetic force maximizes at the excitation current of 20 A and frequency of 200 Hz under the experimental conditions of this study,and increases from center to side-walls,which is more convenient to process thin-walled castings.TMF can break secondary dendritic arm and dendrites overlaps,widen feeding channels,prolong the feeding time,optimize the feeding paths,eliminate shrinkage defects and improve properties.Specifically,for as-cast state,TMF with excitation current of 20 A increases ultimate tensile strength,elongation and micro-hardness from 186 MPa,7.3%and 82.1 kg/mm^(2) to 221 MPa,11.7%and 100.5 kg/mm^(2),decreases porosity from 1.71%to 0.22%,and alters brittle fracture to ductile fracture.展开更多
On March 13,2007,two earthquakes with M4.7 and M4.6 occurred in Zhengfang Village,Shunchang,Fujian.The M4.7 earthquake is the most intensive one in the Fujian region since the establishment of the Fujian digital seism...On March 13,2007,two earthquakes with M4.7 and M4.6 occurred in Zhengfang Village,Shunchang,Fujian.The M4.7 earthquake is the most intensive one in the Fujian region since the establishment of the Fujian digital seismic networks.These two earthquakes provide us with valuable first-hand observation data for seismological research.This paper analyzes their wave-forms and concludes that(1)the crustal thickness in the seismic region is estimated to be about 40km according to the observed head-wave critical distance;(2)there is a salient difference between the ratios of S-wave's maximum amplitudes of these two earthquakes;(3)the focal depth of the M4.7 earthquake is estimated to be 8.4km according to the clear depth phrase sPn in waveforms,which is the same with the result of other determination methods.展开更多
Electron Paramagnetic Resonance(EPR)is the only spectral method for direct detection of paramagnetic substances.EPR technology can be used for the qualitative and quantitative analysis of free radicals and transition ...Electron Paramagnetic Resonance(EPR)is the only spectral method for direct detection of paramagnetic substances.EPR technology can be used for the qualitative and quantitative analysis of free radicals and transition metals in solid,liquid,gas,cell and living samples.It is widely used in chemistry,material science,life science,quantum physics and other researches.This report discusses the basic principle,instrument structure,common problem solving,daily maintenance,and management model of the electron paramagnetic resonance spectrometer(German Bruker A-200)in the State Key Laboratory of Natural and Biomimetic Drugs of Peking University Health Science Center,so that the instrument can be fully used for various scientific researches.展开更多
基金supported by the National Key R&D Program of China(No.2018YFA0306600)AnHui Initiative in Quantum Information Technologies(No.AHY050000)
文摘The formation and qualification of redox sites in transition metal oxides are always the active fields related to electronics, catalysis, sensors, and energy-storage units. In the present study, the temperature dependence of thermal reduction of MoO3 was surveyed at the range of 350℃ to 750℃. Upon reduction, the formed redox species characterized by EPR spectroscopy are the MoVion and superoxide anion radical (O2-) when the reduction was induced at the optimal temperature of 300-350℃. When heating-up from 350℃, the EPR signals started to decline in amplitude. The signals in the range of 400-450℃ decreased to half of that at 350℃, and then to zero at ~600℃. Further treatment at even higher temperature or prolonged heating time at 500℃ caused more reduction and more free electrons were released to the MoO3 bulk, which results in a delocalized means similar to the antiferromagnetic coupling. These data herein are helpful to prepare and study the metal-oxide catalysts.
基金financial supports from the National Key Research and Development Program of China(2017YFA0403804)the National Natural Science Foundation of China(51425402,51671073)。
文摘ZL205 A alloys with large thin-walled shape were continuously processed by coupling travelling magnetic fields(TMF)with sequential solidification,to eliminate the shrinkage defects and optimize the mechanical performance.Through experiments and simulations,the parameter optimization of TMF and the influence on feeding behavior,microstructure and properties were systematically studied.The results indicate that the magnetic force maximizes at the excitation current of 20 A and frequency of 200 Hz under the experimental conditions of this study,and increases from center to side-walls,which is more convenient to process thin-walled castings.TMF can break secondary dendritic arm and dendrites overlaps,widen feeding channels,prolong the feeding time,optimize the feeding paths,eliminate shrinkage defects and improve properties.Specifically,for as-cast state,TMF with excitation current of 20 A increases ultimate tensile strength,elongation and micro-hardness from 186 MPa,7.3%and 82.1 kg/mm^(2) to 221 MPa,11.7%and 100.5 kg/mm^(2),decreases porosity from 1.71%to 0.22%,and alters brittle fracture to ductile fracture.
基金sponsored by the Joint Earthquake Science Foundation of China (106094)
文摘On March 13,2007,two earthquakes with M4.7 and M4.6 occurred in Zhengfang Village,Shunchang,Fujian.The M4.7 earthquake is the most intensive one in the Fujian region since the establishment of the Fujian digital seismic networks.These two earthquakes provide us with valuable first-hand observation data for seismological research.This paper analyzes their wave-forms and concludes that(1)the crustal thickness in the seismic region is estimated to be about 40km according to the observed head-wave critical distance;(2)there is a salient difference between the ratios of S-wave's maximum amplitudes of these two earthquakes;(3)the focal depth of the M4.7 earthquake is estimated to be 8.4km according to the clear depth phrase sPn in waveforms,which is the same with the result of other determination methods.
文摘Electron Paramagnetic Resonance(EPR)is the only spectral method for direct detection of paramagnetic substances.EPR technology can be used for the qualitative and quantitative analysis of free radicals and transition metals in solid,liquid,gas,cell and living samples.It is widely used in chemistry,material science,life science,quantum physics and other researches.This report discusses the basic principle,instrument structure,common problem solving,daily maintenance,and management model of the electron paramagnetic resonance spectrometer(German Bruker A-200)in the State Key Laboratory of Natural and Biomimetic Drugs of Peking University Health Science Center,so that the instrument can be fully used for various scientific researches.
