Thermodynamic functions solutions of a 25 binary systems formed n-alcohols and esters of aliphatic acids by were calculated using the standards ideal solution and ideal gas. The value change regularity of the thermody...Thermodynamic functions solutions of a 25 binary systems formed n-alcohols and esters of aliphatic acids by were calculated using the standards ideal solution and ideal gas. The value change regularity of the thermodynamic functions of solutions depending on their molar mass and concentration of the solutions＇ components was determined by the thermodynamic analysis. The method of prediction of the thermodynamic properties of binary solutions was suggested on the basis of the determined regularities. The corresponding equations were obtained.展开更多
文摘Thermodynamic functions solutions of a 25 binary systems formed n-alcohols and esters of aliphatic acids by were calculated using the standards ideal solution and ideal gas. The value change regularity of the thermodynamic functions of solutions depending on their molar mass and concentration of the solutions＇ components was determined by the thermodynamic analysis. The method of prediction of the thermodynamic properties of binary solutions was suggested on the basis of the determined regularities. The corresponding equations were obtained.
