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碱金属氯化物对预氧化钛铁矿碳热还原反应的协同催化作用 被引量:11
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作者 吴剑辉 孙康 +1 位作者 李伟 马跃宇 《广东有色金属学报》 2000年第1期25-29,共5页
采用计算机控制的热重量分析系统研究了碱金属氯化物对预氧化钛铁矿碳热还原反应的 协同催化作用.还原反应在非等温条件下进行,试验温度从50℃线性上升到1000℃.试验结果表明, 所有碱金属氯化物添加剂均能加速碳热还原反应.... 采用计算机控制的热重量分析系统研究了碱金属氯化物对预氧化钛铁矿碳热还原反应的 协同催化作用.还原反应在非等温条件下进行,试验温度从50℃线性上升到1000℃.试验结果表明, 所有碱金属氯化物添加剂均能加速碳热还原反应.在添加量相同的条件下,二元碱金属氯化物的协 同催化比三元和四元协同催化的效果好,其中LiCl和CsCl的协同催化效应最显著.X-射线衍射结 果表明,碳热还原的主要反应为Fe2TiO5+TiO2+C=2F2TiO3+CO↑. 展开更多
关键词 碱金属化合物 碳热还原 协同催化 预氧化钛铁矿
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Reduction behaviour of Odisha Sands Complex,India ilmenite-coke composite pellets
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作者 D NAYAK N RAY +2 位作者 N DASH S S RATH S K BISWAL 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第6期1678-1690,共13页
Presently,ilmenite concentrates from Odisha Sands Complex at Chhatrapur,India are utilized to produce TiO2 slag by direct smelting in an electric arc furnace.However,the process involves the consumption of excess elec... Presently,ilmenite concentrates from Odisha Sands Complex at Chhatrapur,India are utilized to produce TiO2 slag by direct smelting in an electric arc furnace.However,the process involves the consumption of excess electrical energy and difficulty in handling the arc furnace due to frothing effects.A more efficient process of pre-reducing the ilmenite before smelting has been proposed in the present communication.In particular,studies have been undertaken on the reduction process of ilmenite-coke composite pellets.The difference in the reduction behaviour of raw ilmenite and ilmenite-coke composite pellets has been established and compared with that of the pre-oxidized raw pellets.The effects of various processing parameters like temperature,residence time,and reductant percentage on the metallization of composite pellets in a static bed have been investigated.Metallization of about 90%has been achieved at 1250°C for a reduction period of 360 min with a 4%coke composition.Furthermore,the reduced pellets have been characterized through chemical analysis,optical microscopy,field emission scanning electron microscopy and X-ray diffraction analysis.The reduction behaviour of composite pellets has also been found better than that of pre-oxidized pellets indicating the former to be more efficient. 展开更多
关键词 ILMENITE composite pellet PRE-OXIDATION REDUCTION METALLIZATION
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