Hot corrosion behavior of Ni-xCr-6.8Al based alloys

The hot corrosion behaviors of as-cast and preoxidized Ni-xCr-6.8Al based alloys in the mixture of Na2SO4＋25% NaCl at 873 K were studied. The results show that the mass loss of Ni-xCr-6.8Al based alloys decreases with the increase of Cr content. Preoxidation improves the resistance to corrosion regardless of the concentration of Cr. The kinetics of as-cast Ni-12Cr-6.8Al and Ni-16Cr-6.8Al based alloys fits the parabolic law well, while that of the as-cast Ni-20Cr-6.8Al based alloy fits the power law. The kinetics of all the preoxidized samples obey the logarithmic law. The mechanism of the as-cast alloys can be well explained by the acid-base melting model. The behavior of the preoxidized alloys is found to be mainly determined by the properties of the oxide layer formed during the preoxidation to a large extend.

地板辐射供暖系统间歇运行的性能分析

建立了地板辐射供暖系统不稳定供暖过程的数学模型,通过数值模拟,用数值计算的方法计算了间歇供暖条件下达到室内要求温度所需的预热量与预热时间的关系,指出地板辐射供暖系统的应用局限性。

新风换气能源环境系统的性能参数研究

被动式低能耗居住建筑作为一种高效节能、健康舒适的建筑,其高保温性、高气密性、高效热回收等特点,势必将成为人类未来建筑节能发展的趋势。而适用于被动式低能耗居住建筑的新风换气能源环境系统正是保证这类建筑室内环境舒适度的重要环节。利用理论计算的方法分析了被动式低能耗居住建筑的冷、热需求,进而得到适用于被动式低能耗居住建筑的新风换气能源环境系统的性能参数,为新风换气能源环境系统的研究提供技术依据。

Characterization of Energy_Transduction in Thermal Pretreated Chloroplast from Spinach

Characterization of energy-transduction on die chloroplast thylakoid membranes from spinach (Spinacia oleracca L.) after thermal pretreatment was investigated. The related reactions of energy-transduction in chloroplasts were seriously affected by thermal pretreatment. The results were obtained as following: (1) The rate of cyclic photophosphorylation declined when the pretreatment temperature increased in the range of 25 to 45 degreesC. (2) The thermal pretreatment led to a decrease of the activity of thylakoid membrane-bounded ATPase. (3) Proton uptake of chloroplasts acid the fluorescence quenching of 9-aminoacridine (9-AA) in thylakoid membrane decreased after the thermal pretreatment, but addition of dicyclohexylcarbodiimide (DCCD) could partially restore the fluorescence quenching of 9-AA. (4) Both the rates of fast phase in electrochroism absorption change at 515 nm and the millisecond delayed light emission (ms-DLE) of chloroplast showed a progressive decrease upon raising the temperature of pretreatment. (5) Immunbloting analysis showed that the thermal pretreatment caused the changes of protein content and the electrophoresis mobility of thylakoid membrane-bound ATPase and its alpha -subunit. (6) If the temperature of pretreatment were higher than 33 degreesC, oxygen uptake of PS I -mediated in the samples was rapidly inhibited, but addition of sinapine into the reaction medium could partially restore the ability of oxygen uptake in the samples. These results are briefly discussed in relation to the change of permeability of thylakoid membranes, the dissociation of coupling factor complex as well as accumulation of the radicals in the thylakoid membranes after thermal pretreatment.

FGD Capacity Prediction of Thermal Power Plants in China

Through analyzing the proportion of SO2 emission from thermal power plants in the nationwide SO2 emis- sion in USA, Japan etc. developed countries, and the developmental course of thermal power installed capacity and the FGD capacity in USA, the FGD capacity of thermal power plants in China is forecasted from two angles. One is to predict FGD capacity in accordance with the policy in force in China. The other is to predict FGD capacity based upon the emission right trading policy. As compared, it is held that FGD equipment should be mainly installed on the large size units burning high sulfur coal according to the emission right trading policy. Such a method of work not only can economize large amount of investments and operation costs, but also can realize the same environmental effect.

Design of a Mobile Probe to Predict Convection Heat Transfer on BIPV （Building Integrated Photovoltaic） at UTS （University of Technology Sydney）

In the absence of a simple technique to predict convection heat transfer on BIPV （building integrated photovoltaic） surfaces, a mobile probe with two thermocouples was designed. Thermal boundary layers on vertical flat surfaces ofa PV （photovoltaic） and a metallic plate were traversed. The plate consisted of twelve heaters where heat flux and surface temperature were controlled and measured. Uniform heat flux condition was developed on the heaters to closely simulate non-uniform temperature distribution on vertical PV modules. The two thermocouples on the probe measured local air temperature and contact temperature with the wall surface. Experimental results were presented in the forms of local Nusselt numbers versus Rayleigh numbers ＂Nu = a＇（Ra）b＇＇, and surface temperature versus dimensionless height （Ts - T∞ = c.（z/h）d）. The constant values for ＂a＂, ＂b＂, ＂c＂ and ＂d＂ were determined from the best curve-fitting to the power-law relation. The convection heat transfer predictions from the empirical correlations were found to be in consistent with those predictions made by a number of correlations published in the open literature. A simple technique is then proposed to employ two experimental data from the probe to refine empirical correlations as the operational conditions change. A flexible technique to update correlations is of prime significance requirement in thermal design and operation of BIPV modules. The work is in progress to further extend the correlation to predict the combined radiation and convection on inclined PVs and channels.

Effect of exhaust gas recirculation and intake pre-heating on performance and emission characteristics of dual fuel engines at part loads

Achieving simultaneous reduction of NOx,CO and unburned hydrocarbon(UHC) emissions without compromising engine performance at part loads is the current focus of dual fuel engine research.The present work focuses on an experimental investigation conducted on a dual fuel(diesel-natural gas) engine to examine the simultaneous effect of inlet air pre-heating and exhaust gas recirculation(EGR) ratio on performance and emission characteristics at part loads.The use of EGR at high levels seems to be unable to improve the engine performance at part loads.However,it is shown that EGR combined with pre-heating of inlet air can slightly increase thermal efficiency,resulting in reduced levels of both unburned hydrocarbon and NOx emissions.CO and UHC emissions are reduced by 24% and 31%,respectively,The NOx emissions decrease by 21% because of the lower combustion temperature due to the much inert gas brought by EGR and decreased oxygen concentration in the cylinder.

Effects of Preheat on the Thermodynamics of the ICF Hot Spot

We determine the dependence of key inertial confinement fusion （ICF） hot spot properties on the deuterium-tritium （DT） fuel adiabat accomplished by addition of heat to the cold shell. Our main result is to observe that variation of this parameter reduces the simulation to experiment discrepancy in several experimentally inferred quantities. Simulations are continued from capsule only l D simulations using the Lawrence Livermore National Laboratory ICF code, HYDRA. The continuations employ the high energy density physics （HEDP） University of Chicago code, FLASH, and a hydro only code, FronTier, modified with a radiation equation of state （EOS） model. Hot spot densities, burn-weighted ion temperatures and pressures show a decreasing trend, while the hot spot radius shows an increasing trend in response to added heat to the cold shell. Instantaneous quantities are assessed at the time of maximum neutron production within each simulation.

Pre-treatment to Enhance Biogas Yield from Pulp and Paper Mill Sludge

The purpose of this work was to study the potential to enhance biogas production from pulp and paper mill sludge by the use of thermal pre-treatment in combination with chemical pre-treatment. Biogas from waste is a renewable fuel with very low emissions during combustion. To further reduce the use of fossil fuels, more biogas substrates are necessary. Pulp and paper mill sludge is a large untapped reservoir of potential biogas. Pulp and paper mill sludge was collected from a mill that produces both pulp and paper and has a modified waste activated sludge system as part of its wastewater treatment. Pre-treatments were chosen heat （70 ~C or 140℃） combined with either acid （pH 2 or pH 4） or base （pH 9 or pH 11, obtained with Ca（OH）2 or NaOH）. Biogas potential was tested by anaerobic digestion batch assays under mesophilic conditions. All pre-treatments were tested in six replicates. Biogas volume was measured with a gas-tight syringe and methane concentration was measured with a gas chromatograph. The methane yield from sludge subjected to thermal pre-treatment at 70℃ did not differ from the untreated sludge, but thermal pre-treatment at 140℃ had a positive effect. Within the 70℃ thermal pre-treatment group, the pH 2 acid was the most successful chemical pre-treatment, and Ca（OH）2 pH 9 had the least effect with no measurable improvement in methane yield. For the 140 ℃ thermal pre-treatment group, acid and NaOH impacted methane production negatively, while the Ca（OH）2-treated sludge did not differ from sludge with no chemical pre-treatment. In conclusion, thermal pre-treatment at 70℃ showed no effect, whereas, pre-treatment at 140℃ improved methane yield with 170%, and for this sludge additional, chemical pre-treatments are unnecessary.

被动式超低能耗居住建筑新风热负荷计算方法研究

随着建筑气密性的不断提高,超低能耗建筑等高性能的建筑机械新风系统逐渐成为决定室内空气品质,影响建筑整体能耗水平的关键因素,其合理设计成为目前亟需深入研究的问题。本文在我国现行空气调节设计规范的基础上,考虑建筑气密性、热回收技术等对建筑新风热负荷的影响,针对严寒及寒冷地区冬季热回收装置存在霜冻、过度预热等问题,提出被动式超低能耗建筑新风系统热负荷及年累计新风热负荷计算方法。该法在计算新风系统热负荷的同时细化预热量的计算,有助于预热装置合理选型,及新风能耗的计算。此外本文还对采用不同室外参数对不同地区热负荷计算造成的误差影响进行分析比较,探讨不同温度运行控制策略对预热量及新风热负荷及年累计新风热负荷的影响。

A measurement-device-independent quantum key distribution protocol with a heralded single photon source

With a heralded single photon source(HSPS), a measurement-device-independent quantum key distribution(MDIQKD) protocol is proposed, combined with a three-intensity decoy-state method. HSPS has the two-mode characteristic, one mode is used as signal mode, and the other is used as heralded mode to reduce the influence of the dark count. The lower bound of the yield and the upper bound of the error rate are deduced and the performance of the MDI-QKD protocol with an HSPS is analyzed. The simulation results show that the MDI-QKD protocol with an HSPS can achieve a key generation rate and a secure transmission distance which are close to the theoretical limits of the protocol with a single photon source(SPS). Moreover, the key generation rate will improve with the raise of the senders' detection efficiency. The key generation rate of the MDI-QKD protocol with an HSPS is a little less than that of the MDI-QKD protocol with a weak coherent source(WCS) in the close range, but will exceed the latter in the far range. Furthermore, a farther transmission distance is obtained due to the two-mode characteristic of HSPS.

Comprehensive Approach for Porous Materials Analysis Using a Dedicated Preprocessing Tool for Mass and Heat Transfer Modeling

The paper presents a comprehensive, newly developed software – poROSE(poROus materials examination SoftwarE) for the qualitative and quantitative assessment of porous materials and analysis methodologies developed by the authors as a solution for emerging challenges. A low porosity rock sample was analyzed and thanks to the developed and implemented methodologies in poROSE software, the main geometrical properties were calculated. A tool was also used in preprocessing part of the computational analysis to prepare a geometrical representation of the porous material. The basic functions as elimination of blind pores in the geometrical model were completed and the geometrical model was exported for CFD software. As a result, it was possible to carry out calculations of the basic properties of the analyzed porous material sample. The developed tool allows to carry out quantitative and qualitative analysis to determine the most important properties characterized porous materials. In presented tool the input data can be images from X-ray computed tomography(CT), scanning electron microscope(SEM) or focused ion beam with scanning electron microscope(FIB-SEM) in grey level. A geometric model developed in the proper format can be used as an input to modeling mass, momentum and heat transfer, as well as, in strength or thermo-strength analysis of any porous materials. In this example, thermal analysis was carried out on the skeleton of rock sample. Moreover, thermal conductivity was estimated using empirical equations.

Prediction of thermal conductivity of polymer-based composites by using support vector regression

Support vector regression (SVR) combined with particle swarm optimization (PSO) for its parameter optimization, was proposed to establish a model to predict the thermal conductivity of polymer-based composites under different mass fractions of fillers (mass fraction of polyethylene (PE) and mass fraction of polystyrene (PS)). The prediction performance of SVR was compared with those of other two theoretical models of spherical packing and flake packing. The result demonstrated that the estimated errors by leave-one-out cross validation (LOOCV) test of SVR models, such as mean absolute error (MAE) and mean absolute percentage error (MAPE), all are smaller than those achieved by the two theoretical models via applying identical samples. It is revealed that the generalization ability of SVR model is superior to those of the two theoretical models. This study suggests that SVR can be used as a powerful approach to foresee the thermal property of polymer-based composites under different mass fractions of polyethylene and polystyrene fillers.