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三官能度过氧化物引发制备HIPS树脂 Ⅰ.预聚合动力学
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作者 王淑敏 李杨 +3 位作者 张春庆 杜晓旭 常丽 王玉荣 《合成树脂及塑料》 CAS 北大核心 2009年第1期6-9,共4页
以多官能度过氧化物3,6,9-三甲基-3,6,9-三乙基-1,4,7-三过氧烷为引发剂,采用本体聚合法制备高抗冲聚苯乙烯,考察了各反应条件对预聚合动力学的影响。结果发现:聚合温度由125℃逐渐升高到145℃和引发剂质量分数由0.0075%增加到0.0200%时... 以多官能度过氧化物3,6,9-三甲基-3,6,9-三乙基-1,4,7-三过氧烷为引发剂,采用本体聚合法制备高抗冲聚苯乙烯,考察了各反应条件对预聚合动力学的影响。结果发现:聚合温度由125℃逐渐升高到145℃和引发剂质量分数由0.0075%增加到0.0200%时,聚合速率逐渐加快;当引发剂质量分数高于0.0200%时,聚合速率变化不大;随着基础胶质量分数由5%增加到15%和乙苯质量分数从10%增加到30%,聚合速率逐渐降低。不同引发剂引发聚合的效果与其官能度、半衰期及聚合温度等因素有关。 展开更多
关键词 高抗冲聚苯乙烯 多官能度引发剂 本体聚合 预聚合动力学
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本体法合成ABS树脂 Ⅱ.预聚合反应动力学研究 被引量:6
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作者 杜晓旭 于志省 +3 位作者 李杨 李永田 黄立本 王玉荣 《合成树脂及塑料》 CAS 北大核心 2009年第6期1-5,共5页
采用本体聚合方法,以1,1-二(叔丁基过氧基)环己烷(DP275B)引发苯乙烯、丙烯腈在聚丁二烯橡胶上接枝共聚合。考察了不同聚合工艺条件下丙烯腈-丁二烯-苯乙烯三元共聚物(ABS)预聚合反应动力学行为规律,并求出相应的假一级表观增长反应速... 采用本体聚合方法,以1,1-二(叔丁基过氧基)环己烷(DP275B)引发苯乙烯、丙烯腈在聚丁二烯橡胶上接枝共聚合。考察了不同聚合工艺条件下丙烯腈-丁二烯-苯乙烯三元共聚物(ABS)预聚合反应动力学行为规律,并求出相应的假一级表观增长反应速率常数。结果表明:不同工艺条件下的动力学曲线均符合一级线性关系;镍系高顺式橡胶BR9004体系的预聚合反应速率最快;增加引发剂DP275B浓度、提高引发温度、降低低顺式聚丁二烯橡胶700A用量和聚合搅拌速率均可加快ABS预聚合反应速率;当w(700A)为5.0%,w(DP275B)为0.021%时,共聚单体的表观增长反应活化能为10.84 kJ/mol,频率因子为0.12 min^(-1)。 展开更多
关键词 丙烯腈-丁二烯-苯乙烯三元共聚物本体聚合 聚合反应动力学 聚丁二烯橡胶
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Dynamics and Predictive Control of Gas Phase Propylene Polymerization in Fluidized Bed Reactors 被引量:4
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作者 Ahmad Shamiri Mohamed azlan Hussain +2 位作者 Farouq sabri Mjalli Navid Mostoufi Seyedahmad Hajimolana~ 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第9期1015-1029,共15页
A two-phase dynamic model, describing gas phase propylene polymerization in a fluidized bed reactor, was used to explore the dynamic behavior and process control of the polypropylene production rate and reactor temper... A two-phase dynamic model, describing gas phase propylene polymerization in a fluidized bed reactor, was used to explore the dynamic behavior and process control of the polypropylene production rate and reactor temperature. The open loop analysis revealed the nonlinear behavior of the polypropylene fluidized bed reactor, jus- tifying the use of an advanced control algorithm for efficient control of the process variables. In this case, a central- ized model predictive control (MPC) technique was implemented to control the polypropylene production rate and reactor temperature by manipulating the catalyst feed rate and cooling water flow rate respectively. The corre- sponding MPC controller was able to track changes in the setpoint smoothly for the reactor temperature and pro- duction rate while the setpoint tracking of the conventional proportional-integral (PI) controller was oscillatory with overshoots and obvious interaction between the reactor temperature and production rate loops. The MPC was able to produce controller moves which not only were well within the specified input constraints for both control vari- ables, but also non-aggressive and sufficiently smooth for practical implementations. Furthermore, the closed loop dynamic simulations indicated that the speed of rejecting the process disturbances for the MPC controller were also acceotable for both controlled variables. 展开更多
关键词 model predictive control fluidized bed reactor propylene polymerization Ziegler-Natta catalyst
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