The release of heavy metals from the combustion of hazardous wastes is an environmental issue of in-creasing concern.The species transformation characteristics of toxic heavy metals and their distribution are consid-e...The release of heavy metals from the combustion of hazardous wastes is an environmental issue of in-creasing concern.The species transformation characteristics of toxic heavy metals and their distribution are consid-ered to be a complex problem of mechanism.The behavior of hazardous dyestuff residue is investigated in a tubular furnace under the general condition of hazardous waste pyrolysis and gasfication.Data interpretation has been aided by parallel theoretical study based on a thermodynamic equilibrium model based on the principle of Gibbs free en-ergy minimization.The results show that Ni,Zn,Mn,and Cr are more enriched in dyestuff residue incineration than other heavy metals(Hg,As,and Se)subjected to volatilization.The thermodynamic model calculation is used for explaining the experiment data at 800℃ and analyzing species transformation of heavy metals.These results of species transformation are used to predict the distribution and emission characteristics of trace elements.Although most trace element predictions are validated by the measurements,cautions are in order due to the complexity of incineration systems.展开更多
基金Supported by the National Natural Science Foundation of China (No.50276055)the Superintendent's Fund of Guangzhou Institute of Energy Conversion,Chinese Academy of Sciences (No.0607ba1001).
文摘The release of heavy metals from the combustion of hazardous wastes is an environmental issue of in-creasing concern.The species transformation characteristics of toxic heavy metals and their distribution are consid-ered to be a complex problem of mechanism.The behavior of hazardous dyestuff residue is investigated in a tubular furnace under the general condition of hazardous waste pyrolysis and gasfication.Data interpretation has been aided by parallel theoretical study based on a thermodynamic equilibrium model based on the principle of Gibbs free en-ergy minimization.The results show that Ni,Zn,Mn,and Cr are more enriched in dyestuff residue incineration than other heavy metals(Hg,As,and Se)subjected to volatilization.The thermodynamic model calculation is used for explaining the experiment data at 800℃ and analyzing species transformation of heavy metals.These results of species transformation are used to predict the distribution and emission characteristics of trace elements.Although most trace element predictions are validated by the measurements,cautions are in order due to the complexity of incineration systems.
