The catalytic oxidation of toluene over Ag/SBA‐15synthesized under different pretreatment conditions,including O2at500°C(denoted O500),H2at500°C(H500),and O2at500°C followed by H2at300°C(O500‐H30...The catalytic oxidation of toluene over Ag/SBA‐15synthesized under different pretreatment conditions,including O2at500°C(denoted O500),H2at500°C(H500),and O2at500°C followed by H2at300°C(O500‐H300)was studied.The pretreated samples were investigated by N2physisorption,X‐ray diffraction,and ultraviolet‐visible diffuse reflectance.The pretreatment atmosphere greatly influences the status of the Ag and O species,which in turn significantly impacts the adsorption and catalytic removal of toluene.Ag2O and amorphous Ag particles,as well as a large amount of subsurface oxygen species,are formed on O500,and the subsurface oxygen enhances the interaction between Ag species and toluene,so O500shows good activity at higher temperature.However,its activity at lower temperature is not as high as expected,with a reduced presence of Ag2O and lower adsorption capacity for toluene.H2pretreatment at500°C is conducive to the formation of large Ag particles and yields the largest adsorption capacity for toluene,so H500exhibits the best activity at lower temperatures;however,because of poor interaction between Ag and toluene,its activity at higher temperature is modest.The O500‐H300sample exhibits excellent catalytic activity during the whole reaction process,which can be attributed to the small and highly dispersed Ag nanoparticles as well as the existence of subsurface oxygen.展开更多
Including information of the current road surface conditions can significantly improve the effectiveness of an AEB （automated emergency braking） system to avoid accidents or reduce the injury severity in rear-end cr...Including information of the current road surface conditions can significantly improve the effectiveness of an AEB （automated emergency braking） system to avoid accidents or reduce the injury severity in rear-end crashes. A method to estimate the friction potential based on on-board sensor information is shown in this work. This work expands the scope of existing investigations on whether the accuracy needed for the warning and intervention strategies of AEB can be reached with the proposed method. First, the bandwidth of surface conditions investigated is extended by including low friction surfaces comparable to ice. Second, situations of changing surface conditions and wheel-individual surface conditions were evaluated. Finally, estimation based on different sensor sets was conducted with regard to series application. The investigations are based on measurements performed on a proving ground. The main emphasis was placed on estimation during longitudinal driving conditions. The used sensors include advanced vehicle dynamics measurement equipment as well as standard on-board sensors of the vehicle.展开更多
基金supported by the National Natural Science Foundation of China(21377016,21577014)Program for Changjiang Scholars and Innovative Research Team in University(IRT_13R05)~~
文摘The catalytic oxidation of toluene over Ag/SBA‐15synthesized under different pretreatment conditions,including O2at500°C(denoted O500),H2at500°C(H500),and O2at500°C followed by H2at300°C(O500‐H300)was studied.The pretreated samples were investigated by N2physisorption,X‐ray diffraction,and ultraviolet‐visible diffuse reflectance.The pretreatment atmosphere greatly influences the status of the Ag and O species,which in turn significantly impacts the adsorption and catalytic removal of toluene.Ag2O and amorphous Ag particles,as well as a large amount of subsurface oxygen species,are formed on O500,and the subsurface oxygen enhances the interaction between Ag species and toluene,so O500shows good activity at higher temperature.However,its activity at lower temperature is not as high as expected,with a reduced presence of Ag2O and lower adsorption capacity for toluene.H2pretreatment at500°C is conducive to the formation of large Ag particles and yields the largest adsorption capacity for toluene,so H500exhibits the best activity at lower temperatures;however,because of poor interaction between Ag and toluene,its activity at higher temperature is modest.The O500‐H300sample exhibits excellent catalytic activity during the whole reaction process,which can be attributed to the small and highly dispersed Ag nanoparticles as well as the existence of subsurface oxygen.
文摘Including information of the current road surface conditions can significantly improve the effectiveness of an AEB （automated emergency braking） system to avoid accidents or reduce the injury severity in rear-end crashes. A method to estimate the friction potential based on on-board sensor information is shown in this work. This work expands the scope of existing investigations on whether the accuracy needed for the warning and intervention strategies of AEB can be reached with the proposed method. First, the bandwidth of surface conditions investigated is extended by including low friction surfaces comparable to ice. Second, situations of changing surface conditions and wheel-individual surface conditions were evaluated. Finally, estimation based on different sensor sets was conducted with regard to series application. The investigations are based on measurements performed on a proving ground. The main emphasis was placed on estimation during longitudinal driving conditions. The used sensors include advanced vehicle dynamics measurement equipment as well as standard on-board sensors of the vehicle.
