The mechanical properties of outwash deposits which are taken as unconsolidated geo-materials with the characteristics of non-uniformity, heterogeneity and multiphase have attracted much attention in engineering. Acco...The mechanical properties of outwash deposits which are taken as unconsolidated geo-materials with the characteristics of non-uniformity, heterogeneity and multiphase have attracted much attention in engineering. According to the results of laboratory direct shear test on the remolded samples, the soil particle parameters of numerical model based on in-situ particle size cumulative curves and 3D granular discrete element method were determined. Then, numerical experiments on different lithology, stone content and gradation composition were conducted. The results show that it is not a flat surface but a shear band that yields in the sample. The curve of particle velocity vs distance from the designed shear surface of test model that is taken as a datum plane in the vertical section of sample shows in "S" shape. The shear disturbance area is about twice the maximum diameter of stone blocks. The greater the stiffness of stone is, the rougher the shear surface is. The shear strength of outwash deposits is largely controlled by lithology and stone content, and the bite force between stone blocks is the root reason of larger friction angle. It is also shown that strain hardening and low shear dilatancy occur under high confining pressure as well as possibility of shear shrinkage. But it is easy to behave shear dilatation and strain softening under low confining pressure. The relationship between particle frictional coefficient and stone content presents an approximately quadratic parabola increase. The strain energy first increases and then drops with the increase of frictional energy. The cohesion increases with soil stiffness increasing but decreases with stone stiffness increasing. Numerical results are consistent with the laboratory test results of remolded samples, which indicate that this method can be a beneficial supplement to determine the parameters of engineering deposit bodies.展开更多
The hydrophobic films of TixOy-CmHn. deposited from mixture gases of titanium isopropoxide （TTIP） and oxygen by plasma enhanced chemical vapor deposition （PECVD） were investigated. The films were investigated by s...The hydrophobic films of TixOy-CmHn. deposited from mixture gases of titanium isopropoxide （TTIP） and oxygen by plasma enhanced chemical vapor deposition （PECVD） were investigated. The films were investigated by scanning electron microscope （ SEM ）, transmission electron microscope （ TEM ）, Fourier transform infrared spectrometer （ FTIR）, X-Ray diffraction （ XRD ）, element analysis （ EA ）, ultraviolet visible spectrometer （ UV-Vis）, and water contact angle （WCA）. The results reveal that the surface of the films is formed by mierosized papillaes aggregated by inorganic and organic phases of complex nanoparticles with size from 50 nm to 200 nm when the discharge power is increased from 40 W to 150 W. All fdms demonstrate the strong broad of Ti-O-Ti stretching vibration at 400 -800cm-1, -CH bending vibration at 1 388 cm -1, and broadening -OH stretching vibration at 3 000-3500 cm-1 With the increase of the discharge power, the asdeposited film changes from amorphous to crystallization. The WCA of the film can be as high as 160°, indicating the hydrophobicity. The films show a similar ultraviolet absorption property as the bulk TiO2 film. The composition of the composition of film deposited at 150 W can be formulated as Tio.302-C1.5H3. Therefore, the composition formula of this hydrophobic film could be expressed as TiO2-C5H10O4.7. It is believed that the complex micro/nano structures of TiO2 and C5H10O4.7 residues are responsible for the observed hydrophobicity and the ultraviolet absorption property of the film.展开更多
基金Project(2011CB013504) supported by the National Basic Research Program of ChinaProjects(50911130366, 11172090) supported by the National Natural Science Foundation of ChinaProject supported by Central University Basic Research Special Fund, China
文摘The mechanical properties of outwash deposits which are taken as unconsolidated geo-materials with the characteristics of non-uniformity, heterogeneity and multiphase have attracted much attention in engineering. According to the results of laboratory direct shear test on the remolded samples, the soil particle parameters of numerical model based on in-situ particle size cumulative curves and 3D granular discrete element method were determined. Then, numerical experiments on different lithology, stone content and gradation composition were conducted. The results show that it is not a flat surface but a shear band that yields in the sample. The curve of particle velocity vs distance from the designed shear surface of test model that is taken as a datum plane in the vertical section of sample shows in "S" shape. The shear disturbance area is about twice the maximum diameter of stone blocks. The greater the stiffness of stone is, the rougher the shear surface is. The shear strength of outwash deposits is largely controlled by lithology and stone content, and the bite force between stone blocks is the root reason of larger friction angle. It is also shown that strain hardening and low shear dilatancy occur under high confining pressure as well as possibility of shear shrinkage. But it is easy to behave shear dilatation and strain softening under low confining pressure. The relationship between particle frictional coefficient and stone content presents an approximately quadratic parabola increase. The strain energy first increases and then drops with the increase of frictional energy. The cohesion increases with soil stiffness increasing but decreases with stone stiffness increasing. Numerical results are consistent with the laboratory test results of remolded samples, which indicate that this method can be a beneficial supplement to determine the parameters of engineering deposit bodies.
基金Foundation items: National Natural Science Foundations of China (No.10835004,No.10775031)Science and Technology Commission of Shanghai Municipality,China (No. 10XD1400100)
文摘The hydrophobic films of TixOy-CmHn. deposited from mixture gases of titanium isopropoxide （TTIP） and oxygen by plasma enhanced chemical vapor deposition （PECVD） were investigated. The films were investigated by scanning electron microscope （ SEM ）, transmission electron microscope （ TEM ）, Fourier transform infrared spectrometer （ FTIR）, X-Ray diffraction （ XRD ）, element analysis （ EA ）, ultraviolet visible spectrometer （ UV-Vis）, and water contact angle （WCA）. The results reveal that the surface of the films is formed by mierosized papillaes aggregated by inorganic and organic phases of complex nanoparticles with size from 50 nm to 200 nm when the discharge power is increased from 40 W to 150 W. All fdms demonstrate the strong broad of Ti-O-Ti stretching vibration at 400 -800cm-1, -CH bending vibration at 1 388 cm -1, and broadening -OH stretching vibration at 3 000-3500 cm-1 With the increase of the discharge power, the asdeposited film changes from amorphous to crystallization. The WCA of the film can be as high as 160°, indicating the hydrophobicity. The films show a similar ultraviolet absorption property as the bulk TiO2 film. The composition of the composition of film deposited at 150 W can be formulated as Tio.302-C1.5H3. Therefore, the composition formula of this hydrophobic film could be expressed as TiO2-C5H10O4.7. It is believed that the complex micro/nano structures of TiO2 and C5H10O4.7 residues are responsible for the observed hydrophobicity and the ultraviolet absorption property of the film.
