The most prospective method for certain structural failures and damages that cannot employ redundancy is self-repairing techniques, to ensure especially the maximum flight safety. Based on the characters of self-repai...The most prospective method for certain structural failures and damages that cannot employ redundancy is self-repairing techniques, to ensure especially the maximum flight safety. Based on the characters of self-repairing aircraft, this paper states some basic assumptions of the self-repairing aircraft, and puts forward some special new conceptions concerning the self-repairing aircraft: control input, operating input, command input, repair input and operating and control factor as well as their relationships. Thus it provides a simple and reliable mathematical model structure for the research on the self-repairing control of the aircraft.展开更多
A new electron impact storage ion source has been designed for time of flight mass spectrometers with a high mass resolving power and high sensitivity. Because of the storage and compressing focus of the source, the o...A new electron impact storage ion source has been designed for time of flight mass spectrometers with a high mass resolving power and high sensitivity. Because of the storage and compressing focus of the source, the overall performance of the instrument has been improved greatly with a mass resolving power up to 3 500. The conditions of the second order of the focus are given and the storage ability is proved. The competer simulations and experiment results are given, too.展开更多
The wavelength dependence of photoelectron angular distributions (PADs) of two-photon detachment of Cu^- has been directly studied by using the photoelectron map imaging. Results show that for the laser field intens...The wavelength dependence of photoelectron angular distributions (PADs) of two-photon detachment of Cu^- has been directly studied by using the photoelectron map imaging. Results show that for the laser field intensity of 6.0×10^10W/cm^2, PADs exhibit dramatic change with the external field wavelength. Comparison between the experimental observation and the lowest-order perturbation theory prediction indicates that the pattern of PADs can be explained by the interference of the s and d partial waves in the final state. Relative contri- butions of s and d partial waves in the two-photon detachment at different laser wavelengths are obtained.展开更多
The reactions of anionic zirconium oxide clusters ZrxOy- with C2H6 and C4H10 are investi-gated by a time of flight mass spectrometer coupled with a laser vaporization cluster source.Hydrogen containing products Zr2O5H...The reactions of anionic zirconium oxide clusters ZrxOy- with C2H6 and C4H10 are investi-gated by a time of flight mass spectrometer coupled with a laser vaporization cluster source.Hydrogen containing products Zr2O5H- and Zr3O7H- are observed after the reaction. Den-sity functional theory calculations indicate that the hydrogen abstraction is favorable in the reaction of Zr2O5- with C2H6, which supports that the observed Zr2O5H- and Zr3O7H- are due to hydrogen atom abstraction from the alkane molecules. This work shows a newpossible pathway in the reaction of zirconium oxide cluster anions with alkane molecules.展开更多
We present a remote three-party quantum state sharing (QSTS) scheme with three-atom Greenberger- Horne-Zeilinger (GHZ) states assisted by cavity QED and flying qubits. It exploits some photons to act as the flying...We present a remote three-party quantum state sharing (QSTS) scheme with three-atom Greenberger- Horne-Zeilinger (GHZ) states assisted by cavity QED and flying qubits. It exploits some photons to act as the flying qubits for setting up the quantum channel securely with three-atom systems in a GHZ state, which maybe make this remote QSTS scheme more practical than some other schemes based on atom systems only or ion-trap systems as photons interact with their environments weakly. The coherence of the stationary atom qubits in cavities provides the convenience for the parties in QSTS to check eavesdropping, different from entangled photon systems. Moreover, the present scheme works in a collective-noise condition and it may be more practical than others in applications in future.展开更多
The number concentrations and drop size distributions(DSDs)of warm-rain hydrometeors play an important role in the simulation of microphysical processes.To evaluate the performance of the WDM6 scheme,which predicts th...The number concentrations and drop size distributions(DSDs)of warm-rain hydrometeors play an important role in the simulation of microphysical processes.To evaluate the performance of the WDM6 scheme,which predicts the cloud number concentration(Nc)explicitly in aspects of warm-rain hydrometeors number concentrations and DSDs,the simulation of the WDM6 scheme is compared with airborne observations of a flight trial,as well as with the simulations of the Thompson scheme and Morrison scheme.Results show that the WDM6 scheme produces smaller(larger)cloud(rain)number concentrations and wider cloud DSDs compared to the observations,with the largest biases at upper levels of stratiform cloud(SC).The Thompson scheme and the Morrison scheme,both of which set the Nc as a constant,compare better to the observations than the WDM6 scheme in aspects of Nc and DSD.Sensitivity tests of the initial cloud condensation nuclei(CCN)number concentration(CCN0)of the WDM6 scheme show that a better choice of the initial CCN0 may improve the simulation of convective cloud but helps little in terms of SC.The simulation of rain number concentration and DSD is not sensitive to the CCN0 in the WDM6 scheme.展开更多
A new pulsed helium nano droplets machine has been constructed. The droplets were gener- ated by expansion of the pure helium through the cryogenic valve attached to a closed-cycle cryostat. The mean size of helium dr...A new pulsed helium nano droplets machine has been constructed. The droplets were gener- ated by expansion of the pure helium through the cryogenic valve attached to a closed-cycle cryostat. The mean size of helium droplets can be controlled between 103 and 105 helium atoms by tuning the backing pressure (10-40 bar) and temperature (10-30 K). Compared with the continuous-flow beam source, the density of droplet is at least one order of magni- tude higher, which offers the opportunity to combine the system with the commercial pulsed laser to study chemical reactions inside of the superfluid helium at ultra-low temperature. The performance for the system has been checked by studying the photodissociation of CH3I doped droplets at 252 nm with the velocity map imaging technique. The photofragments, CH3, were detected by (2+1) resonance enhanced multiphoton ionization. The speed and angular distributions derived from resulting images show clear evidence of the relaxation effect by the surrounding helium atoms. The pulsed helium droplets depletion spectroscopy was also demonstrated. The depletion spectrum of benzene doped helium droplets indicates that less than 3% depletion can be observed with the newly constructed apparatus.展开更多
A surface femtosecond two-photon photoemission (2PPE) spectrometer devoted to the study of ultrafast excited electron dynamics and photochemical kinetics on metal and metal oxide surfaces has been constructed. Low e...A surface femtosecond two-photon photoemission (2PPE) spectrometer devoted to the study of ultrafast excited electron dynamics and photochemical kinetics on metal and metal oxide surfaces has been constructed. Low energy photoelectrons are measured using a hemispherical electron energy analyzer with an imaging detector that allows us to detect the energy and the angular distributions of the photoelectrons simultaneously. A Mach-Zehnder interferom- eter was built for the time-resolved 2PPE (TR-2PPE) measurement to study ultrafast surface excited electron dynamics, which was demonstrated on the Cu(111) surface. A scheme for measuring time-dependent 2PPE (TD-2PPE) spectra has also been developed for studies of surface photochemistry. This technique has been applied to a preliminary study on the photochemical kinetics on ethanol/TiO2(110). We have also shown that the ultrafast dynamics of photoinduced surface excited resonances can be investigated in a reliable way by combining the TR-2PPE and TD-2PPE techniques.展开更多
We introduce a modification of reflectron time-of-flight mass spectrometer for laser photodissociation of mass-selected ions. In our apparatus, the ions of interests were selected by a mass gate near the first space f...We introduce a modification of reflectron time-of-flight mass spectrometer for laser photodissociation of mass-selected ions. In our apparatus, the ions of interests were selected by a mass gate near the first space focus point and decelerated right after the mass gate, were then crossed by a laser beam for dissociation. The daughter ions and surviving parent ions were re-accelerated and analyzed by the reflectron time-of-flight mass spectrometer. Compared to the designs reported by other research groups, our selection-deceleration-dissociation-reacceleration approach has better daughter-parent-ions-separation, easier laser timing, and better overlapping between the ion beam and laser beam. We also conducted detailed cal- culations on the parent ion and daughter ion flight times, and provided a simplified formula for the calibration of daughter ion mass.展开更多
A new velocity map imaging spectrometer is constructed for molecular reaction dynamics studies using time-resolved photoelectron/ion spectroscopy method. By combining a kHz pulsed valve and an ICCD camera, this veloci...A new velocity map imaging spectrometer is constructed for molecular reaction dynamics studies using time-resolved photoelectron/ion spectroscopy method. By combining a kHz pulsed valve and an ICCD camera, this velocity map imaging spectrometer can be run at a repetition rate of 1 kHz, totally compatible with the fs Ti:Sapphire laser system, facilitating time-resolved studies in gas phase which are usually time-consuming. Time-resolved velocity map imaging study of NH3 photodissociation at 200 nm was performed and the time-resolved total kinetic energy release spectrum of H+NH~ products provides rich information about the dissociation dynamics of NH3. These results show that this new apparatus is a powerful tool for investigating the molecular reaction dynamics using time-resolved methods.展开更多
fragments, F- and Cl- including two isotope species 35Cl- and 37Cl-, are observed in the photoexcitations of CFC13. The ion-pair anion efficiency spectra of 35Cl- and 37Cl- are recorded in the photon energy range of 7...fragments, F- and Cl- including two isotope species 35Cl- and 37Cl-, are observed in the photoexcitations of CFC13. The ion-pair anion efficiency spectra of 35Cl- and 37Cl- are recorded in the photon energy range of 7.75-22.00 eV. The threshold of ion-pair dissociation CFCl3-CFC12++Cl- is experimentally determined to be 7.944-0.04 eV. With the references of the high-resolution photoabsorption spectra reported in the literatures, we make tentative assignments of the electron valence-to-Rydberg transitions. Furthermore, the multibody ion-pair fragmentation processes to Cl- are discussed by comparison between the calculated thermochemical thresholds and the experimental efficiency spectrum.展开更多
A while ago a Dickinson College studentasked the white-haired chairman of the Eng-lish department if he had ever read Tolstoy’sWar and Peace from cover to cover.The el-derly don considered his answer before speak-
文摘The most prospective method for certain structural failures and damages that cannot employ redundancy is self-repairing techniques, to ensure especially the maximum flight safety. Based on the characters of self-repairing aircraft, this paper states some basic assumptions of the self-repairing aircraft, and puts forward some special new conceptions concerning the self-repairing aircraft: control input, operating input, command input, repair input and operating and control factor as well as their relationships. Thus it provides a simple and reliable mathematical model structure for the research on the self-repairing control of the aircraft.
文摘A new electron impact storage ion source has been designed for time of flight mass spectrometers with a high mass resolving power and high sensitivity. Because of the storage and compressing focus of the source, the overall performance of the instrument has been improved greatly with a mass resolving power up to 3 500. The conditions of the second order of the focus are given and the storage ability is proved. The competer simulations and experiment results are given, too.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China (No.21073188).
文摘The wavelength dependence of photoelectron angular distributions (PADs) of two-photon detachment of Cu^- has been directly studied by using the photoelectron map imaging. Results show that for the laser field intensity of 6.0×10^10W/cm^2, PADs exhibit dramatic change with the external field wavelength. Comparison between the experimental observation and the lowest-order perturbation theory prediction indicates that the pattern of PADs can be explained by the interference of the s and d partial waves in the final state. Relative contri- butions of s and d partial waves in the two-photon detachment at different laser wavelengths are obtained.
基金This work was supported by the Chinese Academy of Sciences (Hundred Talents Fund), the National Natural Science Foundation of China (No.20703048 and No.20803083), and the Center of Molecular Science Foundation of Institute of Chemistry, Chinese Academy of Sciences (No.CMS-LX200902).
文摘The reactions of anionic zirconium oxide clusters ZrxOy- with C2H6 and C4H10 are investi-gated by a time of flight mass spectrometer coupled with a laser vaporization cluster source.Hydrogen containing products Zr2O5H- and Zr3O7H- are observed after the reaction. Den-sity functional theory calculations indicate that the hydrogen abstraction is favorable in the reaction of Zr2O5- with C2H6, which supports that the observed Zr2O5H- and Zr3O7H- are due to hydrogen atom abstraction from the alkane molecules. This work shows a newpossible pathway in the reaction of zirconium oxide cluster anions with alkane molecules.
基金Supported by the National Natural Science Foundation of China under Grant No.10974020the Fundamental Research Funds for the Central Universities
文摘We present a remote three-party quantum state sharing (QSTS) scheme with three-atom Greenberger- Horne-Zeilinger (GHZ) states assisted by cavity QED and flying qubits. It exploits some photons to act as the flying qubits for setting up the quantum channel securely with three-atom systems in a GHZ state, which maybe make this remote QSTS scheme more practical than some other schemes based on atom systems only or ion-trap systems as photons interact with their environments weakly. The coherence of the stationary atom qubits in cavities provides the convenience for the parties in QSTS to check eavesdropping, different from entangled photon systems. Moreover, the present scheme works in a collective-noise condition and it may be more practical than others in applications in future.
基金sponsored by the National Natural Science Foundation of China [grant number 41530427 and41875172]supported by the demonstration project of artificial precipitation enhancement and hail suppression operation technology at the eastern side of Taihang Mountains [Grant No.hbrywcsy-2017-2]
文摘The number concentrations and drop size distributions(DSDs)of warm-rain hydrometeors play an important role in the simulation of microphysical processes.To evaluate the performance of the WDM6 scheme,which predicts the cloud number concentration(Nc)explicitly in aspects of warm-rain hydrometeors number concentrations and DSDs,the simulation of the WDM6 scheme is compared with airborne observations of a flight trial,as well as with the simulations of the Thompson scheme and Morrison scheme.Results show that the WDM6 scheme produces smaller(larger)cloud(rain)number concentrations and wider cloud DSDs compared to the observations,with the largest biases at upper levels of stratiform cloud(SC).The Thompson scheme and the Morrison scheme,both of which set the Nc as a constant,compare better to the observations than the WDM6 scheme in aspects of Nc and DSD.Sensitivity tests of the initial cloud condensation nuclei(CCN)number concentration(CCN0)of the WDM6 scheme show that a better choice of the initial CCN0 may improve the simulation of convective cloud but helps little in terms of SC.The simulation of rain number concentration and DSD is not sensitive to the CCN0 in the WDM6 scheme.
基金The authors would like to thank Dr. Ze-feng Ren for the assistance with the design at the early stage, and Prof. Andrey Vilesov for helpful discussions. This work was supported by the Startup Grant of Dalian In- stitute of Chemical Physics, one Hundred Talents Pro- gram of Chinese Academy of Sciences, the Knowledge Innovation Program of Chinese Academy of Sciences, and the National Natural Science Foundation of China (No.21073187).
文摘A new pulsed helium nano droplets machine has been constructed. The droplets were gener- ated by expansion of the pure helium through the cryogenic valve attached to a closed-cycle cryostat. The mean size of helium droplets can be controlled between 103 and 105 helium atoms by tuning the backing pressure (10-40 bar) and temperature (10-30 K). Compared with the continuous-flow beam source, the density of droplet is at least one order of magni- tude higher, which offers the opportunity to combine the system with the commercial pulsed laser to study chemical reactions inside of the superfluid helium at ultra-low temperature. The performance for the system has been checked by studying the photodissociation of CH3I doped droplets at 252 nm with the velocity map imaging technique. The photofragments, CH3, were detected by (2+1) resonance enhanced multiphoton ionization. The speed and angular distributions derived from resulting images show clear evidence of the relaxation effect by the surrounding helium atoms. The pulsed helium droplets depletion spectroscopy was also demonstrated. The depletion spectrum of benzene doped helium droplets indicates that less than 3% depletion can be observed with the newly constructed apparatus.
文摘A surface femtosecond two-photon photoemission (2PPE) spectrometer devoted to the study of ultrafast excited electron dynamics and photochemical kinetics on metal and metal oxide surfaces has been constructed. Low energy photoelectrons are measured using a hemispherical electron energy analyzer with an imaging detector that allows us to detect the energy and the angular distributions of the photoelectrons simultaneously. A Mach-Zehnder interferom- eter was built for the time-resolved 2PPE (TR-2PPE) measurement to study ultrafast surface excited electron dynamics, which was demonstrated on the Cu(111) surface. A scheme for measuring time-dependent 2PPE (TD-2PPE) spectra has also been developed for studies of surface photochemistry. This technique has been applied to a preliminary study on the photochemical kinetics on ethanol/TiO2(110). We have also shown that the ultrafast dynamics of photoinduced surface excited resonances can be investigated in a reliable way by combining the TR-2PPE and TD-2PPE techniques.
基金V. ACKNOWLEDGMENTS This work supported by the National Natural Science Foundation of China (No.20853001). We thank Professor Qi-he Zhu and Professor Zhen Gao for valuable discussions.
文摘We introduce a modification of reflectron time-of-flight mass spectrometer for laser photodissociation of mass-selected ions. In our apparatus, the ions of interests were selected by a mass gate near the first space focus point and decelerated right after the mass gate, were then crossed by a laser beam for dissociation. The daughter ions and surviving parent ions were re-accelerated and analyzed by the reflectron time-of-flight mass spectrometer. Compared to the designs reported by other research groups, our selection-deceleration-dissociation-reacceleration approach has better daughter-parent-ions-separation, easier laser timing, and better overlapping between the ion beam and laser beam. We also conducted detailed cal- culations on the parent ion and daughter ion flight times, and provided a simplified formula for the calibration of daughter ion mass.
基金This work was supported by the National Basic Research Program of China (No.2013CB922200), the Ministry of Science and Technology of China (No.2012YQ12004704), and the National Natural Science Foundation of China (No.21573228).
文摘A new velocity map imaging spectrometer is constructed for molecular reaction dynamics studies using time-resolved photoelectron/ion spectroscopy method. By combining a kHz pulsed valve and an ICCD camera, this velocity map imaging spectrometer can be run at a repetition rate of 1 kHz, totally compatible with the fs Ti:Sapphire laser system, facilitating time-resolved studies in gas phase which are usually time-consuming. Time-resolved velocity map imaging study of NH3 photodissociation at 200 nm was performed and the time-resolved total kinetic energy release spectrum of H+NH~ products provides rich information about the dissociation dynamics of NH3. These results show that this new apparatus is a powerful tool for investigating the molecular reaction dynamics using time-resolved methods.
文摘fragments, F- and Cl- including two isotope species 35Cl- and 37Cl-, are observed in the photoexcitations of CFC13. The ion-pair anion efficiency spectra of 35Cl- and 37Cl- are recorded in the photon energy range of 7.75-22.00 eV. The threshold of ion-pair dissociation CFCl3-CFC12++Cl- is experimentally determined to be 7.944-0.04 eV. With the references of the high-resolution photoabsorption spectra reported in the literatures, we make tentative assignments of the electron valence-to-Rydberg transitions. Furthermore, the multibody ion-pair fragmentation processes to Cl- are discussed by comparison between the calculated thermochemical thresholds and the experimental efficiency spectrum.
文摘A while ago a Dickinson College studentasked the white-haired chairman of the Eng-lish department if he had ever read Tolstoy’sWar and Peace from cover to cover.The el-derly don considered his answer before speak-