Effects of polycarboxylate type admixture（PCA）on calcium monocarboaluminate hydrate（AFmc）formation in hydrated cement paste containing limestone filler（LF）are investigated by the Fourier transform infrared spect...Effects of polycarboxylate type admixture（PCA）on calcium monocarboaluminate hydrate（AFmc）formation in hydrated cement paste containing limestone filler（LF）are investigated by the Fourier transform infrared spectroscopy（FTIR）,the scanning electron microscopy（SEM）,the derivative thermogravimetric（DTG）analysis and the adsorption amount measurement.Experimental results indicate that AFmc forms during the initial hydration period of cement as early as 15 min.It is found that PCA accelerates the early age AFmc formation and enhances cement hydration by promoting C4AF hydration at the early age,and,as a consequence,the iron associated AFmc phase forms more readily.The phenomenon is not observed when PCA is replaced by a naphthalene formaldehyde sulphonate condensate water reducer.Compatibility between PCA and cement is modified due to the presence of AFmc along with ettringite（AFt）,which results in a less adsorption amount of PCA on the surface of cement minerals.As a kind of high-range water reducer,PCA may be the preferred choice for concrete containing LF.展开更多
The high-flowing sand-concrete （HFSC） containing natural sands as aggregate was carried out. The high fluidity and stability of HFSC can be achieved by tailoring the mix design parameters, such as fine to coarse san...The high-flowing sand-concrete （HFSC） containing natural sands as aggregate was carried out. The high fluidity and stability of HFSC can be achieved by tailoring the mix design parameters, such as fine to coarse sand ratio, dosage of additions, water to binder ratio and dosage of admixtures. Mini-cone slump test, v-fl.mnel time test and viscosity model parameters were used to characterize the behaviour of HFSC in fresh state. The mechanical compressive strength in 28 d was also determined. A factorial design approach was used to establish models highlighting the effect of each mix-parameter on measured properties of HFSC. The derived models are valid for mixtures made with 0 to 0.3 of dune sand to total sand ratio, 82 to 418 kg/m3 of marble powder, 0.42 to 0.46 of water/binder ratio and 1.3% to 1.9% of superplasticizer high water-reducer. The results show that the derived models constitute very efficient means for understanding the influence of key mix-parameters on HFSC properties and are useful in selecting the optimum mix proportions, by simulating their impact on fluidity, stability and compressive strength.展开更多
The properties of the self-compacting concrete mix depend on an automatic introduction of air bubbles caught during the process of mixing. What is interesting, the criterion for self-compactibility is not taken into c...The properties of the self-compacting concrete mix depend on an automatic introduction of air bubbles caught during the process of mixing. What is interesting, the criterion for self-compactibility is not taken into consideration in commonly used self-compacting tests. On the basis of different tests concerning self-compacting concrete mixes, it has been found out that too high air content in their volume was the result of superplasticizer, in spite of meeting the self-compactibility criteria （i.e., self-venting）. For the decrease of too high air volume in SCC, the use of anti-foaming admixture （AFA） is proposed. As a result, the effect of AFA mix flow diameter is increased and the flow time is decreased. Moreover, the workability loss is lower. In case of mix incorporating AFA, their high flowability does not cause segregation of the mix, what is possible in case of SCC incorporating only superplasticizer. However, the time of the introduction of AFA and its type is essential to get higher flowability degree, but it is not important to achieve low air volume in SCC.展开更多
基金The Natural Science Foundation of Jiangsu Province(No.BK2009712)the National Construction Research Project(No.2009-K4-9)
文摘Effects of polycarboxylate type admixture（PCA）on calcium monocarboaluminate hydrate（AFmc）formation in hydrated cement paste containing limestone filler（LF）are investigated by the Fourier transform infrared spectroscopy（FTIR）,the scanning electron microscopy（SEM）,the derivative thermogravimetric（DTG）analysis and the adsorption amount measurement.Experimental results indicate that AFmc forms during the initial hydration period of cement as early as 15 min.It is found that PCA accelerates the early age AFmc formation and enhances cement hydration by promoting C4AF hydration at the early age,and,as a consequence,the iron associated AFmc phase forms more readily.The phenomenon is not observed when PCA is replaced by a naphthalene formaldehyde sulphonate condensate water reducer.Compatibility between PCA and cement is modified due to the presence of AFmc along with ettringite（AFt）,which results in a less adsorption amount of PCA on the surface of cement minerals.As a kind of high-range water reducer,PCA may be the preferred choice for concrete containing LF.
文摘The high-flowing sand-concrete （HFSC） containing natural sands as aggregate was carried out. The high fluidity and stability of HFSC can be achieved by tailoring the mix design parameters, such as fine to coarse sand ratio, dosage of additions, water to binder ratio and dosage of admixtures. Mini-cone slump test, v-fl.mnel time test and viscosity model parameters were used to characterize the behaviour of HFSC in fresh state. The mechanical compressive strength in 28 d was also determined. A factorial design approach was used to establish models highlighting the effect of each mix-parameter on measured properties of HFSC. The derived models are valid for mixtures made with 0 to 0.3 of dune sand to total sand ratio, 82 to 418 kg/m3 of marble powder, 0.42 to 0.46 of water/binder ratio and 1.3% to 1.9% of superplasticizer high water-reducer. The results show that the derived models constitute very efficient means for understanding the influence of key mix-parameters on HFSC properties and are useful in selecting the optimum mix proportions, by simulating their impact on fluidity, stability and compressive strength.
文摘The properties of the self-compacting concrete mix depend on an automatic introduction of air bubbles caught during the process of mixing. What is interesting, the criterion for self-compactibility is not taken into consideration in commonly used self-compacting tests. On the basis of different tests concerning self-compacting concrete mixes, it has been found out that too high air content in their volume was the result of superplasticizer, in spite of meeting the self-compactibility criteria （i.e., self-venting）. For the decrease of too high air volume in SCC, the use of anti-foaming admixture （AFA） is proposed. As a result, the effect of AFA mix flow diameter is increased and the flow time is decreased. Moreover, the workability loss is lower. In case of mix incorporating AFA, their high flowability does not cause segregation of the mix, what is possible in case of SCC incorporating only superplasticizer. However, the time of the introduction of AFA and its type is essential to get higher flowability degree, but it is not important to achieve low air volume in SCC.
