Corrosion has always been a difficult problem that troubles and restricts the application and development ofengineering materials.By endowing coatings on metal surfaces with polymer material,it is possible to protect ...Corrosion has always been a difficult problem that troubles and restricts the application and development ofengineering materials.By endowing coatings on metal surfaces with polymer material,it is possible to protect othermaterials from factors including acid and alkali,water vapor,bacteria.Therefore,it is necessary to summarize theresearch progress of polymer materials in the field of pollution and corrosion prevention in recent years.This articlesummarizes four types of polymer materials with good weather resistance:polyurethane(PU),polydimethylsiloxane(PDMS),polyvinylidene fluoride(PVDF),and polyvinylidene chloride(PVDC).These four polymer materials aresuitable for making polymer anti-corrosion or anti-fouling materials and each has its own characteristics.PU can firmlyadhere to various substrates,effectively protecting and extending their lifespan,but the environmentally friendly varietiescurrently used,namely water-borne polyurethanes(WPU),generally have poor mechanical properties.PDMS is nontoxicand has excellent hydrophobicity,but its static anti-fouling ability is insufficient when applied in the field of antifouling.PVDF has good chemical resistance and high mechanical properties,good UV resistance making it suitable foroutdoor use like in the marine environment.However,PVDF lacks flexibility after molding and its manufacturing cost isrelatively high.PVDC has excellent water vapor barrier properties,but poor adhesion to metal material surfaces.Therefore,researchers need to modify these four polymers when using them to solve the problem of corrosion orbiofouling.The article will review the research progress of four types of polymers in recent years from the perspectivesof anti-corrosion,anti-fouling,and a strategy named as self-healing that is beneficial for protecting polymer surfacesfrom mechanical damage,and summarize the modification methods adopted by researchers when applying thesematerials.Finally,a summary of the application and the prospects of these polymer materials are presented.展开更多
Self-healing polymers represent a class of materials with built-in capability of rehabilitating damages. The topic has attracted increasingly more attention in the past few years. The on-going research activities clea...Self-healing polymers represent a class of materials with built-in capability of rehabilitating damages. The topic has attracted increasingly more attention in the past few years. The on-going research activities clearly indicate that self-healing polymeric materials turn out to be a typical multi-disciplinary area concerning polymer chemistry, organic synthesis, polymer physics, theoretical and experimental mechanics, processing, composites manufacturing, interfacial engineering, etc. The present article briefly reviews the achievements of the groups worldwide, and particularly the work carried out in our own laboratory towards strength recovery for structural applications. To ensure sufficient coverage, thermoplastics and thermosetting polymers, extrinsic and intrinsic self-healing, autonomic and non-autonomic healing approaches are included. Innovative routes that correlate materials chemistry to full capacity restoration are discussed for further development from bioinspired toward biomimetic repair.展开更多
基金Project(ZR2022QD001)supported by the Shandong Provincial Natural Science Youth Fund Project,ChinaProject(42306228)supported by the National Natural Science Foundation of ChinaProject(2022CXPT027)supported by the Key R&D Program of Shandong Province,China。
文摘Corrosion has always been a difficult problem that troubles and restricts the application and development ofengineering materials.By endowing coatings on metal surfaces with polymer material,it is possible to protect othermaterials from factors including acid and alkali,water vapor,bacteria.Therefore,it is necessary to summarize theresearch progress of polymer materials in the field of pollution and corrosion prevention in recent years.This articlesummarizes four types of polymer materials with good weather resistance:polyurethane(PU),polydimethylsiloxane(PDMS),polyvinylidene fluoride(PVDF),and polyvinylidene chloride(PVDC).These four polymer materials aresuitable for making polymer anti-corrosion or anti-fouling materials and each has its own characteristics.PU can firmlyadhere to various substrates,effectively protecting and extending their lifespan,but the environmentally friendly varietiescurrently used,namely water-borne polyurethanes(WPU),generally have poor mechanical properties.PDMS is nontoxicand has excellent hydrophobicity,but its static anti-fouling ability is insufficient when applied in the field of antifouling.PVDF has good chemical resistance and high mechanical properties,good UV resistance making it suitable foroutdoor use like in the marine environment.However,PVDF lacks flexibility after molding and its manufacturing cost isrelatively high.PVDC has excellent water vapor barrier properties,but poor adhesion to metal material surfaces.Therefore,researchers need to modify these four polymers when using them to solve the problem of corrosion orbiofouling.The article will review the research progress of four types of polymers in recent years from the perspectivesof anti-corrosion,anti-fouling,and a strategy named as self-healing that is beneficial for protecting polymer surfacesfrom mechanical damage,and summarize the modification methods adopted by researchers when applying thesematerials.Finally,a summary of the application and the prospects of these polymer materials are presented.
基金supported by the National Natural Science Foundation of China (20874117, 50903095, 51073176 and U0634001)Doctoral Fund of Ministry of Education of China (20090171110026)the Science and Technology Program of Guangdong Province (2010B010800021)
文摘Self-healing polymers represent a class of materials with built-in capability of rehabilitating damages. The topic has attracted increasingly more attention in the past few years. The on-going research activities clearly indicate that self-healing polymeric materials turn out to be a typical multi-disciplinary area concerning polymer chemistry, organic synthesis, polymer physics, theoretical and experimental mechanics, processing, composites manufacturing, interfacial engineering, etc. The present article briefly reviews the achievements of the groups worldwide, and particularly the work carried out in our own laboratory towards strength recovery for structural applications. To ensure sufficient coverage, thermoplastics and thermosetting polymers, extrinsic and intrinsic self-healing, autonomic and non-autonomic healing approaches are included. Innovative routes that correlate materials chemistry to full capacity restoration are discussed for further development from bioinspired toward biomimetic repair.
