The binary vapor–liquid equilibrium data of CO_2 in diethylene glycol(monomethyl,monoethyl,monobutyl,dimethyl,diethyl,dibutyl)ether were determined from 288.15 to 318.15 K at pressure up to 6 MPa based on the constan...The binary vapor–liquid equilibrium data of CO_2 in diethylene glycol(monomethyl,monoethyl,monobutyl,dimethyl,diethyl,dibutyl)ether were determined from 288.15 to 318.15 K at pressure up to 6 MPa based on the constant-volume method.It was found by contrast that the ether group in solvents can promote the CO_2 absorption,but the hydroxyl group will inhibit the CO_2 absorption.Furthermore,the solubilities of CO_2 showed an upward trend with the increasing molecular lengths of absorbents.The experimental data were also correlated with a modified Patel–Teja equation of state(PT EOS)combined with the traditional van der Waals one-fluid mixing rules and the results showed a satisfactory agreement between the model and the experimental data.展开更多
For the question of applying high-pressure water injection to increase gas extraction efficiency by increasing the permeability of water to drive gas action, an independently designed gas desorption experimental measu...For the question of applying high-pressure water injection to increase gas extraction efficiency by increasing the permeability of water to drive gas action, an independently designed gas desorption experimental measuring device was used under the condition of external solution invasion. The law of water effect on gas desorption was obtained after water invasion through experiment for the first time. The results show that water＇s later invasion not only can make the quantity of gas dcsorp- tion greatly reduced, but also can make gas desorption end early. Therefore, when evaluating the applications of high-pressure water injection to increase gas extraction efficiency, we should take water damaging effects on gas desorption into account.展开更多
基金the National Natural Science Foundation of China(21306088)the State Key Laboratory of Chemical Engineering(SKL-Ch E-13A01,Tsinghua University,China)the Priority Academic Program Development of Jiangsu Higher Education Institutions(China)
文摘The binary vapor–liquid equilibrium data of CO_2 in diethylene glycol(monomethyl,monoethyl,monobutyl,dimethyl,diethyl,dibutyl)ether were determined from 288.15 to 318.15 K at pressure up to 6 MPa based on the constant-volume method.It was found by contrast that the ether group in solvents can promote the CO_2 absorption,but the hydroxyl group will inhibit the CO_2 absorption.Furthermore,the solubilities of CO_2 showed an upward trend with the increasing molecular lengths of absorbents.The experimental data were also correlated with a modified Patel–Teja equation of state(PT EOS)combined with the traditional van der Waals one-fluid mixing rules and the results showed a satisfactory agreement between the model and the experimental data.
文摘For the question of applying high-pressure water injection to increase gas extraction efficiency by increasing the permeability of water to drive gas action, an independently designed gas desorption experimental measuring device was used under the condition of external solution invasion. The law of water effect on gas desorption was obtained after water invasion through experiment for the first time. The results show that water＇s later invasion not only can make the quantity of gas dcsorp- tion greatly reduced, but also can make gas desorption end early. Therefore, when evaluating the applications of high-pressure water injection to increase gas extraction efficiency, we should take water damaging effects on gas desorption into account.
