Carbon is an important alloying element in improving high temperature mechanical properties of various metallic materials.The effects of carbon on high temperature mechanical properties of aβ-stabilized Ti?45Al?3Fe?2...Carbon is an important alloying element in improving high temperature mechanical properties of various metallic materials.The effects of carbon on high temperature mechanical properties of aβ-stabilized Ti?45Al?3Fe?2Mo(molar fraction,%)alloy were studied through compressive and creep tests.The results show that the carbon addition(0.5%,molar fraction)obviously enhances the high temperature compressive strength and creep resistance of theβ-stabilized Ti?45Al?3Fe?2Mo alloy.A lot of nano-scaled Ti3AlC carbides precipitate in theβ-stabilized alloy and these carbides pin the dislocations,and greatly increase the high temperature properties.At the same time,the carbon addition decreases the amount of?phase,refines the lamellar spacing,and causes solution strengthening,which also contribute to the improvement of the high temperature properties.展开更多
A fiber Bragg grating(FBG) high-temperature and high pressure sensor has been designed and fabricated by using the Al2O3 thin-wall tube as a substrate.The test results show that the sensor can withstand a pressure ran...A fiber Bragg grating(FBG) high-temperature and high pressure sensor has been designed and fabricated by using the Al2O3 thin-wall tube as a substrate.The test results show that the sensor can withstand a pressure range of 0-45 MPa and a temperature range of -10-300 ℃,and has a pressure sensitivity of 0.0426 nm/MPa and a temperature sensitivity of 0.0112 nm /展开更多
The gas-liquid mass transfer of H2 and CO in a high temperature and high-pressure three-phase slurry bubble column reactor is studied. The gas-liquid volumetric mass transfer coefficients kLa are obtained by measuring...The gas-liquid mass transfer of H2 and CO in a high temperature and high-pressure three-phase slurry bubble column reactor is studied. The gas-liquid volumetric mass transfer coefficients kLa are obtained by measuring the dissolution rate of H2 and CO. The influences of the main operation conditions, such as temperature, pressure, superficial gas velocity and solid concentration, are studied systematically. Two empirical correlations are proposed to predict kLa values for H2 and CO in liquid paraffin/solid particles slurry bubble column reactors.展开更多
Three groups of experiments on brittle-plastic transition and instability modes of granite were performed in a triaxial vessel with solid pressure medium at high temperature and high pressure. The results of experimen...Three groups of experiments on brittle-plastic transition and instability modes of granite were performed in a triaxial vessel with solid pressure medium at high temperature and high pressure. The results of experiments show that brittle faulting is the major failure mode at temperature <300℃, but crystal-plastic deformation is dominate at temperature >800℃, and there is a transition with increasing temperature from semi-brittle faulting to cataclastic flow and semi-brittle flow at temperatures of 300～800℃. So, temperature is the most influential factor in brittle-plastic transition of granite and confining pressure is the second factor. The results also show that progressive failure of granite occurs at lower pressure or high temperature where there is crystal plasticity, and sudden instability occurs at room temperature and high pressure (>300MPa) or high temperature and great pressure(550℃600MPa ～650℃700MPa), and a broad regime of quasi-sudden instability exists between the T-P condition of progressive failure and sudden instability. So, instability modes of granite depend simultaneously on the pressure and temperature.展开更多
The thermodynamic properties of LiBC are investigated by using the full-potential linearlzed muffin-tin orbital method （FP-LMTO） within the frame of density functional theory （DFT） and using the quasi-harmonic Deb...The thermodynamic properties of LiBC are investigated by using the full-potential linearlzed muffin-tin orbital method （FP-LMTO） within the frame of density functional theory （DFT） and using the quasi-harmonic Debye model. The dependencies of the normalized lattice parameters a/a0 and c/c0, the ratio （c/a）/2, the normalized primitive volume V/V0 on pressure and temperature are successfully obtained. It is found that the interlayer covalent interactions （Li-B bonds or Li-C bonds） are more sensitive to temperature and pressure than intralayer ones （B-C bonds）, as gives rise to the extreme lattice anisotropy in the bulk hop LiBC.展开更多
The hot deformation behavior of Al-6.2Zn-0.70Mg-0.30Mn-0.17 Zr alloy and its microstructural evolution were investigated by isothermal compression test in the deformation temperature range between 623 and 773 K and th...The hot deformation behavior of Al-6.2Zn-0.70Mg-0.30Mn-0.17 Zr alloy and its microstructural evolution were investigated by isothermal compression test in the deformation temperature range between 623 and 773 K and the strain rate range between 0.01 and 20 s^(-1).The results show that the flow stress decreased with decreasing strain rate and increasing deformation temperature.At low deformation temperature(≤673 K) and high strain rate(≥1 s^(-1)),the main flow softening was caused by dynamic recovery;conversely,at higher deformation temperature and lower strain rate,the main flow softening was caused by dynamic recrystallization.Moreover,the slipping mechanism transformed from dislocation glide to grain boundary sliding with increasing the deformation temperature and decreasing the strain rate.According to TEM observation,numerous Al_3Zr particles precipitated in matrix,which could effectively inhibit the dynamic recrystallization of the alloy.Based on the processing map,the optimum processing conditions for experimental alloy were in deformation temperature range from 730 K to 773 K and strain rate range from 0.033 s^(-1) to 0.18 s^(-1) with the maximum efficiency of 39%.展开更多
The compressive strength and ilexural toughness as well as fracture energy of fiber reinforced highperformance concrete （FRHPC） subjected to different high temperatures were studied. The results showed that after ex...The compressive strength and ilexural toughness as well as fracture energy of fiber reinforced highperformance concrete （FRHPC） subjected to different high temperatures were studied. The results showed that after exposure at 300,600 and 900℃, the concrete mixes retained 88.1% , 41.3% and 10.2% of the original compressive strength on average, respectively. Steel fiber and polypropylene （PP） fiber were both effective in minimizing the damage effect of high temperatures on the compressive strength. The HPC reinforced with steel fibers showed higher flexural toughness and fracture energy before and after the high-temperature exposures. In comparison, PP fibers had minor beneficial effects on the flexural toughness and fracture energy. The mechanical properties of HPC reinforced with hybrid fibers （steel fiber ＋ PP fiber） were equivalent to or better than those of HPC reinforced with steel fibers alone. In addition, the failure pattern of FRHPC beams changed from pull-out of steel fibers at lower temperatures （20, 300 and 600℃） to tensile failure of steel fibers at higher temperature （900 ℃）.展开更多
A large amount of residue including benzoic acid, benzyl benzoate and fluorenone can form in the production of benzoic acid by oxidizing toluene. To recycle the resources and reduce secondary pollution, the treatment ...A large amount of residue including benzoic acid, benzyl benzoate and fluorenone can form in the production of benzoic acid by oxidizing toluene. To recycle the resources and reduce secondary pollution, the treatment of benzoic acid residue was carried out to obtain the three purified materials by flash-vacuum distillation combination method, and the influence of the operating parameters, such as the top pressure, reflux ratio and top and bottom temperatures was investigated to obtain the best operating conditions. The experimental results show that the benzoic acid purity can reach 97% through distillation under the following conditions： the top pressure is 1 600 Pa, the bottom temperature is 190--200℃, the top temperature is 130--135℃, and reflux ratio is 5：1. The best operating conditions for benzyl benzoate distillation column are： the top pressure is 400 Pa, bottom temperature is 250-- 260 ℃, the top temperature is 150--160 , and reflux ratio is 5：1. The benzyl benzoate purity can reach 95%, and the fiuorenone purity can reach 92 %. When refined by melt crystallization, the benzoic acid purity can be improved up to 99.6%, and the purities of benzyl benzoate and fluorenone are both above 95%.展开更多
The relative permeability curve has been measured with simulation oil (refined oil) and gas (nitrogen or air) at room temperature and a lowpressure, both of which are very important parameters for depicting the flow ...The relative permeability curve has been measured with simulation oil (refined oil) and gas (nitrogen or air) at room temperature and a lowpressure, both of which are very important parameters for depicting the flow of fluid through porous media in a hydrocarbon reservoir. This basic measurement is often applied in exploitation evaluation, but the underground conditions with high temperature and pressure, and the phase equilibrium of oil and gas, are not taken into consideration when the relative permeability curve is tested. There is an important theoretical and practical sense in testing the diphase relative permeability curve of the equilibrium of oil and gas under the conditions of high temperature and pressure. The test method for the relative permeability curve is proposed in this paper. The relative permeability of the equilibrium of oil and gas and the standard one are tested in two fluids, and the differences between these two methods are stated. The research results can be applied to the simulation and prediction of CVD in long cores and then the phenomenon can better explain that the recovery of condensate gas rich in condensate oil is higher than that of CVD test in PVT. Meanwhile, the research shows that the relative permeability curve of equilibrium oil and gas is sensitive to the rate of exploitation, and the viewpoint proves that an improved gas recovery rate can properly increase the recovery of condensate oil.展开更多
A rational equation of state of the perturbation type with a repulsion and attraction term has been applied to reproduce critical curves of six different binary systems up to high temperatures and pressures. A square ...A rational equation of state of the perturbation type with a repulsion and attraction term has been applied to reproduce critical curves of six different binary systems up to high temperatures and pressures. A square well potential for intermolecular interaction is used. With pairwise combination rules for these potentials three adjustable parameters are needed. The experimental critical point and phase equilibrium data are compared with the values predicted using the equation of state. Good agreement is obtained for the analysis of the critical pressure composition data and molar volumes.展开更多
In order to avoid the curing effects of paraffin on the transport process and reduce the transport difficulty,usually high temperature and high pressure are used in the transportation of oil and gas.The differences of...In order to avoid the curing effects of paraffin on the transport process and reduce the transport difficulty,usually high temperature and high pressure are used in the transportation of oil and gas.The differences of temperature and pressure cause additional stress along the pipeline,due to the constraint of the foundation soil,the additional stress can not release freely,when the additional stress is large enough to motivate the submarine pipelines buckle.In this work,the energy method is introduced to deduce the analytical solution which is suitable for the global buckling modes of idealized subsea pipeline and analyze the relationship between the critical buckling temperature,buckling length and amplitude under different high-order global lateral buckling modes.To obtain a consistent formulation of the problem,the principles of virtual displacements and the variation calculus for variable matching points are applied.The finite element method based on elasto-plastic theory is used to simulate the lateral global buckling of the pipelines under high temperature and pressure.The factors influencing the lateral buckling of pipelines are further studied.Based upon some actual engineering projects,the finite element results are compared with the analytical ones,and then the influence of thermal stress,the section rigidity of pipeline,the soil properties and the trigging force to the high order lateral buckling are discussed.The method of applying the small trigging force on pipeline is reliable in global buckling numerical analysis.In practice,increasing the section rigidity of a pipeline is an effective measure to improve the ability to resist the global buckling.展开更多
基金Project(2014CB6644002)supported by the National Basic Research Program of ChinaProject(2016YFB0700302)supported by the National Major Scientific Research Development Program,ChinaProject(2017JJ2311)supported by the Hunan Natural Science Foundation of China
文摘Carbon is an important alloying element in improving high temperature mechanical properties of various metallic materials.The effects of carbon on high temperature mechanical properties of aβ-stabilized Ti?45Al?3Fe?2Mo(molar fraction,%)alloy were studied through compressive and creep tests.The results show that the carbon addition(0.5%,molar fraction)obviously enhances the high temperature compressive strength and creep resistance of theβ-stabilized Ti?45Al?3Fe?2Mo alloy.A lot of nano-scaled Ti3AlC carbides precipitate in theβ-stabilized alloy and these carbides pin the dislocations,and greatly increase the high temperature properties.At the same time,the carbon addition decreases the amount of?phase,refines the lamellar spacing,and causes solution strengthening,which also contribute to the improvement of the high temperature properties.
基金the National "863" Project of China (No.2002AA313150)
文摘A fiber Bragg grating(FBG) high-temperature and high pressure sensor has been designed and fabricated by using the Al2O3 thin-wall tube as a substrate.The test results show that the sensor can withstand a pressure range of 0-45 MPa and a temperature range of -10-300 ℃,and has a pressure sensitivity of 0.0426 nm/MPa and a temperature sensitivity of 0.0112 nm /
基金the National Natural Science Foundation of China (No. 29870619).
文摘The gas-liquid mass transfer of H2 and CO in a high temperature and high-pressure three-phase slurry bubble column reactor is studied. The gas-liquid volumetric mass transfer coefficients kLa are obtained by measuring the dissolution rate of H2 and CO. The influences of the main operation conditions, such as temperature, pressure, superficial gas velocity and solid concentration, are studied systematically. Two empirical correlations are proposed to predict kLa values for H2 and CO in liquid paraffin/solid particles slurry bubble column reactors.
文摘Three groups of experiments on brittle-plastic transition and instability modes of granite were performed in a triaxial vessel with solid pressure medium at high temperature and high pressure. The results of experiments show that brittle faulting is the major failure mode at temperature <300℃, but crystal-plastic deformation is dominate at temperature >800℃, and there is a transition with increasing temperature from semi-brittle faulting to cataclastic flow and semi-brittle flow at temperatures of 300～800℃. So, temperature is the most influential factor in brittle-plastic transition of granite and confining pressure is the second factor. The results also show that progressive failure of granite occurs at lower pressure or high temperature where there is crystal plasticity, and sudden instability occurs at room temperature and high pressure (>300MPa) or high temperature and great pressure(550℃600MPa ～650℃700MPa), and a broad regime of quasi-sudden instability exists between the T-P condition of progressive failure and sudden instability. So, instability modes of granite depend simultaneously on the pressure and temperature.
基金The project supported by National Natural Science Foundation of China under Grant No. 10576020
文摘The thermodynamic properties of LiBC are investigated by using the full-potential linearlzed muffin-tin orbital method （FP-LMTO） within the frame of density functional theory （DFT） and using the quasi-harmonic Debye model. The dependencies of the normalized lattice parameters a/a0 and c/c0, the ratio （c/a）/2, the normalized primitive volume V/V0 on pressure and temperature are successfully obtained. It is found that the interlayer covalent interactions （Li-B bonds or Li-C bonds） are more sensitive to temperature and pressure than intralayer ones （B-C bonds）, as gives rise to the extreme lattice anisotropy in the bulk hop LiBC.
基金Project(2016GK1004)supported by the Science and Technology Major Project of Hunan Province,China
文摘The hot deformation behavior of Al-6.2Zn-0.70Mg-0.30Mn-0.17 Zr alloy and its microstructural evolution were investigated by isothermal compression test in the deformation temperature range between 623 and 773 K and the strain rate range between 0.01 and 20 s^(-1).The results show that the flow stress decreased with decreasing strain rate and increasing deformation temperature.At low deformation temperature(≤673 K) and high strain rate(≥1 s^(-1)),the main flow softening was caused by dynamic recovery;conversely,at higher deformation temperature and lower strain rate,the main flow softening was caused by dynamic recrystallization.Moreover,the slipping mechanism transformed from dislocation glide to grain boundary sliding with increasing the deformation temperature and decreasing the strain rate.According to TEM observation,numerous Al_3Zr particles precipitated in matrix,which could effectively inhibit the dynamic recrystallization of the alloy.Based on the processing map,the optimum processing conditions for experimental alloy were in deformation temperature range from 730 K to 773 K and strain rate range from 0.033 s^(-1) to 0.18 s^(-1) with the maximum efficiency of 39%.
基金Sponsored by the National Natural Science Foundation of China (Grant No.50278013)
文摘The compressive strength and ilexural toughness as well as fracture energy of fiber reinforced highperformance concrete （FRHPC） subjected to different high temperatures were studied. The results showed that after exposure at 300,600 and 900℃, the concrete mixes retained 88.1% , 41.3% and 10.2% of the original compressive strength on average, respectively. Steel fiber and polypropylene （PP） fiber were both effective in minimizing the damage effect of high temperatures on the compressive strength. The HPC reinforced with steel fibers showed higher flexural toughness and fracture energy before and after the high-temperature exposures. In comparison, PP fibers had minor beneficial effects on the flexural toughness and fracture energy. The mechanical properties of HPC reinforced with hybrid fibers （steel fiber ＋ PP fiber） were equivalent to or better than those of HPC reinforced with steel fibers alone. In addition, the failure pattern of FRHPC beams changed from pull-out of steel fibers at lower temperatures （20, 300 and 600℃） to tensile failure of steel fibers at higher temperature （900 ℃）.
文摘A large amount of residue including benzoic acid, benzyl benzoate and fluorenone can form in the production of benzoic acid by oxidizing toluene. To recycle the resources and reduce secondary pollution, the treatment of benzoic acid residue was carried out to obtain the three purified materials by flash-vacuum distillation combination method, and the influence of the operating parameters, such as the top pressure, reflux ratio and top and bottom temperatures was investigated to obtain the best operating conditions. The experimental results show that the benzoic acid purity can reach 97% through distillation under the following conditions： the top pressure is 1 600 Pa, the bottom temperature is 190--200℃, the top temperature is 130--135℃, and reflux ratio is 5：1. The best operating conditions for benzyl benzoate distillation column are： the top pressure is 400 Pa, bottom temperature is 250-- 260 ℃, the top temperature is 150--160 , and reflux ratio is 5：1. The benzyl benzoate purity can reach 95%, and the fiuorenone purity can reach 92 %. When refined by melt crystallization, the benzoic acid purity can be improved up to 99.6%, and the purities of benzyl benzoate and fluorenone are both above 95%.
基金This paper was subsidized by the 15th National key Sci-Tech Project (NO.2001BA605A02-04-01)
文摘The relative permeability curve has been measured with simulation oil (refined oil) and gas (nitrogen or air) at room temperature and a lowpressure, both of which are very important parameters for depicting the flow of fluid through porous media in a hydrocarbon reservoir. This basic measurement is often applied in exploitation evaluation, but the underground conditions with high temperature and pressure, and the phase equilibrium of oil and gas, are not taken into consideration when the relative permeability curve is tested. There is an important theoretical and practical sense in testing the diphase relative permeability curve of the equilibrium of oil and gas under the conditions of high temperature and pressure. The test method for the relative permeability curve is proposed in this paper. The relative permeability of the equilibrium of oil and gas and the standard one are tested in two fluids, and the differences between these two methods are stated. The research results can be applied to the simulation and prediction of CVD in long cores and then the phenomenon can better explain that the recovery of condensate gas rich in condensate oil is higher than that of CVD test in PVT. Meanwhile, the research shows that the relative permeability curve of equilibrium oil and gas is sensitive to the rate of exploitation, and the viewpoint proves that an improved gas recovery rate can properly increase the recovery of condensate oil.
文摘A rational equation of state of the perturbation type with a repulsion and attraction term has been applied to reproduce critical curves of six different binary systems up to high temperatures and pressures. A square well potential for intermolecular interaction is used. With pairwise combination rules for these potentials three adjustable parameters are needed. The experimental critical point and phase equilibrium data are compared with the values predicted using the equation of state. Good agreement is obtained for the analysis of the critical pressure composition data and molar volumes.
基金Project(51021004)supported by Innovative Research Groups of the National Natural Science Foundation of ChinaProject(NCET-11-0370)supported by Program for New Century Excellent Talents in Universities of China+1 种基金Project(40776055)supported by the National Natural Science Foundation of ChinaProject(1002)supported by State Key Laboratory of Ocean Engineering Foundation,China
文摘In order to avoid the curing effects of paraffin on the transport process and reduce the transport difficulty,usually high temperature and high pressure are used in the transportation of oil and gas.The differences of temperature and pressure cause additional stress along the pipeline,due to the constraint of the foundation soil,the additional stress can not release freely,when the additional stress is large enough to motivate the submarine pipelines buckle.In this work,the energy method is introduced to deduce the analytical solution which is suitable for the global buckling modes of idealized subsea pipeline and analyze the relationship between the critical buckling temperature,buckling length and amplitude under different high-order global lateral buckling modes.To obtain a consistent formulation of the problem,the principles of virtual displacements and the variation calculus for variable matching points are applied.The finite element method based on elasto-plastic theory is used to simulate the lateral global buckling of the pipelines under high temperature and pressure.The factors influencing the lateral buckling of pipelines are further studied.Based upon some actual engineering projects,the finite element results are compared with the analytical ones,and then the influence of thermal stress,the section rigidity of pipeline,the soil properties and the trigging force to the high order lateral buckling are discussed.The method of applying the small trigging force on pipeline is reliable in global buckling numerical analysis.In practice,increasing the section rigidity of a pipeline is an effective measure to improve the ability to resist the global buckling.
