高合工钢Cr12MoV系列连铸工艺研究探讨

东特股份公司通过对高碳高铬冷作模具Cr12MoV系列连铸工艺研究,成功开发了Cr12MoV等高合工品种连铸生产工艺,所生产的连铸坯表面、内在质量满足下工序的使用需求,高合工钢连铸工艺的成功开发代替原有的模铸工艺,使炼钢生产效率提高、成本显著降低。

Effect of NiAl content on phases and microstructures of TiC-TiB_2-NiAl composites fabricated by reaction synthesis

TiC-TiB2-NiAl composites were fabricated by self-propagating high temperature reaction synthesis（SHS） with Ti, B4C, Ni and Al powders as raw materials. The effects of NiAl content on phase constituents and microstructures were investigated. The results show that the reaction products are composed of TiB2, TiC and NiAl. The content of NiAl increases with the adding of Ni＋Al in green compacts. TiB2, TiC and NiAl grains present in different shapes in the matrix, TiB2 being in hexagonal or rectangular shapes, TiC in spherical shapes, and NiAl squeezed into the gaps of TiC and TiB2 grains. With the increase of NiAl content, the grains of TiC-TiB2-NiAl composites are refined, their density and compressive strength are improved, and the shapes of TiC grains become spherical instead of irregular ones. Finally, the fracture mechanism of the composites transforms from intergranular fracture mode to the compounded fracture mode of intergranular fracture and transgranular fracture.

Hot deformation behavior and workability of pre-extruded ZK60A magnesium alloy

The hot deformation behavior and workability of pre-extruded ZK60A magnesium alloy were investigated by compression tests in the temperature range of 250-450 ℃and the strain rate range of 0.001-10 s 1. The constitutive equation for the pre-extruded ZK60A alloy can be described by hyperbolic sine function. Processing maps were constructed from true strains of -0.2 to -0.8. The alloy experienced complete dynamic recrystallization （DRX） and showed good workability in the temperature range of 300-400 ℃ and the strain rate range of 0.01-0.001 s-Z, where hot working in pre-extruded ZK60A, such as forging, can be carried out. For large deformation to true strain of over -0.5, strain rates above 0.1 s-1 are not recommended at all temperatures, where flow instability such as local strain concentration, twinning deformation, abnormal grain growth, micro-cracks, and shear fracture were observed. Climb-controlled dislocation creep dominates both the plastic deformation and nucleation of DRX of the pre-extruded ZK60A magnesium alloy.

Hot deformation behavior of spray forming LSHR alloy using constitutive equation and processing map

Flow behaviors of spray forming low solvus high refractory (LSHR) alloy were investigated using hot compression tests performed on a Gleeble?3500 thermal mechanical simulator at temperatures of 1020?1150 °C and strain rates of 0.0003?1.0 s?1. The constitutive equation was established, power dissipation (η) maps and hot processing maps were plotted. The microstructure evolution and dislocation distribution of domains with different values of η in power dissipation maps were also observed. The results show that the flow stress increases with decreasing temperature and increasing strain rate. The activation energy of the spray forming LSHR alloy is 1243.86 kJ/mol. When the value of η is 0.36 at the strain of 0.5, the domain in the processing map shows characteristics of typical dynamic recrystallization (DRX) and low dislocation density. According to the microstructure evolution and processing maps, the optimum processing condition for good hot workability of spray forming LSHR alloy can be summed up as:temperature range 1110?1150 °C; strain rate range 0.01?0.3 s?1.

A Study on Theoretical Model and Applied Evaluation of Land Use Performance of High-tech Zone in Urban Fringe: A Case Study in Haidian District, Beijing

High-tech industrial zone is an important carrier for constructing innovative cities. It also plays an important role in implementing the national independent innovative strategy. How-ever, most of the high-tech industrial zones have many problems in their development process, such as efficiency of land use, weakness of oriented function and lack of land intensive. To solve these problems, the authors of this paper introduced the concept of land use performance and established the theoretical model to assess the land use performance of high-tech industrial zones. The model consists of the following three-dimensional parts: land use benefit, land use efficiency and innovative function. Based on this theory model, an index system which was composed of three secondary indictors, eight tertiary indictors and 37 fourth-grade indictors was set up to evaluate the land use performance of high-tech zone. To avoid the defects of plus model and function model, the authors brought out a three-dimensional evaluation model to examine the index of the land use performance of the high-tech industrial parks, which equals to the evaluation indicator system of land use performance of high-tech zone based on the above research. The authors examined the land use performance of five different high-tech industrial parks in Haidian District, Beijing City. The results indicated that the indicator system per-forms better in the aspect of evaluating land use benefit, land use efficiency and function of the high-tech industrial zone compared with other models.

Formation mechanism of basin-like depression defect in electric upsetting process of Ni80A superalloy

A kind of surface instability,basin-like depression defect companied by mixed grain structure at the bottom of large-scale valve during electric upsetting process,would significantly influence the microstructures and mechanical properties of components.In order to analyze the forming process of the basin-like depression defect,a finite element model for the electric upsetting process of Ni80A superalloy was developed using multi-field and multi-scale coupling analysis method.Subsequently,a series of parameters loading path schemes for force and current were designed by varying the initial value,peak value and value level,and their effects on basin-like depression and mixed grain structure were simulated and uncovered.It is concluded that the changes of heating speed and pressurization speed result in the different flow velocities between the inner and outer layers of billet,thus exerting the basin-like depression.Simulation results also indicate that these defects can be optimized through the parameter coordination between force and current.Finally,the validity and reliability of the finite element model were verified by physical experiments in electric upsetting process.

Improving wear resistance of magnesium by droplet spraying of Al-Si alloy

Abstract： In order to improve the surface hardness and wear resistance of magnesium, Al-13%Si （mass fraction） alloy coating was deposited on pure magnesium by droplet spraying process. The microstructure was studied by electron probe microanalysis and X-ray diffraction. The micro-hardness and wear resistance of coating were investigated in comparison with those of the substrate. It is found that the coating layer is composed of a-Al cellular due to rapid solidification. Formation mechanism of the coating is due to the obstruction of diffusion by in-situ formed Mg2Si in interracial layer. The coating exhibits higher hardness compared to that of the Mg substrate. As result of its high hardness, the wear resistance of the coating layer is about ten times that of the substrate. The droplet spraying process demonstrates that the magnesium surface can be strengthened by using the existing Al-Si alloys.

Synthesis of Foliar Fertilizer and Ca-S-Si Compound Fertilizer from Titanium-bearing Blast Furnace Slag

With titanium-bearing blast furnace slag, ammonium sulfate, citric acid and potassium carbonate as raw materials to produce foliar fertilizer and Ca-S-Si compound fertilizer by means of heating process for the first time, which improved the solubility of the slag and converted the nutritional elements into such ones which are prone to be absorbed by plants. The effects of process conditions on dissolution rate of titanium were mainly analyzed through the orthogonal experiment. The results showed that the optimum synthesis process conditions of foliar fertilizer from the slag were 360 ℃ for 35 min, the mass ratio of ammonium sulfate and titanium-bearing blast furnace slag was 8：1. Under these conditions more than 80% of iron, titanium, magnesium and part of silicon in titanium-bearing blast furnace slag converted into water-soluble substances and existing in foliar fertilizer. Foliar fertilizer contained nitrogen, sulfur, potassium, iron, titanium, magnesium and silicon, and pH value of foliar fertilizer was 6. Ca-S-Si compound fertilizer mainly contained calcium silicate and calcium sulfate, which existed in the form of citric acid-soluble substance and slightly soluble substance, respectively.

Vertical drainage capacity of new electrical drainage board on improvement of super soft clayey ground

As an advanced polymer composites electro-kinetic geosynthetics, the electro-osmotic vertical drainage(EVD) board could drain water quickly and accelerate consolidation process. However, the drainage rate was mainly impacted by the vertical drainage capability. Therefore, vertical drainage capability at the top of EVD board was theoretically analyzed. Basic requirements for drainage at the top of the board were summed up, as well as the formula of anode pore pressure when losing the vertical drainage capability. Meanwhile, a contrast test on the top and bottom drainage capacities was conducted. In use of the advanced EVD board, the voltage potential and pore pressure of anode were measured. Moreover, the derived formulas were verified. The result shows that the decrease of electric force gradient had an observable impact on the drainage capability. There was nearly no difference between the energy consumption for the two drainage methods. Although a little less water was discharged, the top drainage method had more advantages, such as high initial drainage velocity, few soil cracks, low anode water content and high soil strength. All of these show that the super soft soil ground could be consolidated quickly in use of the advanced EVD board through the top drainage. The top drainage method could efficiently improve the drainage effect, decrease the energy consumption and speed up the project proceeding.

Influence of process parameters on deep drawing of AA6111 aluminum alloy at elevated temperatures

To gain a deep insight into the hot drawing process of aluminum alloy sheet, simulations of cylindrical cup drawing at elevated temperatures were carried out with experimental validation. The influence of four important process parameters, namely,punch velocity, blank holder force(BHF), friction coefficient and initial forming temperature of blank on drawing characteristics(i.e.minimum thickness and thickness deviation) was investigated with the help of design of experiments(DOE), analysis of variance(ANOVA) and analysis of mean(ANOM). Based on the results of ANOVA, it is shown that the blank holder force has the greatest influence on minimum thickness. The importance of punch velocity for thickness deviation is 44.35% followed by BHF of 24.88%,friction coefficient of 15.77% and initial forming temperature of blank of 14.995%. After determining the significance of each factor on forming characteristics, how the individual parameter affects characteristics was further analyzed by ANOM.

An Experimental Study of Structured Packing in High Pressure Services

Both distillation performance and hydrodynamic study for backmixing by tracer technique were carried out in a high-pressure packed column with 0.15 m inner diameter over a wide range of operating conditions. Isobutane and n-pentane are employed as test mixture in the distillation experiment and air/water is used for the hydrodynamic study. The column is installed with Mellapak 350Y structured packing and the total packing height is 2.0 m. With the increasing operating pressure, the separation efficiency increases slightly while the F-factor corresponding to the maximum efficiency at each pressure is descending. It is noted that, at all operating pressures, with the increase of F-factor, the packing efficiency is slightly higher up to the flooding point. The application of SRP model to high-pressure distillation gives much lower values of HTUOG than those obtained experimentally. An additional term, the height of mixing unit, is introduced to correct the SRP model and improve its accuracy at high pressure. From the tracer experiments, the height of mixing unit for gas phase was found to be larger than that for the liquid phase. From this viewpoint, it is believed that the gas phase backmixing gives more unfavorable influence on the separation efficiency in comparison with liquid phase.

Uses of Blast Furnace Slag as Complex Fertilizer

Significant quantities of slag are generated as waste material or by-product every day from steel industries. They usually contain considerable quantities of valuable metals and materials. Transforming these solid wastes from one form to another to be reused either by the same production unit or by different industrial installation is very much essential not only for conserving metals and mineral resources but also for protecting the environment. The sustainable development concept requires a more efficient management of waste materials and preservation of environment. The paper presents the basic characteristics of slag, analyses and it＇s modification by incorporating some essential plant nutrients and the possibility of its application as fertilizer was studied.

Characterization of phases in Mg-10Y-5Gd-2Zn-0.5Zr alloy processed by heat treatment

Characterizations of phases in Mg-10%Y-5%Gd-2%Zn-0.5%Zr （WGZ1052） alloy during heat treatments were investigated by OM, XRD, SEM and EDS. The mechanisms of microstrucmre evolution were discussed. The results show that, after high temperature heat treatments, the Mg12ZnY phases still exist. During solution-treatment at 535 ~C, the amount of the long-period stacking order structures decreases. At 545℃ for 20 h and 24 h, there are still remnant Mg12ZnY compounds in the Mg matrix, the shape of which does not change and the amount does not decrease obviously.

Warm hydroforming of magnesium alloy tube with large expansion ratio

Process of warm tube hydroforming was experimentally investigated for forming an AZ31B magnesium alloy tubular part with a large expansion ratio. Effects of temperature on the mechanical properties and formability were studied by uniaxial tensile test and hydraulic bulge test. Total elongation increases with temperature up to 250℃, but uniform elongation and maximum expansion ratio get the highest value at 175℃. Different axial feeding amounts were applied in experiments to determine the reasonable loading path. A preform with useful wrinkles was then realized and the tubular part with an expansion ratio of 50% was formed. Finally, mechanical condition to produce useful wrinkles is deduced and the result illustrates that useful wrinkles are easier to be obtained for tube with higher strain hardening coefficient value and tubular part with smaller expansion ratio.

An Experimental Study on Slotting of Inconel 718 Thin Sheet

Many difficult-to-cut materials such as Ni-base super alloy, titanium alloy, and austenite stainless steel which are used extensively in aerospace generally have high strength-to-weight ratios, high corrosion resistance, high strength retention ability at elevated temperatures, and low thermal conductivity. These characteristics can result in uneven tool wear and chatter vibration. Therefore, determining the appropriate end-milling conditions is more difficult for difficult-to-cut materials than for other materials. There has been much research on the high-speed milling of difficult-to-cut materials, and effective end-milling conditions, end-mill tool shapes, and processing methods have been reported. In addition, irregular pitch and lead end-mills with different helix angles have been developed by tool maker＇s to reduce chatter vibration, making it easier to perform high-speed milling. However, there have been few reports of slotting information useful for determining appropriate end-milling conditions and processing methods for Ni-base super alloy. The aim of this study is to derive end-milling condition with high efficiency grooving process for Ni-base super alloy （Inconel 718） sheet. Effects of cutting parameters were examined from the view point of cutting resistance, ＂tool tip maximum temperature and tool flank wear width. As a result from experiments, if the grooving process condition of axial depth of cut is smaller than other conditions on the same material removable rate value, it has been found that it is possible to reduce the tool tip maximum temperature and prolong the tool life.

Design method of pile-slab structure roadbed of ballastless track on soil subgrade

Pile-slab structure roadbed is a new form of ballastless track for high speed railway. Due to lack of corresponding design code, based on the analysis of its structure characteristics and application requirements, it is proposed to carry out load effect combination according to ultimate limit state and serviceability limit state, and the most unfavorable combination of each state is chosen to carry through design calculation for pile-slab structure. Space model of pile-slab structure can be simplified as a plane flame model, by using the orthogonal test method, and the design parameter of pile-slab structure is optimized. Moreover, based on the engineering background of Suining-Chongqing high-speed railway, the dynamic deformation characteristics of pile-slab structure roadbed are further researched by carrying on the indoor dynamic model test. The test results show that the settlement after construction of subgrade satisfies the requirement of settlement control to build ballastless track on soil subgrade for high-speed railway. Slab structure plays the role of arch shell as load is transmitted from slab to pile, and the vertical dynamic stress of subgrade soil is approximately of ＂K＂ form distribution with the depth. The distribution of pile stress is closely related to soil characteristics, which has an upset triangle shape where the large dynamic stress is at the top. Pile compared with soil shares most dynamic stress. Pile structure expands the depth of the dynamic response of subgrade has limited effect on dynamic response. These results can provide subgrade. and improves the stress of subgrade soil, and the speed of train scientific basis for pile-slab structure roadbed used on soil

Index system for assessing ecological stability of circular economy industrial chain of electronic industry and its empirical study

With the development of science and technology and the rapid growth of productive forees new and high technology industries have. For example, computer, mobile phone, etc. are increasingly popular, especially hi-tech products updating more and more quickly, which has initiated some problems： resources depletion, environmental pollution, ecosystems damage, etc. While people are enjoying convenient and comfortable life from hi-tech, they are worrying about quantities of e-wastes discharged.In order to reduce the amount and harm of e-wastes, this paper starts from the connotation of the ecological stability of circular economy electronics industry chain （CEEIC, for shorO, uses the food chain principle for reference to describe the links and connection of the electronics industry chain, and selects factors from the three link： production, consumption and recycle to construct indexes system based on their characteristics, with which a scientific evaluation is carried on for CEEIC by using fuzzy comprehensive evaluation.

Influence of Holding Time on Hot Deformation Behavior of Hard-Deformed Superalloy U720Li

To improve the hot workability of hard-deformed superalloy U720Li,the effect of holding time before deformation(5 and 10 min)on hot deformation behavior was investigated by hot compression tests.Results show that the flow stress increases with increase in strain rate,while decreases with increase in deformation temperature and holding time.Based on the obtained Arrhenius-type constitutive models,the calculated peak stresses are in good agreement with experimental values,indicating that this model can accurately predict the hot deformation behavior of U720Li alloy,and the deformation activation energies for the holding time of 5 and 10 min were calculated to be 992.006 and 850.996 kJ·mol^(-1),respectively.Moreover,processing maps of U720Li alloy with these two holding durations were constructed.Through observation of deformation microstructures in each domain of the processing maps,the optimal hot working conditions for the holding time of 5 min are determined to be 1090‒1110℃/1‒10 s^(-1) and 1146‒1180℃/1‒10 s^(-1),and the optimal hot working conditions for the holding time of 10 min are 1080‒1090℃/1‒10 s-1 and 1153‒1160℃/1‒10 s^(-1),indicating that the safe processing window can be obviously enlarged by shortening the holding time reasonably.In the absence of cracking,the dynamic recrystallization(DRX)grain size increases gradually with increasing the deformation temperature and holding time,but it first decreases and then increases with the increase in strain rate.When the deformation temperature is below 1100℃,the DRX mechanism is mainly the particle-induced continuous DRX.As the temperature is raised to above 1130℃,the main DRX mechanism changes to discontinuous DRX.

Cutting force and its frequency spectrum characteristics in high speed milling of titanium alloy with a polycrystalline diamond tool

In this paper, a series of experiments were performed by high speed milling of Ti-6.5Al-2Zr-1Mo-1V (TA15) by use of polycrystalline diamond (PCD) tools. The characteristics of high speed machining (HSM) dynamic milling forces were investi- gated. The effects of the parameters of the process, i.e., cutting speed, feed per tooth, and depth of axial cut, on cutting forces were studied. The cutting force signals under different cutting speed conditions and different cutting tool wear stages were analyzed by frequency spectrum analysis. The trend and frequency domain aspects of the dynamic forces were evaluated and discussed. The results indicate that a characteristic frequency in cutting force power spectrum does in fact exist. The amplitudes increase with the increase of cutting speed and tool wear level, which could be applied to the monitoring of the cutting process.

Synthetic biodegradable functional polymers for tissue engineering:a brief review

Scaffolds play a crucial role in tissue engineering. Biodegradable polymers with great processing flexibility are the predominant scaffolding materials. Synthetic biodegradable polymers with well-defined structure and without immunological concerns associated with naturally derived polymers are widely used in tissue engineering. The synthetic biodegradable polymers that are widely used in tissue engineering, including polyesters, polyanhydrides, polyphosphazenes, polyurethane, and poly(glycerol sebacate) are summarized in this article. New developments in conducting polymers, photoresponsive polymers, amino-acid-based polymers, enzymatically degradable polymers, and peptide-activated polymers are also discussed. In addition to chemical functionalization, the scaffold designs that mimic the nano and micro features of the extracellular matrix(ECM) are presented as well, and composite and nanocomposite scaffolds are also reviewed.