Synthesis of the spinel structure lithium manganese oxide （LiMn2O4） by supercritical hydrothermal （SH） accelerated solid state reaction （SSR） route was studied. The impacts of the reaction pressure, reaction tem...Synthesis of the spinel structure lithium manganese oxide （LiMn2O4） by supercritical hydrothermal （SH） accelerated solid state reaction （SSR） route was studied. The impacts of the reaction pressure, reaction temperature and reaction time of SH route, and the calcination temperature of SSR route on the purity, particle morphology and electrochemical properties of the prepared LiMn2O4 materials were studied. The experimental results show that after 15 min reaction in SH route at 400 ℃ and 30 MPa, the reaction time of SSR could be significantly decreased, e.g. down to 3 h with the formation temperature of 800 ℃, compared with the conventional solid state reaction method. The prepared LiMn2O4 material exhibits good crystallinity, uniform size distribution and good electrochemical performance, and has an initial specific capacity of 120 mA.h/g at a rate of 0.1C （1C=148 mA/g） and a good rate capability at high rates, even up to 50C.展开更多
The karst process acts as carbon sequestration for atmospheric CO_2.The amount of karst carbon sequestration (KCS) depends on the discharge of karst catchment and inorganic carbon concentration of the water body.Based...The karst process acts as carbon sequestration for atmospheric CO_2.The amount of karst carbon sequestration (KCS) depends on the discharge of karst catchment and inorganic carbon concentration of the water body.Based on the data from the monitoring station on Banzhai subterranean stream located in Maolan National Nature Reserve of Guizhou province,the process and influence factors of KCS have been analyzed.It shows that the amount of KCS is about 353 t C per year in the catchment of Banzhai subterranean stream,and there is good linear relationship between the strength of KCS and discharge of the stream at various time scales.Therefore,how to monitor the discharge accurately is the key to the estimation of KCS.And stations with real-time monitoring function are very important for KCS calculation because of strong seasonal variability of the karst water cycle.展开更多
Nowadays, technologies in construction field have offered several kinds of chemical admixtures, which offer different behaviors at the fresh state of the batch and by consequence, it is resulted with different mechani...Nowadays, technologies in construction field have offered several kinds of chemical admixtures, which offer different behaviors at the fresh state of the batch and by consequence, it is resulted with different mechanical behaviors at the solid state of the mix. This study focused on the behavior of a new kind of admixture at fresh and solid states. Currently, the concrete material has become a very expensive material because the high price mostly of aggregates, representing the three quarters of the concrete components. By consequence, it costs money and on the other hand, it produces a lot of wastes. The main aspect which guides this study is to make a kind of concrete based mainly on local material and sustainable concrete material （SCM or waste material）, which is one very abundant material in quality and quantity, under the current tendency the results obtained in this study summarize up the importance of the temperature during the development of the mechanical characteristics of mortar, mainly on compressive strength at age of 28 days. This is in the case of the addition of limestone crushed additive by percentage of substitution.展开更多
A field study was conducted in the paddy soil amended with municipal solid waste （MSW） and sewage sludge （SS） to find out total, DTPA extractable nickel （Ni） and chrome （Cr） in soil and their uptake by rice pl...A field study was conducted in the paddy soil amended with municipal solid waste （MSW） and sewage sludge （SS） to find out total, DTPA extractable nickel （Ni） and chrome （Cr） in soil and their uptake by rice plant as split-plot arrangement based on randomized complete block design with three replications. The results indicated that the most available Ni （2.10 ppm） measured under 3 years application of 40 ton.ha~ MSW＋I/2 chemical fertilizer （CF）. Also, with 3 application of 40 ton-ha＂l MSW concluded the highest available Cr. The most accumulation of Ni in root （14.51 ppm） and grain （8.89 ppm） happened under 3 years application of 40 ton.ha-1 SS and 20 ton ha-1 MSW＋I/2 CF, respectively. With application of 40 ton.ha-1 SS and 40 ton SS＋1/2 CF, respectively happened the maximum Cr uptake by root and grain （12.43 and 3.65 ppm, respectively）.展开更多
During the hydration process, the Ultra-fine Cements present specific physical and chemical characteristics; they are, very short setting time and high heat release. For special applications, such as rapid hardening a...During the hydration process, the Ultra-fine Cements present specific physical and chemical characteristics; they are, very short setting time and high heat release. For special applications, such as rapid hardening and early high strength mortars or concretes, these characteristics can be considered advantageous. Some commercial products used for concrete reinforcement and repairs are the Rapid Hardening Mortars, these mortars must develop a time of setting up to 3 h and an initial compressive strength of about 3.5 MPa once the hardening of the paste is reached. The objective of the present research work is to use Ultra-fine Cement for the preparation of a series of different Rapid Hardening Mortars （with different percentages of Ultra-fine Cement）, these mortars required the addition of a polycarboxylate-base specification F Superplasticizer. It was observed that the optimum water/cement （W/C） ratio for the hydration of the Ultra-fine Cements is W/C = 0.385. The Ultra-fine Cements were obtained by the High Energy Ball-milling technique at laboratory scale, 90% of the Particle Size Distribution is below 11 μm and the Blaine Specific Surface Area is over 9000 cm^2/g.展开更多
基金Project supported by the Research Funds of the Key Laboratory of Fuel Cell Technology of Guangdong Province,ChinaProject(7411793079907)supported by the Guangzhou Special Foundation for Applied Basic Research+1 种基金Project(2013A15GX048)supported by the Dalian Science and Technology Project Foundation,ChinaProject(21376035)supported by the National Natural Science Foundation of China
文摘Synthesis of the spinel structure lithium manganese oxide （LiMn2O4） by supercritical hydrothermal （SH） accelerated solid state reaction （SSR） route was studied. The impacts of the reaction pressure, reaction temperature and reaction time of SH route, and the calcination temperature of SSR route on the purity, particle morphology and electrochemical properties of the prepared LiMn2O4 materials were studied. The experimental results show that after 15 min reaction in SH route at 400 ℃ and 30 MPa, the reaction time of SSR could be significantly decreased, e.g. down to 3 h with the formation temperature of 800 ℃, compared with the conventional solid state reaction method. The prepared LiMn2O4 material exhibits good crystallinity, uniform size distribution and good electrochemical performance, and has an initial specific capacity of 120 mA.h/g at a rate of 0.1C （1C=148 mA/g） and a good rate capability at high rates, even up to 50C.
基金funded by the project (No.41072192)from National Natural Science Foundation of Chinathe project(No.1212011087122)from China Geological Survey
文摘The karst process acts as carbon sequestration for atmospheric CO_2.The amount of karst carbon sequestration (KCS) depends on the discharge of karst catchment and inorganic carbon concentration of the water body.Based on the data from the monitoring station on Banzhai subterranean stream located in Maolan National Nature Reserve of Guizhou province,the process and influence factors of KCS have been analyzed.It shows that the amount of KCS is about 353 t C per year in the catchment of Banzhai subterranean stream,and there is good linear relationship between the strength of KCS and discharge of the stream at various time scales.Therefore,how to monitor the discharge accurately is the key to the estimation of KCS.And stations with real-time monitoring function are very important for KCS calculation because of strong seasonal variability of the karst water cycle.
文摘Nowadays, technologies in construction field have offered several kinds of chemical admixtures, which offer different behaviors at the fresh state of the batch and by consequence, it is resulted with different mechanical behaviors at the solid state of the mix. This study focused on the behavior of a new kind of admixture at fresh and solid states. Currently, the concrete material has become a very expensive material because the high price mostly of aggregates, representing the three quarters of the concrete components. By consequence, it costs money and on the other hand, it produces a lot of wastes. The main aspect which guides this study is to make a kind of concrete based mainly on local material and sustainable concrete material （SCM or waste material）, which is one very abundant material in quality and quantity, under the current tendency the results obtained in this study summarize up the importance of the temperature during the development of the mechanical characteristics of mortar, mainly on compressive strength at age of 28 days. This is in the case of the addition of limestone crushed additive by percentage of substitution.
文摘A field study was conducted in the paddy soil amended with municipal solid waste （MSW） and sewage sludge （SS） to find out total, DTPA extractable nickel （Ni） and chrome （Cr） in soil and their uptake by rice plant as split-plot arrangement based on randomized complete block design with three replications. The results indicated that the most available Ni （2.10 ppm） measured under 3 years application of 40 ton.ha~ MSW＋I/2 chemical fertilizer （CF）. Also, with 3 application of 40 ton-ha＂l MSW concluded the highest available Cr. The most accumulation of Ni in root （14.51 ppm） and grain （8.89 ppm） happened under 3 years application of 40 ton.ha-1 SS and 20 ton ha-1 MSW＋I/2 CF, respectively. With application of 40 ton.ha-1 SS and 40 ton SS＋1/2 CF, respectively happened the maximum Cr uptake by root and grain （12.43 and 3.65 ppm, respectively）.
文摘During the hydration process, the Ultra-fine Cements present specific physical and chemical characteristics; they are, very short setting time and high heat release. For special applications, such as rapid hardening and early high strength mortars or concretes, these characteristics can be considered advantageous. Some commercial products used for concrete reinforcement and repairs are the Rapid Hardening Mortars, these mortars must develop a time of setting up to 3 h and an initial compressive strength of about 3.5 MPa once the hardening of the paste is reached. The objective of the present research work is to use Ultra-fine Cement for the preparation of a series of different Rapid Hardening Mortars （with different percentages of Ultra-fine Cement）, these mortars required the addition of a polycarboxylate-base specification F Superplasticizer. It was observed that the optimum water/cement （W/C） ratio for the hydration of the Ultra-fine Cements is W/C = 0.385. The Ultra-fine Cements were obtained by the High Energy Ball-milling technique at laboratory scale, 90% of the Particle Size Distribution is below 11 μm and the Blaine Specific Surface Area is over 9000 cm^2/g.
