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基于双配体金属有机骨架电化学传感食品包装中迁移的壬基酚
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作者 黄迪惠 李梅 +3 位作者 陈锦阳 杨嘉宜 代莉莉 叶瑞洪 《现代食品科技》 CAS 北大核心 2023年第3期323-330,共8页
该研究制备了一种基于铁基金属有机骨架负载于高导电石墨烯(Fe-HHTP-HITP-HCG)的电化学传感器测定痕量的壬基酚(NP)。双配体金属有机骨架(Fe-HHTP-HITP)在高导电石墨烯(HCG)的空隙中生长而成Fe-HHTP-HITP-HCG,然后通过滴涂成膜的方式制... 该研究制备了一种基于铁基金属有机骨架负载于高导电石墨烯(Fe-HHTP-HITP-HCG)的电化学传感器测定痕量的壬基酚(NP)。双配体金属有机骨架(Fe-HHTP-HITP)在高导电石墨烯(HCG)的空隙中生长而成Fe-HHTP-HITP-HCG,然后通过滴涂成膜的方式制成电化学传感器;考察了缓冲液的种类、pH值、配体比例、HCG比例、累积电位、累积时间等实验条件;采用循环伏安法(CV)、场发射扫描电子显微镜(SEM)、傅立叶红外光谱(FT-IR)和X射线衍射(XRD)对电极的性能进行了评价。实验显示,Fe-HHTP-HITP-HCG具有较高的电化学活性与催化活性,有良好的响应作用。实验结果显示,当涂层为4层时,NP的检测浓度范围为1.0×10^(-7)mol/L~1.0×10^(-4)mol/L,检出限为1.22×10^(-8)mol/L。该传感器应用于牛奶袋迁移出的NP时,其加标回收率范围为96.90%~102.00%。因此,实验提出了一种利用金属有机骨架复合材料进行NP灵敏度检测的新策略。 展开更多
关键词 壬基酚 双配体金属有机骨架 高导电石墨烯 循环伏安法 电化学传感器
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Low-power memristors based on layered 2D SnSe/graphene materials 被引量:7
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作者 Hong Wang Tianqi Yu +2 位作者 Jianhui Zhao Shufang Wang Xiaobing Yan 《Science China Materials》 SCIE EI CAS CSCD 2021年第8期1989-1996,共8页
The emerging two-terminal memristor with a conductance-adjustable function under external stimulation is considered a strong candidate for use in artificial memory and electronic synapses. However, the stability, unif... The emerging two-terminal memristor with a conductance-adjustable function under external stimulation is considered a strong candidate for use in artificial memory and electronic synapses. However, the stability, uniformity, and power consumption of memristors are still challenging in neuromorphic computing. Here an Au/SnSe/graphene/SiO_(2)/Si memristor was fabricated, incorporating two-dimensional graphene with high thermal conductivity. The device not only exhibits excellent electrical characteristics(e.g., high stability,good uniformity and a high ROFF/RON ratio), but also can implement biological synaptic functions such as paired-pulse facilitation, short-term plasticity and long-term plasticity. Its set and reset power values can be as low as 16.7 and 2.3 nW,respectively. Meanwhile, the resistance switching mechanism for the device, which might be associated with the formation and rupture of a filamentary conducting path consisting of Sn vacancies, was confirmed by high-resolution transmission electron microscopy observations. The proposed device is an excellent candidate for use in high-density storage and lowpower neuromorphic computing applications. 展开更多
关键词 GRAPHENE SnSe MEMRISTOR electronic synapse
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