Aqueous organic flow batteries have attracted dramatic attention for stationary energy storage due to their resource sustainability and low cost. However, the current reported systems can normally be operated stably u...Aqueous organic flow batteries have attracted dramatic attention for stationary energy storage due to their resource sustainability and low cost. However, the current reported systems can normally be operated stably under a nitrogen or argon atmosphere due to their poor stability. Herein a stable airinsensitive biphenol derivative cathode, 3,30,5,50-tetramethylaminemethylene-4,40-biphenol(TABP), with high solubility(>1.5 mol L^(-1)) and redox potential(0.91 V vs. SHE) is designed and synthesized by a scalable one-step method. Paring with silicotungstic acid(SWO), an SWO/TABP flow battery shows a stable performance of zero capacity decay over 900 cycles under the air atmosphere. Further, an SWO/TABP flow battery manifests a high rate performance with an energy efficiency of 85% at a current density of60 m A cm^(-2) and a very high volumetric capacity of more than 47 Ah L^(-1). This work provides a new and practical option for next-generation practical large-scale energy storage.展开更多
In this paper, a split step ABCD matrix method is suggested to investigate Gaussian beam propagation in a Kerr type metamaterial medium. This method is based on dividing the medium interval into subsequent steps.Meanw...In this paper, a split step ABCD matrix method is suggested to investigate Gaussian beam propagation in a Kerr type metamaterial medium. This method is based on dividing the medium interval into subsequent steps.Meanwhile, Gaussian beam profile in every step is obtained by finding the ABCD matrix of that particular step, and is used to find the ABCD matrix of the next step. Results of the suggested matrix method have been compared with the results of numerical split-step Fourier method for a Kerr medium, which indicates a good agreement. Then, we use the ABCD matrix to investigate Gaussian beams propagation in a Kerr type metamaterial, which is also in agreement with pervious results by other methods.展开更多
Using a variational approach,the propagation of a moderately intense laser pulse in a parabolic preformed plasma channel is investigated.The effects of higher-order relativistic nonlinearity (HRN) and wakefield are in...Using a variational approach,the propagation of a moderately intense laser pulse in a parabolic preformed plasma channel is investigated.The effects of higher-order relativistic nonlinearity (HRN) and wakefield are included.The effect of HRN serves as an additional defocusing mechanism and has the same order of magnitude in the spot size as that of the transverse wakefield (TWF).The effect of longitudinal wakefield is much larger than those of HRN and TWF for an intense laser pulse with the pulse length equaling the plasma wavelength.The catastrophic focusing of the laser spot size would be prevented in the present of HRN and then it varies with periodic focusing oscillations.展开更多
基金The authors acknowledge financial support from the National Natural Science Foundation of China(21925804,21935003)CASDOE Collaborative Project(121421KYSB20170032)+1 种基金CAS Engineering Laboratory for Electrochemical Energy Storage,Liaoning Revitalization Talents Program(XLYC1802050)China and DICP funding,China(ZZBS201707)。
文摘Aqueous organic flow batteries have attracted dramatic attention for stationary energy storage due to their resource sustainability and low cost. However, the current reported systems can normally be operated stably under a nitrogen or argon atmosphere due to their poor stability. Herein a stable airinsensitive biphenol derivative cathode, 3,30,5,50-tetramethylaminemethylene-4,40-biphenol(TABP), with high solubility(>1.5 mol L^(-1)) and redox potential(0.91 V vs. SHE) is designed and synthesized by a scalable one-step method. Paring with silicotungstic acid(SWO), an SWO/TABP flow battery shows a stable performance of zero capacity decay over 900 cycles under the air atmosphere. Further, an SWO/TABP flow battery manifests a high rate performance with an energy efficiency of 85% at a current density of60 m A cm^(-2) and a very high volumetric capacity of more than 47 Ah L^(-1). This work provides a new and practical option for next-generation practical large-scale energy storage.
文摘In this paper, a split step ABCD matrix method is suggested to investigate Gaussian beam propagation in a Kerr type metamaterial medium. This method is based on dividing the medium interval into subsequent steps.Meanwhile, Gaussian beam profile in every step is obtained by finding the ABCD matrix of that particular step, and is used to find the ABCD matrix of the next step. Results of the suggested matrix method have been compared with the results of numerical split-step Fourier method for a Kerr medium, which indicates a good agreement. Then, we use the ABCD matrix to investigate Gaussian beams propagation in a Kerr type metamaterial, which is also in agreement with pervious results by other methods.
基金Supported by the National Natural Science Foundation of China under Grant Nos.11047152,11147005,and 11178002the Natural Science Foundation of Jiangxi Province under Grant Nos.2010GQW0048 and 20122BAB202003
文摘Using a variational approach,the propagation of a moderately intense laser pulse in a parabolic preformed plasma channel is investigated.The effects of higher-order relativistic nonlinearity (HRN) and wakefield are included.The effect of HRN serves as an additional defocusing mechanism and has the same order of magnitude in the spot size as that of the transverse wakefield (TWF).The effect of longitudinal wakefield is much larger than those of HRN and TWF for an intense laser pulse with the pulse length equaling the plasma wavelength.The catastrophic focusing of the laser spot size would be prevented in the present of HRN and then it varies with periodic focusing oscillations.
