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晶态骨架介孔CeO2和CeO2-ZrO2的合成与结构表征 被引量:4
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作者 李霞章 NI Chao-Ying 陈志刚 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2008年第5期986-990,共5页
以乙酸铈、乙酸锫为无机源,嵌段共聚物P123为模版剂,采用溶胶-凝胶法合成了介孔CeO_2及CeO_2-ZrO_2复合体,用XRD、氮气吸附脱附、TEM、HRTEM、SAED等对材料进行了表征.结果表明,所得介孔CeO_2具有规则的晶态孔道结构,孔径约在10nm左右,... 以乙酸铈、乙酸锫为无机源,嵌段共聚物P123为模版剂,采用溶胶-凝胶法合成了介孔CeO_2及CeO_2-ZrO_2复合体,用XRD、氮气吸附脱附、TEM、HRTEM、SAED等对材料进行了表征.结果表明,所得介孔CeO_2具有规则的晶态孔道结构,孔径约在10nm左右,特别是其孔壁晶粒高度定向排列且平行于孔道方向.原位高温TEM观测表明,该介孔CeO_2在800℃仍具有很高的孔道完整性.掺杂ZrO_2后发现,在ZrO_2摩尔含量低于30%时仍具备高度定向排列结构,高于30%时骨架晶粒取向逐渐趋向无序化. 展开更多
关键词 高度定向排列 介孔CeO2 原位TEM 热稳定性
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电子功能外延薄膜的电沉积(英文)
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作者 黄葵 黄容姣 +1 位作者 刘素琴 何震 《电化学》 CAS CSCD 北大核心 2022年第7期23-46,共24页
电沉积作为一种在温和条件下从溶液中合成材料的技术已被广泛应用于在导体和半导体基底表面合成各种功能材料。电沉积一般由人为施加于基底的电刺激(如:施加电位/电流)来触发。这种电刺激通过氧化或还原靠近基底表面的溶液层内部的离子... 电沉积作为一种在温和条件下从溶液中合成材料的技术已被广泛应用于在导体和半导体基底表面合成各种功能材料。电沉积一般由人为施加于基底的电刺激(如:施加电位/电流)来触发。这种电刺激通过氧化或还原靠近基底表面的溶液层内部的离子、分子或配合物从而使该溶液层偏离其热力学平衡状态,随后引起目标产物在基底表面的沉积。在电沉积过程中,许多实验参数都可能从不同的方面对沉积物的物化性质造成影响。迄今为止,已通过电沉积制备出多种单质(包括金属和非金属单质)、化合物(例如:金属氧化物、金属氢氧化物、金属硫化物等)以及复合材料。电沉积制备的这些材料大多为多晶、织构或外延薄膜的形式。其中,外延薄膜是一种具有特定的面外和面内晶体生长取向且其晶体取向受基底控制的类单晶薄膜。由于外延薄膜中高度有序的原子排列,它们常呈现出独特的电磁性质。本文总结了常见的电沉积合成路线及影响沉积物外延生长的关键实验因素。此外,本文简要介绍了用于表征外延薄膜的技术。最后,本文还讨论了一些采用电沉积制备的具有特殊电子、电磁及光电特性的功能外延薄膜。 展开更多
关键词 电沉积 电镀 薄膜 高度定向
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Uncertainty analysis of ship model vertical center of gravity and transverse moment of inertia test 被引量:1
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作者 史圣哲 郑亚雄 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2015年第1期41-46,共6页
The usability of test results of ship model vertical center of gravity and transverse moment of inertia is generally depends on its uncertainty. Referring to the guidelines for uncertainty analysis in examination of l... The usability of test results of ship model vertical center of gravity and transverse moment of inertia is generally depends on its uncertainty. Referring to the guidelines for uncertainty analysis in examination of liquid dynamic recommended by International Towing Tank Conference ( ITTC), the results were analyzed, bias limits and precision limits were calculated and total uncertainty was estimated. The total uncertainty of six tests on ship model vertical center of gravity is is 0. 16% of the mean value, and the total uncertainty of six tests on ship model transverse moment of inertia is 5.66% of the mean value. The test results show that the total uncertainty of both the multiple tests and the single test is from the precision limits of ship model vertical center of gravity and transverse moment of inertia tests. Thus, the improved measurement system stability can enormously decrease the total uncertainty of multiple tests and the single test. 展开更多
关键词 ship model test vertical center of gravity transverse moment of inertia uncertainty analysis
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An orientation method and analysis of optical radiation sources based on polyhedron and parallel incident light 被引量:1
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作者 WANG Jiang 《Science China(Technological Sciences)》 SCIE EI CAS 2013年第2期475-483,共9页
The spatial orientation of optical radiation sources has long been the hot topic in the aerospace and the military applications.Current researches mainly focus on the high precision orientation on the partial field of... The spatial orientation of optical radiation sources has long been the hot topic in the aerospace and the military applications.Current researches mainly focus on the high precision orientation on the partial field of view.Thus,combination of several partial fields of view is required to achieve orientation when the field of view exceeds 180°,which results in the increase of size,weight,power consumption and the cost.By defining radiation energy and direction of the optical radiation source as a vector and applying the cosine law of radiation and vector theorem,it is shown that the vector can be obtained from unit normal vectors on the three un-coplanar surfaces and from the energy projected by the optical radiation source.Based on this,an orientation method with 360° full field of view by a polyhedron is suggested,the mathematical formula for anti-multipath interference is supposed and the error upper limit is derived.The feasibility and effectiveness of this method are validated by measurements and simulation.An accuracy better than 2.866° and 0.574° is achieved when the ratio of measurement error of energy on arbitrary surface and the true value are 5% and 1%,respectively,given the matrix composed of unit normal vectors on three measurement surfaces is orthogonal. 展开更多
关键词 optical radiation sources orientation radiation energy unit normal vector POLYHEDRON
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