Dynamic characteristics of UV enhanced gas–solid PVC chlorination process were revealed by a UV–Vis spectral online analysis method. Experimental results showed an instantaneous increase of the chlorination rate as ...Dynamic characteristics of UV enhanced gas–solid PVC chlorination process were revealed by a UV–Vis spectral online analysis method. Experimental results showed an instantaneous increase of the chlorination rate as soon as UV light was affiliated, which demonstrated the intensified effect of UV radiation on PVC chlorination directly.Different affiliation methods of UV light were then studied, proving that continuous UV radiation could enhance the chlorination process significantly while intermittent UV radiation was able to initiate the chlorination reaction once it was conducted. Besides, experiments were carried out to study the influences of parameters on the chlorination process such as UV wavelength, chlorination temperature, partial pressure of chlorine gas and PVC raw materials. Among all the parameters, chlorination temperature and partial pressure of chlorine gas were testified as two key factors to determine the chlorination performance. Thermal analysis of CPVC products showed that their corresponding properties such as the glass transition temperature(Tg) and the homogeneity of chlorine distribution in polymer phase were improved with the increase of chlorine content.展开更多
An algorithm （differential mode） is presented for the improvement of harmonic tidal analysis along T/P tracks, in which the differences between the observed sea surface heights at adjacent points are taken as observ...An algorithm （differential mode） is presented for the improvement of harmonic tidal analysis along T/P tracks, in which the differences between the observed sea surface heights at adjacent points are taken as observations. Also, the observation equations are constrained with the results of the crossover analysis; the parameter estimations are performed at 0.1° latitude intervals by the least squares. Cycle 10 to 330 T/P altimeter data covering the China Sea and the Northwest Pacific Ocean （2°-50° N,105°-150° E） are adopted for a refined along-track harmonic tidal analysis, and harmonic constants of 12 constituents in 8 474 points are obtained, which indicates that the algorithm can efficiently remove non-tidal effects in the altimeter observations, and improve the precision of tide parameters. Moreover, parameters along altimetry tracks represent a smoother distribution than those obtained by traditional algorithms. The root mean squares of the fitting errors between the tidal height model and the observations reduce from 11 cm to 1.3 cm.展开更多
Environmental impact evaluation system boundary of high-speed railway was defined based on the total life cycle theory,and the index system to evaluate the environmental impact of high-speed railway was established wi...Environmental impact evaluation system boundary of high-speed railway was defined based on the total life cycle theory,and the index system to evaluate the environmental impact of high-speed railway was established with the fuzzy analytic hierarchy method,and the matter-element evaluation model was established on the basis of the extension theory.By calculating its comprehensive interrelatedness,the evaluation rank of environment impacts of high-speed railway was determined.The numerical example shows that the model has vast prospect,which can not only expand the application areas of extension theory,but also change the traditional evaluation methods and provide new ideas and means for environmental impact evaluation of high-speed railway.展开更多
The standard finite elements of degree p over the rectangular meshes are applied to solve a kind of nonlinear viscoelastic wave equations with nonlinear boundary conditions, and the superclose property of the continuo...The standard finite elements of degree p over the rectangular meshes are applied to solve a kind of nonlinear viscoelastic wave equations with nonlinear boundary conditions, and the superclose property of the continuous Galerkin approximation is derived without using the nonclassical elliptic projection of the exact solution of the model problem. The global superconvergence of one order higher than the traditional error estimate is also obtained through the postprocessing technique.展开更多
基金Supported by the National Science and Technology Key Supporting Project(2013BAF08B05)the National Natural Science Foundation of China(21176137)
文摘Dynamic characteristics of UV enhanced gas–solid PVC chlorination process were revealed by a UV–Vis spectral online analysis method. Experimental results showed an instantaneous increase of the chlorination rate as soon as UV light was affiliated, which demonstrated the intensified effect of UV radiation on PVC chlorination directly.Different affiliation methods of UV light were then studied, proving that continuous UV radiation could enhance the chlorination process significantly while intermittent UV radiation was able to initiate the chlorination reaction once it was conducted. Besides, experiments were carried out to study the influences of parameters on the chlorination process such as UV wavelength, chlorination temperature, partial pressure of chlorine gas and PVC raw materials. Among all the parameters, chlorination temperature and partial pressure of chlorine gas were testified as two key factors to determine the chlorination performance. Thermal analysis of CPVC products showed that their corresponding properties such as the glass transition temperature(Tg) and the homogeneity of chlorine distribution in polymer phase were improved with the increase of chlorine content.
基金Supported by the National Natural Science Foundation of China （No. 40671161） and the Open Research Fund Program of the Key Laboratory of Geospace Environment and Geodesy, Ministry of Education, China（No.1469990324233-03-04）.
文摘An algorithm （differential mode） is presented for the improvement of harmonic tidal analysis along T/P tracks, in which the differences between the observed sea surface heights at adjacent points are taken as observations. Also, the observation equations are constrained with the results of the crossover analysis; the parameter estimations are performed at 0.1° latitude intervals by the least squares. Cycle 10 to 330 T/P altimeter data covering the China Sea and the Northwest Pacific Ocean （2°-50° N,105°-150° E） are adopted for a refined along-track harmonic tidal analysis, and harmonic constants of 12 constituents in 8 474 points are obtained, which indicates that the algorithm can efficiently remove non-tidal effects in the altimeter observations, and improve the precision of tide parameters. Moreover, parameters along altimetry tracks represent a smoother distribution than those obtained by traditional algorithms. The root mean squares of the fitting errors between the tidal height model and the observations reduce from 11 cm to 1.3 cm.
基金Project(2011QNZT062)supported by the Fundamental Research Funds for Central Universities of China
文摘Environmental impact evaluation system boundary of high-speed railway was defined based on the total life cycle theory,and the index system to evaluate the environmental impact of high-speed railway was established with the fuzzy analytic hierarchy method,and the matter-element evaluation model was established on the basis of the extension theory.By calculating its comprehensive interrelatedness,the evaluation rank of environment impacts of high-speed railway was determined.The numerical example shows that the model has vast prospect,which can not only expand the application areas of extension theory,but also change the traditional evaluation methods and provide new ideas and means for environmental impact evaluation of high-speed railway.
基金supported by the National Natural Science Foundation of China under Grant Nos.10671184 and 10971203
文摘The standard finite elements of degree p over the rectangular meshes are applied to solve a kind of nonlinear viscoelastic wave equations with nonlinear boundary conditions, and the superclose property of the continuous Galerkin approximation is derived without using the nonclassical elliptic projection of the exact solution of the model problem. The global superconvergence of one order higher than the traditional error estimate is also obtained through the postprocessing technique.
