Coal bump is a dynamic process,thus it is necessary to reveal the process validly.2D-ball code is an efficient approach developed by the authors based on the basicDEM rationale proposed by Cundall.Numerical simulation...Coal bump is a dynamic process,thus it is necessary to reveal the process validly.2D-ball code is an efficient approach developed by the authors based on the basicDEM rationale proposed by Cundall.Numerical simulations show that the coal bump experiencesa process of energy accumulation,sudden release of energy and energy decrease.The stiffness of coal particles has a great influence on the coal bump morphosisand particle velocity.Generally,the larger the stiffness of particles,the longer the shootingoff period and the larger the bump velocity.This is in agreement with the results of laboratoryexperiment and in-situ studies.However,the stiffness of particles has an influence onthe quantity value energy and no influence on the releasing energy pattern of the coalbump.展开更多
To predict the temperature of a motorized spindle more accurately,a novel temperature prediction model based on the back-propagation neural network optimized by adaptive particle swarm optimization(APSO-BPNN)is propos...To predict the temperature of a motorized spindle more accurately,a novel temperature prediction model based on the back-propagation neural network optimized by adaptive particle swarm optimization(APSO-BPNN)is proposed.First,on the basis of the PSO-BPNN algorithm,the adaptive inertia weight is introduced to make the weight change with the fitness of the particle,the adaptive learning factor is used to obtain different search abilities in the early and later stages of the algorithm,the mutation operator is incorporated to increase the diversity of the population and avoid premature convergence,and the APSO-BPNN model is constructed.Then,the temperature of different measurement points of the motorized spindle is forecasted by the BPNN,PSO-BPNN,and APSO-BPNN models.The experimental results demonstrate that the APSO-BPNN model has a significant advantage over the other two methods regarding prediction precision and robustness.The presented algorithm can provide a theoretical basis for intelligently controlling temperature and developing an early warning system for high-speed motorized spindles and machine tools.展开更多
Supercapacitors operating in aqueous solutions are low cost energy storage devices with high cycling stability and fast charging and discharging capabilities, but generally suffer from low energy densities. Here, we g...Supercapacitors operating in aqueous solutions are low cost energy storage devices with high cycling stability and fast charging and discharging capabilities, but generally suffer from low energy densities. Here, we grow Ni(OH)2 nanoplates and RuO2 nanoparticles on high quality graphene sheets in order to maximize the specific capacitances of these materials. We then pair up a Ni(OH)2/graphene electrode with a RuO2/graphene electrode to afford a high performance asymmetrical supercapacitor with high energy and power density operating in aqueous solutions at a voltage of -1.5 V. The asymmetrical supercapacitor exhibits significantly higher energy densities than symmetrical RuO2-RuO2 supercapacitors or asymmetrical supercapacitors based on either RuO2- carbon or Ni(OH)2-carbon electrode pairs. A high energy density of -48 W.h/kg at a power density of -0.23 kW/kg, and a high power density of -21 kW/kg at an energy density of N14 W-h/kg have been achieved with our Ni(OH)2/graphene and RuO2/graphene asymmetrical supercapacitor. Thus, pairing up metal-oxide/graphene and metal-hydroxide/graphene hybrid materials for asymmetrical supercapacitors represents a new approach to high performance energy storage.展开更多
The most commonly found fingermarks at crime scenes are latent and, thus, an efficient method for detecting latent fingermarks is very important. However, traditional developing techniques have drawbacks such as low d...The most commonly found fingermarks at crime scenes are latent and, thus, an efficient method for detecting latent fingermarks is very important. However, traditional developing techniques have drawbacks such as low detection sensitivity, high background interference, complicated operation, and high toxicity. To tackle this challenge, we employed fluorescent NaYF4:Yb, Er upconversion nanoparticles (UCNPs), which can fluoresce visible light when excited by 980 nm human-safe near-infrared light, to stain the latent fingermarks on various substrate surfaces. The UCNPs were successfully used as a novel fluorescent label for the detection of latent fingermarks with high sensitivity, low background, high efficiency, and low toxicity on various substrates including non-infiltrating materials (glass, marble, aluminum alloy sheets, stainless steel sheets, aluminum foils, and plastic cards), semi-infiltrating materials (floor leathers, ceramic tiles, wood floor, and painted wood), and infiltrating materials such as various types of papers. This work shows that UCNPs are a versatile fluorescent label for the facile detection of fingermarks on virtually any material, enabling their practical applications in forensic sciences.展开更多
Disturbances in the metabolism of lipoprotein profiles and oxidative stress in hemodialyzed (HD) and post-renal transplant (Tx) patients are proatherogenic, but elevated concentrations of plasma high-density lipop...Disturbances in the metabolism of lipoprotein profiles and oxidative stress in hemodialyzed (HD) and post-renal transplant (Tx) patients are proatherogenic, but elevated concentrations of plasma high-density lipoprotein (HDL) reduce the risk of cardiovascular disease. We investigated the concentrations of lipid, lipoprotein, HDL particle, oxidized low-density lipoprotein (ox-LDL) and anti-ox-LDL, and paraoxonase-1 (PON-1) activity in HD (n=33) and Tx (n=71) patients who were non-smokers without active inflammatory disease, liver disease, diabetes, or malignancy. HD patients had moderate hypertriglyceridemia, normocholesterolemia, low HDL-C, apolipoprotein A-I (apoA-I) and HDL particle concentrations as well as PON-1 activity, and increased ox-LDL and anti-ox-LDL levels. Tx patients had hypertriglyceridemia, hypercholesterolemia, moderately decreased HDL-C and HDL particle concentrations and PON-1 activity, and moderately increased ox-LDL and anti-ox-LDL levels as compared to the reference, but ox-LDL and anti-ox-LDL levels and PON-1 activity were more disturbed in HD patients. However, in both patient groups, lipid and lipoprotein ratios (total cholesterol (TC)/HDL-C, LDL-C/HDL-C, triglyceride (TG)/HDL-C, HDL-C/non-HDL-C, apoA-I/apoB, HDL-C/apoA-I, TG/HDL) were atherogenic. The Spearman's rank coefficient test showed that the concentration of ox-LDL correlated positively with HDL particle level (R=0.363, P=0.004), and negatively with TC (R=-0.306, P=0.012), LDL-C (R=-0.283, P=0.020), and non-HDL-C (R=-0.263, P=0.030) levels in Tx patients. Multiple stepwise forward regression analysis in Tx patients demonstrated that ox-LDL concentration, as an independent variable, was associated significantly positively with HDL particle level. The results indicated that ox-LDL and de- creased PON-1 activity in Tx patients may give rise to more mildly-oxidized HDLs, which are less stable, easily undergo metabolic remodeling, generate a greater number of smaller pre-13-HDL particles, and thus accelerate reverse cholesterol transport, which may be beneficial for Tx patients. Further studies are necessary to confirm this.展开更多
Previous wind tunnel experiments on snow drift usually used artificial snow as a substitute of natural snow, which can not fully reflect the motion characteristics of snow drift in natural environments. In this paper ...Previous wind tunnel experiments on snow drift usually used artificial snow as a substitute of natural snow, which can not fully reflect the motion characteristics of snow drift in natural environments. In this paper we conducted a series of experiments in wind tunnel to investigate the motion of natural snow (fresh snow and old snow), which was collected out-door without destroying the surface structure. The results indicated that the threshold velocity of fresh snow is less than that of old snow, and that the mass flux rates of the two kinds of snow exponentially decrease with height whereas the snow transport rate increases exponentially with wind velocity. Based on the PIV measuring of the velocities of snow particles over two kinds of terrains (flat ground and roadbed), we found that the particle velocity obeys a Gaussian distribution for flat ground, top surface and leeward slope of the roadbed. However, for the windward slope of roadbed the particle velocity distribution displays poor correlation with a Gaussian function due to the acceleration of snow particles when saltating across the slop. Statistical analysis showed that impacting and liftoff velocities of snow particles also obey Gaussian distributions.展开更多
Combustion characteristics of nanofluid fuels containing aluminum nanoparticles were investigated in half-opening slot tubes from the fundamental view. The effects of particle loading rates(0.25% and 2.5% by weight), ...Combustion characteristics of nanofluid fuels containing aluminum nanoparticles were investigated in half-opening slot tubes from the fundamental view. The effects of particle loading rates(0.25% and 2.5% by weight), type of base fuels(ethanol and butanol),and fuel flow rates(0.2, 0.6, and 1 mL/min) were studied in details. The combustion characteristics of the nanofluid fuels and pure based fuels were also examined to provide a comparison. Flame was unstable with reignition, stable state, nearly extinguishment repeatedly at low flow rate. At medium flow rate, flame height was increased and flame tended to be stable. At high flow rate,flame became unstable and was disturbed by the droplet forming and dripping significantly. Al atoms inside the oxide layer should be melted before the particles combustion, while Al oxide layer should be melted before the particles aggregates combustion. The effects of particles on the combustion characteristics, especially on the evaporation rate of base fuel, were discussed. The reasons for various combustion phenomena of nanofluid fuels were given, which can provide the useful guidance for the experimental research and practical applications of nanofluid fuels.展开更多
In the paper,the behavior of the particle acted by the oscillating bubble is studied using a high-speed video camera.The bubble is generated using a very low voltage of 55 V.Images are captured at a speed of 15000 fps...In the paper,the behavior of the particle acted by the oscillating bubble is studied using a high-speed video camera.The bubble is generated using a very low voltage of 55 V.Images are captured at a speed of 15000 fps(frames per second).It is found that the velocity of the particle is dependent on the liquid viscosity,particle size,and tube diameter.Particle velocity decreases with the increase of the glycron-water mixture viscosity.A model is presented to predict the velocity and verified by experimental results.These observations may be beneficial for the application in medical treatment.展开更多
Magnetic nanoscale systems,including nanodots,nanofibers,nanowires and nanoparticles,are currently attracting great interest due to their interesting physical and promising applications in various fields,such as magne...Magnetic nanoscale systems,including nanodots,nanofibers,nanowires and nanoparticles,are currently attracting great interest due to their interesting physical and promising applications in various fields,such as magnetic recording,sensors,target drugs and catalysts,as well as others.To achieve ultrahigh recording density,the method of heat assisted magnetic recording(HAMR) has been introduced.In this work,with the help of a Monte Carlo method,the mechanisms of thermally assisted magnetization switching in FePt single-domain particles driven by an external magnetic field are investigated,where the temperature in the particles is assumed to follow a Gaussian distribution.Two nucleation modes are observed for different distributions of temperature.One is initiated by many droplets,which join each other at the boundary of the system;the other is ini-tiated by many droplets at the boundary,but in growth tending toward the inner part of the system.An inverse proportional relationship between the metastable lifetime and the distribution is also found.展开更多
An atomic layer deposition (ALD) method has been employed to synthesize Fe3O4/graphene and Ni/graphene composites. The structure and microwave absorbing properties of the as-prepared composites are investigated. The...An atomic layer deposition (ALD) method has been employed to synthesize Fe3O4/graphene and Ni/graphene composites. The structure and microwave absorbing properties of the as-prepared composites are investigated. The surfaces of graphene are densely covered by Fe3O4 or Ni nanoparticles with a narrow size distribution, and the magnetic nanoparticles are well distributed on each graphene sheet without significant conglomeration or large vacancies. The coated graphene materials exhibit remarkably improved electromagnetic (EM) absorption properties compared to the pristine graphene. The optimal reflection loss (RL) reaches -46.4 dB at 15.6 GHz with a thickness of only 1.4 mm for the Fe3O4/graphene composites obtained by applying 100 cycles of Fe2O3 deposition followed by a hydrogen reduction. The enhanced absorption ability arises from the effective impedance matching, multiple interfacial polarization and increased magnetic loss from the added magnetic constituents. Moreover, compared with other recently reported materials, the composites have a lower filling ratio and smaller coating thickness resulting in significantly increased EM absorption properties. This demonstrates that nanoscale surface modification of magnetic particles on graphene by ALD is a very promising way to design lightweight and high-efficiency microwave absorbers.展开更多
We present an empirical model for the effective thermal conductivity (ETC) of a polymer composite that includes dependency on the filler size distribution-chosen as the Rosin-Rammler distribution. The ETC is determine...We present an empirical model for the effective thermal conductivity (ETC) of a polymer composite that includes dependency on the filler size distribution-chosen as the Rosin-Rammler distribution. The ETC is determined based on certain hypotheses that connect the behavior of a real composite material A, to that of a model composite material B, filled with mono-dimensional filler. The application of these hypotheses to the Maxwell model for ETC is presented. The validation of the new model and its characteristic equation was carried out using experimental data from the reference. The comparison showed that by using the size distribution law a very good fit between the equation of the new model (the size distribution model for the ETC) and the reference experimental results is obtained, even for high volume fractions, up to about 50%.展开更多
In the solar system, our Sun is Nature's most efficient particle accelerator. In large solar flares and fast coronal mass ejections(CMEs), protons and heavy ions can be accelerated to over ~GeV/nucleon. Large flar...In the solar system, our Sun is Nature's most efficient particle accelerator. In large solar flares and fast coronal mass ejections(CMEs), protons and heavy ions can be accelerated to over ~GeV/nucleon. Large flares and fast CMEs often occur together. However there are clues that different acceleration mechanisms exist in these two processes. In solar flares, particles are accelerated at magnetic reconnection sites and stochastic acceleration likely dominates. In comparison, at CME-driven shocks,diffusive shock acceleration dominates. Besides solar flares and CMEs, which are transient events, acceleration of particles has also been observed in other places in the solar system, including the solar wind termination shock, planetary bow shocks, and shocks bounding the Corotation Interaction Regions(CIRs). Understanding how particles are accelerated in these places has been a central topic of space physics. However, because observations of energetic particles are often made at spacecraft near the Earth,propagation of energetic particles in the solar wind smears out many distinct features of the acceleration process. The propagation of a charged particle in the solar wind closely relates to the turbulent electric field and magnetic field of the solar wind through particle-wave interaction. A correct interpretation of the observations therefore requires a thorough understanding of the solar wind turbulence. Conversely, one can deduce properties of the solar wind turbulence from energetic particle observations. In this article I briefly review some of the current state of knowledge of particle acceleration and transport in the inner heliosphere and discuss a few topics which may bear the key features to further understand the problem of particle acceleration and transport.展开更多
基金Supported by the National Natural Science Fundation of China(50534080,50674063)Taishan Scholar Engineering Construction Fund of Shandong Province of China(J06N04)
文摘Coal bump is a dynamic process,thus it is necessary to reveal the process validly.2D-ball code is an efficient approach developed by the authors based on the basicDEM rationale proposed by Cundall.Numerical simulations show that the coal bump experiencesa process of energy accumulation,sudden release of energy and energy decrease.The stiffness of coal particles has a great influence on the coal bump morphosisand particle velocity.Generally,the larger the stiffness of particles,the longer the shootingoff period and the larger the bump velocity.This is in agreement with the results of laboratoryexperiment and in-situ studies.However,the stiffness of particles has an influence onthe quantity value energy and no influence on the releasing energy pattern of the coalbump.
基金The National Natural Science Foundation of China(No.51465035)the Natural Science Foundation of Gansu,China(No.20JR5R-A466)。
文摘To predict the temperature of a motorized spindle more accurately,a novel temperature prediction model based on the back-propagation neural network optimized by adaptive particle swarm optimization(APSO-BPNN)is proposed.First,on the basis of the PSO-BPNN algorithm,the adaptive inertia weight is introduced to make the weight change with the fitness of the particle,the adaptive learning factor is used to obtain different search abilities in the early and later stages of the algorithm,the mutation operator is incorporated to increase the diversity of the population and avoid premature convergence,and the APSO-BPNN model is constructed.Then,the temperature of different measurement points of the motorized spindle is forecasted by the BPNN,PSO-BPNN,and APSO-BPNN models.The experimental results demonstrate that the APSO-BPNN model has a significant advantage over the other two methods regarding prediction precision and robustness.The presented algorithm can provide a theoretical basis for intelligently controlling temperature and developing an early warning system for high-speed motorized spindles and machine tools.
文摘Supercapacitors operating in aqueous solutions are low cost energy storage devices with high cycling stability and fast charging and discharging capabilities, but generally suffer from low energy densities. Here, we grow Ni(OH)2 nanoplates and RuO2 nanoparticles on high quality graphene sheets in order to maximize the specific capacitances of these materials. We then pair up a Ni(OH)2/graphene electrode with a RuO2/graphene electrode to afford a high performance asymmetrical supercapacitor with high energy and power density operating in aqueous solutions at a voltage of -1.5 V. The asymmetrical supercapacitor exhibits significantly higher energy densities than symmetrical RuO2-RuO2 supercapacitors or asymmetrical supercapacitors based on either RuO2- carbon or Ni(OH)2-carbon electrode pairs. A high energy density of -48 W.h/kg at a power density of -0.23 kW/kg, and a high power density of -21 kW/kg at an energy density of N14 W-h/kg have been achieved with our Ni(OH)2/graphene and RuO2/graphene asymmetrical supercapacitor. Thus, pairing up metal-oxide/graphene and metal-hydroxide/graphene hybrid materials for asymmetrical supercapacitors represents a new approach to high performance energy storage.
基金This work is supported by the National Natural Science Foundation of China (No. 21205139), the Application and Innovation Project of Chinese Ministry of Public Security (No. 2012YYCXXJXY127), and the Program for Liaoning Excellent Talents in University (No. LJQ2014130). MYY is thankful for the grant support from the National Natural Science Foundation of China (Nos. 20804037 and 21172194) and National High Technology Research and Development Program 863 (No. 2013AA102507). YZ, PHQ and CBM would like to thank the financial support from National Institutes of Health (No. EB015190), National Natural Science Foundation (No. CMMI-1234957 and DMR-0847758), Department of Defense Peer Reviewed Medical Research Program (No. W81XWH-12-1-0384), Oklahoma Center for the Advancement of Science and Technology (No. HR14-160) and Oklahoma Center for Adult Stem Cell Research (No. 434003).
文摘The most commonly found fingermarks at crime scenes are latent and, thus, an efficient method for detecting latent fingermarks is very important. However, traditional developing techniques have drawbacks such as low detection sensitivity, high background interference, complicated operation, and high toxicity. To tackle this challenge, we employed fluorescent NaYF4:Yb, Er upconversion nanoparticles (UCNPs), which can fluoresce visible light when excited by 980 nm human-safe near-infrared light, to stain the latent fingermarks on various substrate surfaces. The UCNPs were successfully used as a novel fluorescent label for the detection of latent fingermarks with high sensitivity, low background, high efficiency, and low toxicity on various substrates including non-infiltrating materials (glass, marble, aluminum alloy sheets, stainless steel sheets, aluminum foils, and plastic cards), semi-infiltrating materials (floor leathers, ceramic tiles, wood floor, and painted wood), and infiltrating materials such as various types of papers. This work shows that UCNPs are a versatile fluorescent label for the facile detection of fingermarks on virtually any material, enabling their practical applications in forensic sciences.
基金Project(Nos.PW 55/09 and DS 41/10) supported by the Department of Laboratory Diagnostics,Medical University of Lublin,Poland
文摘Disturbances in the metabolism of lipoprotein profiles and oxidative stress in hemodialyzed (HD) and post-renal transplant (Tx) patients are proatherogenic, but elevated concentrations of plasma high-density lipoprotein (HDL) reduce the risk of cardiovascular disease. We investigated the concentrations of lipid, lipoprotein, HDL particle, oxidized low-density lipoprotein (ox-LDL) and anti-ox-LDL, and paraoxonase-1 (PON-1) activity in HD (n=33) and Tx (n=71) patients who were non-smokers without active inflammatory disease, liver disease, diabetes, or malignancy. HD patients had moderate hypertriglyceridemia, normocholesterolemia, low HDL-C, apolipoprotein A-I (apoA-I) and HDL particle concentrations as well as PON-1 activity, and increased ox-LDL and anti-ox-LDL levels. Tx patients had hypertriglyceridemia, hypercholesterolemia, moderately decreased HDL-C and HDL particle concentrations and PON-1 activity, and moderately increased ox-LDL and anti-ox-LDL levels as compared to the reference, but ox-LDL and anti-ox-LDL levels and PON-1 activity were more disturbed in HD patients. However, in both patient groups, lipid and lipoprotein ratios (total cholesterol (TC)/HDL-C, LDL-C/HDL-C, triglyceride (TG)/HDL-C, HDL-C/non-HDL-C, apoA-I/apoB, HDL-C/apoA-I, TG/HDL) were atherogenic. The Spearman's rank coefficient test showed that the concentration of ox-LDL correlated positively with HDL particle level (R=0.363, P=0.004), and negatively with TC (R=-0.306, P=0.012), LDL-C (R=-0.283, P=0.020), and non-HDL-C (R=-0.263, P=0.030) levels in Tx patients. Multiple stepwise forward regression analysis in Tx patients demonstrated that ox-LDL concentration, as an independent variable, was associated significantly positively with HDL particle level. The results indicated that ox-LDL and de- creased PON-1 activity in Tx patients may give rise to more mildly-oxidized HDLs, which are less stable, easily undergo metabolic remodeling, generate a greater number of smaller pre-13-HDL particles, and thus accelerate reverse cholesterol transport, which may be beneficial for Tx patients. Further studies are necessary to confirm this.
基金supported by the National Natural Science Foundation of China (Grant Nos. 40971009 and 10811130470)the National Basic Research Program of China ("973" Project) (Grant No. 2009CB421304)
文摘Previous wind tunnel experiments on snow drift usually used artificial snow as a substitute of natural snow, which can not fully reflect the motion characteristics of snow drift in natural environments. In this paper we conducted a series of experiments in wind tunnel to investigate the motion of natural snow (fresh snow and old snow), which was collected out-door without destroying the surface structure. The results indicated that the threshold velocity of fresh snow is less than that of old snow, and that the mass flux rates of the two kinds of snow exponentially decrease with height whereas the snow transport rate increases exponentially with wind velocity. Based on the PIV measuring of the velocities of snow particles over two kinds of terrains (flat ground and roadbed), we found that the particle velocity obeys a Gaussian distribution for flat ground, top surface and leeward slope of the roadbed. However, for the windward slope of roadbed the particle velocity distribution displays poor correlation with a Gaussian function due to the acceleration of snow particles when saltating across the slop. Statistical analysis showed that impacting and liftoff velocities of snow particles also obey Gaussian distributions.
基金supported by the National Natural Science Foundation of China(Grant No.51576100)the Jiangsu Provincial Natural Science Foundation of China(Grant No.BK20140034)the Jiangsu Provincial Project of“Six Talent Summit”(Grant No.2014-XNY-002)
文摘Combustion characteristics of nanofluid fuels containing aluminum nanoparticles were investigated in half-opening slot tubes from the fundamental view. The effects of particle loading rates(0.25% and 2.5% by weight), type of base fuels(ethanol and butanol),and fuel flow rates(0.2, 0.6, and 1 mL/min) were studied in details. The combustion characteristics of the nanofluid fuels and pure based fuels were also examined to provide a comparison. Flame was unstable with reignition, stable state, nearly extinguishment repeatedly at low flow rate. At medium flow rate, flame height was increased and flame tended to be stable. At high flow rate,flame became unstable and was disturbed by the droplet forming and dripping significantly. Al atoms inside the oxide layer should be melted before the particles combustion, while Al oxide layer should be melted before the particles aggregates combustion. The effects of particles on the combustion characteristics, especially on the evaporation rate of base fuel, were discussed. The reasons for various combustion phenomena of nanofluid fuels were given, which can provide the useful guidance for the experimental research and practical applications of nanofluid fuels.
基金supported by the National Natural Science Foundation of China(Grant Nos.51222501 and 51221004)the Fundamental Research Funds for the Central Universities
文摘In the paper,the behavior of the particle acted by the oscillating bubble is studied using a high-speed video camera.The bubble is generated using a very low voltage of 55 V.Images are captured at a speed of 15000 fps(frames per second).It is found that the velocity of the particle is dependent on the liquid viscosity,particle size,and tube diameter.Particle velocity decreases with the increase of the glycron-water mixture viscosity.A model is presented to predict the velocity and verified by experimental results.These observations may be beneficial for the application in medical treatment.
基金support by the Fund for Talents Introduction of Chongqing University of Arts and Sciences (Grant No. Z2011RCYJ03)
文摘Magnetic nanoscale systems,including nanodots,nanofibers,nanowires and nanoparticles,are currently attracting great interest due to their interesting physical and promising applications in various fields,such as magnetic recording,sensors,target drugs and catalysts,as well as others.To achieve ultrahigh recording density,the method of heat assisted magnetic recording(HAMR) has been introduced.In this work,with the help of a Monte Carlo method,the mechanisms of thermally assisted magnetization switching in FePt single-domain particles driven by an external magnetic field are investigated,where the temperature in the particles is assumed to follow a Gaussian distribution.Two nucleation modes are observed for different distributions of temperature.One is initiated by many droplets,which join each other at the boundary of the system;the other is ini-tiated by many droplets at the boundary,but in growth tending toward the inner part of the system.An inverse proportional relationship between the metastable lifetime and the distribution is also found.
文摘An atomic layer deposition (ALD) method has been employed to synthesize Fe3O4/graphene and Ni/graphene composites. The structure and microwave absorbing properties of the as-prepared composites are investigated. The surfaces of graphene are densely covered by Fe3O4 or Ni nanoparticles with a narrow size distribution, and the magnetic nanoparticles are well distributed on each graphene sheet without significant conglomeration or large vacancies. The coated graphene materials exhibit remarkably improved electromagnetic (EM) absorption properties compared to the pristine graphene. The optimal reflection loss (RL) reaches -46.4 dB at 15.6 GHz with a thickness of only 1.4 mm for the Fe3O4/graphene composites obtained by applying 100 cycles of Fe2O3 deposition followed by a hydrogen reduction. The enhanced absorption ability arises from the effective impedance matching, multiple interfacial polarization and increased magnetic loss from the added magnetic constituents. Moreover, compared with other recently reported materials, the composites have a lower filling ratio and smaller coating thickness resulting in significantly increased EM absorption properties. This demonstrates that nanoscale surface modification of magnetic particles on graphene by ALD is a very promising way to design lightweight and high-efficiency microwave absorbers.
基金Project (No. 71-088/2007) supported by Program "Partnerships in Priority Areas", the Romanian Ministry of Education and Research
文摘We present an empirical model for the effective thermal conductivity (ETC) of a polymer composite that includes dependency on the filler size distribution-chosen as the Rosin-Rammler distribution. The ETC is determined based on certain hypotheses that connect the behavior of a real composite material A, to that of a model composite material B, filled with mono-dimensional filler. The application of these hypotheses to the Maxwell model for ETC is presented. The validation of the new model and its characteristic equation was carried out using experimental data from the reference. The comparison showed that by using the size distribution law a very good fit between the equation of the new model (the size distribution model for the ETC) and the reference experimental results is obtained, even for high volume fractions, up to about 50%.
基金supported in part by a guest professorship grant from the School of Geophysics and Information Technology, China University of Geosciences (Beijing)
文摘In the solar system, our Sun is Nature's most efficient particle accelerator. In large solar flares and fast coronal mass ejections(CMEs), protons and heavy ions can be accelerated to over ~GeV/nucleon. Large flares and fast CMEs often occur together. However there are clues that different acceleration mechanisms exist in these two processes. In solar flares, particles are accelerated at magnetic reconnection sites and stochastic acceleration likely dominates. In comparison, at CME-driven shocks,diffusive shock acceleration dominates. Besides solar flares and CMEs, which are transient events, acceleration of particles has also been observed in other places in the solar system, including the solar wind termination shock, planetary bow shocks, and shocks bounding the Corotation Interaction Regions(CIRs). Understanding how particles are accelerated in these places has been a central topic of space physics. However, because observations of energetic particles are often made at spacecraft near the Earth,propagation of energetic particles in the solar wind smears out many distinct features of the acceleration process. The propagation of a charged particle in the solar wind closely relates to the turbulent electric field and magnetic field of the solar wind through particle-wave interaction. A correct interpretation of the observations therefore requires a thorough understanding of the solar wind turbulence. Conversely, one can deduce properties of the solar wind turbulence from energetic particle observations. In this article I briefly review some of the current state of knowledge of particle acceleration and transport in the inner heliosphere and discuss a few topics which may bear the key features to further understand the problem of particle acceleration and transport.