The density functional theory （DFT） is the most popular method for evaluating bond dis- sociation enthalpies （BDEs） of most molecules. Thus, we are committed to looking for alternative methods that can balance the...The density functional theory （DFT） is the most popular method for evaluating bond dis- sociation enthalpies （BDEs） of most molecules. Thus, we are committed to looking for alternative methods that can balance the computational cost and higher precision to the best for large systems. The performance of DFT, double-hybrid DFT, and high-level com- posite methods are examined. The tested sets contain monocyclic and polycyclic aromatic molecules, branched hydrocarbons, small inorganic molecules, etc. The results show that the mPW2PLYP and G4MP2 methods achieve reasonable agreement with the benchmark val- ues for most tested molecules, and the mean absolute deviations are 2.43 and 1.96 kcal/mol after excluding the BDEs of branched hydrocarbons. We recommend the G4MP2 is the most appropriate method for small systems （atoms number≤20）; the double-hybrid DFT methods are advised for large aromatic molecules in medium size （20≤atoms number≤50）, and the double-hybrid DFT methods with empirical dispersion correction are recommended for long-chain and branched hydrocarbons in the same size scope; the DFT methods are ad- vised to apply for large systems （atoms number〉50）, and the M06-2X and B3P86 methods are also favorable. Moreover, the differences of optimized geometry of different methods are discussed and the effects of basis sets for various methods are investigated.展开更多
Using the recently developed finite-basis-set method with B splines, excited states of H atoms in a magnetic field have been calculated. Energy levels are presented for the ten excited states, 2so, 3d＇0, 3po, 3p-1, 3...Using the recently developed finite-basis-set method with B splines, excited states of H atoms in a magnetic field have been calculated. Energy levels are presented for the ten excited states, 2so, 3d＇0, 3po, 3p-1, 3d_1, 4d-1, 3d-2, 4d-2, 4f-2 , and 5f-2 as a function of magnetic field strengths with a range from zero up to 2.35 × 10^6 T. The obtained results are compared with available high accuracy theoretical data reported in the literature and found to be in excellent agreement. The comparison also shows that the current method can produce energy levels with an accuracy higher than the existing high accuracy method [Phys. Rev. A 54 （1996） 287]. Here high accuracy energy levels are for the first time reported for the 3d＇0, 4d-1, 4d-2, 4f-2, and 5f-2 states.展开更多
A high-precision pseudo-noise ranging system is often required in satellite-formation missions. But in an actual PN ranging system, digital signal processing limits the ranging accuracy, only level up with meter-scale...A high-precision pseudo-noise ranging system is often required in satellite-formation missions. But in an actual PN ranging system, digital signal processing limits the ranging accuracy, only level up with meter-scale. Using non-integer chip to sample time ratio, noncommensurate sampling was seen as an effective solution to cope with the drawback of digital effects. However, researchers only paid attention to selecting specific ratios or giving a simulation model to verify the effectiveness of the noncommensurate ratios. A qualitative analysis model is proposed to characterize the relationship between the range accuracy and the noncommensurate sampling parameters. Moreover, a method is also presented which can be used to choose the noncommensurate ratio and the correlation length to get higher phase delay distinguishability and lower range jitter. The simulation results indicate the correctness of our analyses and the optimal ranging accuracy can be up to centimeter-level with the proposed approach.展开更多
Background： To understand an effective golf swing, both swing speed and impact precision must be thoroughly and simultaneously examined. The aim of this study was to perform both swing speed test and impact precision...Background： To understand an effective golf swing, both swing speed and impact precision must be thoroughly and simultaneously examined. The aim of this study was to perform both swing speed test and impact precision test to ascertain what swing type determines an effective impact. Methods： Seven golfers from a college team （handicap： 0--12） were recruited to complete a swing speed test and impact precision test using a 5-iron club, A force plate and electromyography （EMG） system were used to collect data in the swing speed test to compare the difference between two motion sequences. High speed video cameras were used to determine the displacement of rotation center for impact precision test. Results： The results showed a significant difference （p 〈 0.01） in clubhead speed with different motion sequences and muscle contraction patterns. In the impact precision test, the displacement of the rotation center which defined as the inner center point of the C7 was significantly different （p 〈 0.05） between different ball impacted marks on club face. Conclusion： The vertical peak ground reaction force on left foot occurring before impact and the left latissimus dorsi contracting prior to the right pectoralis major represent a superior skill by allowing the club to strike the ball with normal collision at a faster speed.展开更多
The multisensor online measure system for high precision marking and cutting robot system is designed and the data fusion method is introduced, which combines augment state multiscale process with extend Kalman filter...The multisensor online measure system for high precision marking and cutting robot system is designed and the data fusion method is introduced, which combines augment state multiscale process with extend Kalman filter. The technology measuring the three-dimensional deforming information of profiled bars is applied. The experimental result shows that applying the multisensor data fusion technology can enhance the measure precision and the reliability of measure system.展开更多
In this study, the suitability of current design methods for the 0.2% proof yield strength of the comer regions for high strength cold-formed steel at normal room temperature was investigated. The current standard pre...In this study, the suitability of current design methods for the 0.2% proof yield strength of the comer regions for high strength cold-formed steel at normal room temperature was investigated. The current standard predictions are generally accurate for outer comer specimen but conservative for inner comer specimen. Based on the experimental results, an analytical model to predict the comer strength of high strength cold-formed steel at normal room temperature was also proposed. The comparison indicated that the proposed model predicted well the comer strength of high strength cold-formed steel not only at normal room temperature but also at elevated temperatures. It is shown that the predictions obtained from the proposed model agree well with the test results. Generally the comer strength enhancement of high strength cold-formed steel decreases when the temperature increases.展开更多
Soil Moisture and Ocean Salinity （SMOS） Level 3 （L3） sea surface salinity （SSS） products are provided by the Barcelona Expert Centre （BEC）. Strong biases were observed on the SMOS SSS products, thus the data f...Soil Moisture and Ocean Salinity （SMOS） Level 3 （L3） sea surface salinity （SSS） products are provided by the Barcelona Expert Centre （BEC）. Strong biases were observed on the SMOS SSS products, thus the data from the Centre Aval de Traitement des Donnees SMOS （CATDS） were adjusted for biases using a large-scale correction derived from observed differences between the SMOS SSS and World Ocean Atlas （WOA） climatology data. However, this large-scale correction method is not suitable for correcting the large gradient of salinity biases. Here, we present a method for the correction of SSS regional bias of the monthly L3 products. Based on the stable characteristics of the large SSS biases from month to month in some regions, corrected SMOS SSS maps can be obtained from the monthly mean values after removing the regional biases. The accuracy of the SMOS SSS measurements is greatly improved, especially near the coastline, at high latitudes, and in some open ocean regions. The SMOS and ISAS SSS data are also compared with Aquarius SSS to verify the corrected SMOS SSS data. The correction method presented here only corrects annual mean biases. The measurement accuracy of the SSS may be improved by considering the influence of atmospheric and ocean circulation in different seasons and years.展开更多
This paper presents a new method of improving Global Positioning System(GPS)positioning precision. Based on the altitude hold mode, the method does not need any other equipment. Under this constraint condition, the To...This paper presents a new method of improving Global Positioning System(GPS)positioning precision. Based on the altitude hold mode, the method does not need any other equipment. Under this constraint condition, the Total Least Squares(TLS) algorithm is used to prove that the method is effective. Theoretical analysis shows that the algorithm can significantly improve the GPS positioning precision.展开更多
As a transport means of oil and gas the submarine pipeline has many merits, such as continuous delivery, large conveying capacity, convenient management, etc. A tube was chosen in our study to simulate the submarine p...As a transport means of oil and gas the submarine pipeline has many merits, such as continuous delivery, large conveying capacity, convenient management, etc. A tube was chosen in our study to simulate the submarine pipeline in the experiments. A high accuracy instrument ADV and high precision point-type pressure sensors were used to measure the parameters of the flow field, including the pressure distribution, velocities at seven cross sections near the submarine pipeline with five different clearance ratios, and twelve dynamic pressure values around the pipeline. The pressure distributions and velocity changes around the pipe under dif- ferent flow velocities and clearance ratios were analyzed. These results might be useful for further study of submarine pipeline ero- sion and protection.展开更多
文摘The density functional theory （DFT） is the most popular method for evaluating bond dis- sociation enthalpies （BDEs） of most molecules. Thus, we are committed to looking for alternative methods that can balance the computational cost and higher precision to the best for large systems. The performance of DFT, double-hybrid DFT, and high-level com- posite methods are examined. The tested sets contain monocyclic and polycyclic aromatic molecules, branched hydrocarbons, small inorganic molecules, etc. The results show that the mPW2PLYP and G4MP2 methods achieve reasonable agreement with the benchmark val- ues for most tested molecules, and the mean absolute deviations are 2.43 and 1.96 kcal/mol after excluding the BDEs of branched hydrocarbons. We recommend the G4MP2 is the most appropriate method for small systems （atoms number≤20）; the double-hybrid DFT methods are advised for large aromatic molecules in medium size （20≤atoms number≤50）, and the double-hybrid DFT methods with empirical dispersion correction are recommended for long-chain and branched hydrocarbons in the same size scope; the DFT methods are ad- vised to apply for large systems （atoms number〉50）, and the M06-2X and B3P86 methods are also favorable. Moreover, the differences of optimized geometry of different methods are discussed and the effects of basis sets for various methods are investigated.
文摘Using the recently developed finite-basis-set method with B splines, excited states of H atoms in a magnetic field have been calculated. Energy levels are presented for the ten excited states, 2so, 3d＇0, 3po, 3p-1, 3d_1, 4d-1, 3d-2, 4d-2, 4f-2 , and 5f-2 as a function of magnetic field strengths with a range from zero up to 2.35 × 10^6 T. The obtained results are compared with available high accuracy theoretical data reported in the literature and found to be in excellent agreement. The comparison also shows that the current method can produce energy levels with an accuracy higher than the existing high accuracy method [Phys. Rev. A 54 （1996） 287]. Here high accuracy energy levels are for the first time reported for the 3d＇0, 4d-1, 4d-2, 4f-2, and 5f-2 states.
基金Project(60904090) supported by the National Natural Science Foundation of China
文摘A high-precision pseudo-noise ranging system is often required in satellite-formation missions. But in an actual PN ranging system, digital signal processing limits the ranging accuracy, only level up with meter-scale. Using non-integer chip to sample time ratio, noncommensurate sampling was seen as an effective solution to cope with the drawback of digital effects. However, researchers only paid attention to selecting specific ratios or giving a simulation model to verify the effectiveness of the noncommensurate ratios. A qualitative analysis model is proposed to characterize the relationship between the range accuracy and the noncommensurate sampling parameters. Moreover, a method is also presented which can be used to choose the noncommensurate ratio and the correlation length to get higher phase delay distinguishability and lower range jitter. The simulation results indicate the correctness of our analyses and the optimal ranging accuracy can be up to centimeter-level with the proposed approach.
文摘Background： To understand an effective golf swing, both swing speed and impact precision must be thoroughly and simultaneously examined. The aim of this study was to perform both swing speed test and impact precision test to ascertain what swing type determines an effective impact. Methods： Seven golfers from a college team （handicap： 0--12） were recruited to complete a swing speed test and impact precision test using a 5-iron club, A force plate and electromyography （EMG） system were used to collect data in the swing speed test to compare the difference between two motion sequences. High speed video cameras were used to determine the displacement of rotation center for impact precision test. Results： The results showed a significant difference （p 〈 0.01） in clubhead speed with different motion sequences and muscle contraction patterns. In the impact precision test, the displacement of the rotation center which defined as the inner center point of the C7 was significantly different （p 〈 0.05） between different ball impacted marks on club face. Conclusion： The vertical peak ground reaction force on left foot occurring before impact and the left latissimus dorsi contracting prior to the right pectoralis major represent a superior skill by allowing the club to strike the ball with normal collision at a faster speed.
文摘The multisensor online measure system for high precision marking and cutting robot system is designed and the data fusion method is introduced, which combines augment state multiscale process with extend Kalman filter. The technology measuring the three-dimensional deforming information of profiled bars is applied. The experimental result shows that applying the multisensor data fusion technology can enhance the measure precision and the reliability of measure system.
基金Project (No. 113000-X80703) supported by the Postdoctoral Fund of Zhejiang Province, China
文摘In this study, the suitability of current design methods for the 0.2% proof yield strength of the comer regions for high strength cold-formed steel at normal room temperature was investigated. The current standard predictions are generally accurate for outer comer specimen but conservative for inner comer specimen. Based on the experimental results, an analytical model to predict the comer strength of high strength cold-formed steel at normal room temperature was also proposed. The comparison indicated that the proposed model predicted well the comer strength of high strength cold-formed steel not only at normal room temperature but also at elevated temperatures. It is shown that the predictions obtained from the proposed model agree well with the test results. Generally the comer strength enhancement of high strength cold-formed steel decreases when the temperature increases.
基金Supported by the National Natural Science Foundation of China(No.41076117)
文摘Soil Moisture and Ocean Salinity （SMOS） Level 3 （L3） sea surface salinity （SSS） products are provided by the Barcelona Expert Centre （BEC）. Strong biases were observed on the SMOS SSS products, thus the data from the Centre Aval de Traitement des Donnees SMOS （CATDS） were adjusted for biases using a large-scale correction derived from observed differences between the SMOS SSS and World Ocean Atlas （WOA） climatology data. However, this large-scale correction method is not suitable for correcting the large gradient of salinity biases. Here, we present a method for the correction of SSS regional bias of the monthly L3 products. Based on the stable characteristics of the large SSS biases from month to month in some regions, corrected SMOS SSS maps can be obtained from the monthly mean values after removing the regional biases. The accuracy of the SMOS SSS measurements is greatly improved, especially near the coastline, at high latitudes, and in some open ocean regions. The SMOS and ISAS SSS data are also compared with Aquarius SSS to verify the corrected SMOS SSS data. The correction method presented here only corrects annual mean biases. The measurement accuracy of the SSS may be improved by considering the influence of atmospheric and ocean circulation in different seasons and years.
文摘This paper presents a new method of improving Global Positioning System(GPS)positioning precision. Based on the altitude hold mode, the method does not need any other equipment. Under this constraint condition, the Total Least Squares(TLS) algorithm is used to prove that the method is effective. Theoretical analysis shows that the algorithm can significantly improve the GPS positioning precision.
文摘As a transport means of oil and gas the submarine pipeline has many merits, such as continuous delivery, large conveying capacity, convenient management, etc. A tube was chosen in our study to simulate the submarine pipeline in the experiments. A high accuracy instrument ADV and high precision point-type pressure sensors were used to measure the parameters of the flow field, including the pressure distribution, velocities at seven cross sections near the submarine pipeline with five different clearance ratios, and twelve dynamic pressure values around the pipeline. The pressure distributions and velocity changes around the pipe under dif- ferent flow velocities and clearance ratios were analyzed. These results might be useful for further study of submarine pipeline ero- sion and protection.
