高性能CCL基材品质控制浅析

随着PCB设计走向高密度、精细化，以及PCB在特殊环境下应用所产生的CAF现象日益成为关注的焦点；同时随着欧盟的Robs法规的推出，PCB行业要求材料的使用以及装配过程的无铅化，特别是无铅化装配条件下，高的装配温度要求材料具有优良的耐热性才能满足装配要求。

矿物掺合料对水泥基材料自收缩变形行为的影响及机理研究

采用体积测量和长度测量相结合的试验手段,对高性能水泥基材料的自收缩变形规律进行了分阶段、全过程的研究分析,研究了矿物掺合料的种类(粉煤灰和磨细矿渣)、掺入比以及细度对自收缩的影响。结合毛细管张力理论,探讨了粉煤灰和磨细矿渣对自收缩的影响机理。

PCB镀通孔发生“空洞”的根本原因和对策

文章概述了多层板镀通孔发生"空洞"的根本原因与对策。基材、钻孔、孔壁粗糙度、孔尺寸、化学镀铜和电镀铜等都会影响PTH的"空洞"问题。

Influence of different curing regimes on the microstructure and macro performance of UHPFRCC

This study investigates the influence of different curing regimes on the microstructure and macro properties of ultra-high performance fiber reinforced cementitious composite （UHPFRCC）, and aims to discover whether it is possible to produce qualified UHPFRCC using different curing regimes. A control mix of UHPFRCC is prepared. The mechanical performance and the short-term durability of the UHPFRCC matrix under three curing regimes are studied. In addition, the microstructures of the UHPFRCC matrix with different curing conditions are analyzed by combining scanning electron microscopy （SEM） and mercury intrusion porosimetry （MIP）. The results explore how different UHPFRCC curing regimes affect its microstructure and how the microstructure affects its macro behavior. Heat and steam curing for 3 d is succeeded to produce the UHPFRCC with nearly the same mechanical properties and durability as those of the 90 d standard curing. However, the heat cured UHPFRCC does not show great resistance to chloride-ion penetration.

快速植生垫护坡结构在航道工程中的应用

快速植生垫护坡作为一种新型生态护坡,具有较好的抗冲刷性、生态环保性、耐久性、施工便捷性及较高的性价比,在工程实践中具有较好的防护和生态效果。本文详细介绍了快速植生垫的结构特点、试验研究和工程应用,为生态航道护岸工程提供参考。

Main properties of ultra-high performance fiber reinforced cement composites under couple effect of load and environment

This study aims to reveal the mechanism that how the content of steel fibers and strength grades affect the macro performance of the ultra-high performance fiber reinforced cementitious composite （UHPFRCC） and to study the UHPFRCC durability under the combined effect of loads and environments. Three types of high and ultra-high performance fiber reinforced cement composites with different strength grades （100, 150, 200 MPa） and different steel fiber volume fractions （0%, 1%, 2%, 3%） are prepared. The main properties of mechanical performance and short-term durability are studied. A preloading frame is designed to apply a four- point load external flexural stress with a stress selection ratio of 0.5 for UHPFRCC150 specimens. The results show that the growth in strength grade with a proper content of steel fiber greatly increases the strength and toughness of the HPFRCC and the UHPFRCC while decreasing the dry-shrinkage ratio. For the loaded specimens, the existence of steel fiber can reduce the negative influence of tensile stress on the Cl- penetration resistance of the UHPFRCC in addition to improving its ability to resist the freeze-thaw damage.

Deformation behavior of high performance fiber reinforced cementitious composite prepared with asphalt emulsion

A novel engineered cementitious composite(ECC) was prepared with the complex binder of Portland cement and asphalt emulsion.By adjusting the amount of asphalt emulsion,different mixture proportions were adopted in experiments,including four-point bending test,compressive test,and scanning electric microscopy(SEM).The SEM observation was conducted to evaluate the contribution of polyvinyl alcohol(PVA) fiber and asphalt emulsion to the composite toughening mechanism.The tests results show that the most remarkable deflection-hardening behavior and saturated multiple cracking are achieved when the content of asphalt emulsion is 10%.However,excessive content of asphalt emulsion causes severe damages on the deformation behavior as well as loss in compressive strength of the mixture.SEM observation indicates that the influence of asphalt emulsion on the fiber/matrix interfacial property changes the dominant fiber failure type from rupture into pull-out mode,and thus causes beneficial effects for strain-hardening behavior.

Numerical study on flexural behaviors of steel reinforced engineered cementitious composite(ECC) and ECC/concrete composite beams

Engineered cementitious composite(ECC)is a class of high performance cementitious composites with pseudo strain-hardening behavior and excellent crack control capacity.Substitution of concrete with ECC can largely reduce the cracking and durability problems associated with brittleness of concrete.In this paper,a simplified constitutive model of the ECC material was applied to simulate the flexural behaviors of the steel reinforced ECC and ECC/concrete composite beams with finite element method.The simulation results are found to be in good agreement with test results,indicating that the finite element model is reasonably accurate in simulating the flexural behaviors of the steel reinforced ECC flexural members.The effects of the ECC modulus,ECC tensile ductility,ECC thickness and ECC position on flexural behaviors in terms of ultimate moment,deflection and the maximum crack width of the steel reinforced ECC or ECC/concrete composite beam are hence evaluated.

Graphene-based Li-ion hybrid supercapacitors with ultrahigh performance

There is a growing demand for hybrid supercapacitor systems to overcome the energy density limitation of existing-generation electric double layer capacitors （EDLCs）, leading to next generation-Ⅱ supercapacitors with minimum sacrifice in power density and cycle life. Here, an advanced graphene-based hybrid system, consisting of a graphene-inserted Li4Ti5O12 （LTO） composite anode （G-LTO） and a three-dimensional porous graphene-sucrose cathode, has been fabricated for the purpose of combining both the benefits of Li-ion batteries （energy source） and supercapacitors （power source）. Graphene-based materials play a vital role in both electrodes in respect of the high performance of the hybrid supercapacitor. For example, compared with the theoretical capacity of 175 mA-h.g-1 for pure LTO, the G-LTO nanocomposite delivered excellent reversible capacities of 207, 190, and 176 mA·1h·g-1 at rates of 0.3, 0.5, and 1 C, respectively, in the potential range 1.0-2.5 V vs. Li/Li＋; these are among the highest values for LTO-based nano- composites at the same rates and potential range. Based on this, an optimized hybrid supercapacitor was fabricated following the standard industry procedure; this displayed an ultrahigh energy density of 95 Wh·kg-1 at a rate of 0.4 C （2.5 h） over a wide voltage range （0-3 V）, and still retained an energy density of 32 Wh·kg-1 at a high rate of up to 100 C, equivalent to a full discharge in 36 s, which is exceptionally fast for hybrid supercapacitors. The excellent performance of this Li-ion hybrid supercapacitor indicates that graphene-based materials may indeed play a significant role in next-generation supercapacitors with excellent electrochemical performance.