Poly （ m-phenylene isophthalamine） （PMIA） and Poly（ p-phenylene terphthalamine） （PPTA） are among the most important high-temperature resistant aramid fibers. The pyrolysis behaviors of these two fibers under i...Poly （ m-phenylene isophthalamine） （PMIA） and Poly（ p-phenylene terphthalamine） （PPTA） are among the most important high-temperature resistant aramid fibers. The pyrolysis behaviors of these two fibers under inert gases were studied using pyrolysis-gas chromatography/mass spectrometry （Py-GC/MS） and thermogravimetric analysis coupled with mass spectrometry （ TGA-DTA/MS ）. The pyrolysis processes of PMIA and PPTA are distinguishing, and the stepwise pyrolysates reflect these differences. A mechanism system of pyrolysis is suggested, which involving hydrolysis and homolysis, At low pyrolysis temperatures, hydrolysis is a primary reaction, and it is very noticeable in the first-step pyrolysis region of PMIA. Elevating pyrolysis temperature, homolysis is enhanced and keep a large advantage in the high temperature range. On the other hand, at higher temperatures, carbonization happens and the homolysis and carbonization of PPTA are emphasized more than of PMIA.展开更多
Building on the success of the company’s unique Evolon？product,Freudenberg Performance Materials has now pushed the limits even further by developing Evolon？New Generation.This high-tech textile is made from super-...Building on the success of the company’s unique Evolon？product,Freudenberg Performance Materials has now pushed the limits even further by developing Evolon？New Generation.This high-tech textile is made from super-microfilaments that are half the thickness and twice the density of those used in the original Evolon？.Evolon？展开更多
文摘Poly （ m-phenylene isophthalamine） （PMIA） and Poly（ p-phenylene terphthalamine） （PPTA） are among the most important high-temperature resistant aramid fibers. The pyrolysis behaviors of these two fibers under inert gases were studied using pyrolysis-gas chromatography/mass spectrometry （Py-GC/MS） and thermogravimetric analysis coupled with mass spectrometry （ TGA-DTA/MS ）. The pyrolysis processes of PMIA and PPTA are distinguishing, and the stepwise pyrolysates reflect these differences. A mechanism system of pyrolysis is suggested, which involving hydrolysis and homolysis, At low pyrolysis temperatures, hydrolysis is a primary reaction, and it is very noticeable in the first-step pyrolysis region of PMIA. Elevating pyrolysis temperature, homolysis is enhanced and keep a large advantage in the high temperature range. On the other hand, at higher temperatures, carbonization happens and the homolysis and carbonization of PPTA are emphasized more than of PMIA.
文摘Building on the success of the company’s unique Evolon？product,Freudenberg Performance Materials has now pushed the limits even further by developing Evolon？New Generation.This high-tech textile is made from super-microfilaments that are half the thickness and twice the density of those used in the original Evolon？.Evolon？
