An efficient synthesis of 2,6-pyridine dimethyl formate happened under the microwave irradiation is proposed. It is noteworthy that some factors influence the product yield such as time, temperature, ratio of reactant...An efficient synthesis of 2,6-pyridine dimethyl formate happened under the microwave irradiation is proposed. It is noteworthy that some factors influence the product yield such as time, temperature, ratio of reactants, and acidity which were discussed. The optimized quantity of 2,6-pyridine dimethyl acid is 10 mmol and methanol is 25 mmol. The yield is up to 95%-96% when using 2 mL 30% sulfuric acid. All products have been characterized by IR and 1H NMR.展开更多
Abies georgei var. smithii is a dominant species playing an important role in protecting biodiversity and sustaining the forestry ecosystems in Southeastern Tibetan Plateau. Stem sap flows of five different diameters ...Abies georgei var. smithii is a dominant species playing an important role in protecting biodiversity and sustaining the forestry ecosystems in Southeastern Tibetan Plateau. Stem sap flows of five different diameters at the breast height(DBH) A. georgei var. smithii samples were monitored continuously with the thermal dissipation probe for the entire growing period in order to understand the water transportation mechanism and the effects of environmental factors on its transpiration and growth. Relative environment factors, temperature and humidity of air, photosynthetically active radiation, rainfall, and wind speed, soil moisture, etc. were measured by the automatic weather stations. Diurnal and seasonal variations in sap flow rate with the different stem diameters and their correlations with meteorological factors were analyzed. The diurnal change in sap flow velocity showed a single-peak curve at the daily time scale, whereas a lower sap flow velocity can be observed in the largest DBH sample tree at night. The maximum average velocity was observed in August, whereas the minimum velocity was observed in January, and a large amount of water evaporated in summer owing to the higher sap flow velocity. In addition, sap flow velocity was closely related to changes in the micrometeorological factors, with average sap flow velocity showing significant linear correlations with air temperature, photosynthetically active radiation, rainfall, and vapor pressure deficit of air and soil moisture. Therefore, some measures, improving the light and temperature conditions, should be taken for protecting A. georgei var. smithii population in the Tibetan Plateau.展开更多
The fraction of photosynthetically active radiation （FPAR） is a key variable in the assessment of vegetation productivity and land ecosystem carbon cycles. Based on ground-measured corn hyperspectral reflectance and...The fraction of photosynthetically active radiation （FPAR） is a key variable in the assessment of vegetation productivity and land ecosystem carbon cycles. Based on ground-measured corn hyperspectral reflectance and FPAR data over Northeast China, the correlations between corn-canopy FPAR and hyperspectral reflectance were analyzed, and the FPAR estimation performances using vegetation index （VI） and neural network （NN） methods with different two-band-combination hyperspectral reflectance were investigated. The results indicated that the corn-canopy FPAR retained almost a constant value in an entire day. The negative correlations between FPAR and visible and shortwave infrared reflectance （SWIR） bands are stronger than the positive correlations between FPAR and near-infrared band re- flectance （NIR）. For the six VIs, the normalized difference vegetation index （NDVI） and simple ratio （SR） performed best for estimating corn FPAR （the maximum R2 of 0.8849 and 0.8852, respectively）. However, the NN method esti- mated results （the maximum Rz is 0.9417） were obviously better than all of the VIs. For NN method, the two-band combinations showing the best corn FPAR estimation performances were from the NIR and visible bands; for VIs, however, they were from the SWIR and NIR bands. As for both the methods, the SWIR band performed exceptionally well for corn FPAR estimation. This may be attributable to the fact that the reflectance of the SWIR band were strongly controlled by leaf water content, which is a key component of corn photosynthesis and greatly affects the absorption of photosynthetically active radiation （APAR）, and makes further impact on corn-canopy FPAR.展开更多
Investigations are directed to the development of high-power sources ofUWB （ultrawideband） radiation based on excitation of anterma arrays with bipolar voltage pulses. In the previously designed high-power UWB sourc...Investigations are directed to the development of high-power sources ofUWB （ultrawideband） radiation based on excitation of anterma arrays with bipolar voltage pulses. In the previously designed high-power UWB sources only one bipolar pulse former and different feeder systems for pulse distribution through the array elements were used. By means of this approach, a number of UWB sources were created with the bipolar voltage pulse length ranging from 0.2 to 2 ns and effective potential of radiation ranging from 0.4 to 3 MV. The approach has got a restriction related to the electrical breakdown in a bipolar voltage pulse former. A new approach to the creation of high-power UWB sources based on a multicharmel bipolar pulse former is suggested： the number of bipolar pulse formers is equal to the number of antennas in the array. The main problem in realization of this approach is a stable operation of bipolar pulse formers in order to ensure a coherent summation of radiated pulses in the far-field zone. The result of this work is the instability of-150 ps at the pulse length of 3 ns obtained in a one-channel bipolar pulse former indicating that the suggested approach is realizable.展开更多
文摘An efficient synthesis of 2,6-pyridine dimethyl formate happened under the microwave irradiation is proposed. It is noteworthy that some factors influence the product yield such as time, temperature, ratio of reactants, and acidity which were discussed. The optimized quantity of 2,6-pyridine dimethyl acid is 10 mmol and methanol is 25 mmol. The yield is up to 95%-96% when using 2 mL 30% sulfuric acid. All products have been characterized by IR and 1H NMR.
基金supported by the Tibetan Natural Scientific Foundation of China (13-28)Tibetan Linzhi National Forest Ecological Research Station (2012-LYPT-DW-016)+1 种基金Promotion Plan of Plateau Basic Ecological Academic Team Abilitysupported by CFERN&GENE Award funds on ecological paper
文摘Abies georgei var. smithii is a dominant species playing an important role in protecting biodiversity and sustaining the forestry ecosystems in Southeastern Tibetan Plateau. Stem sap flows of five different diameters at the breast height(DBH) A. georgei var. smithii samples were monitored continuously with the thermal dissipation probe for the entire growing period in order to understand the water transportation mechanism and the effects of environmental factors on its transpiration and growth. Relative environment factors, temperature and humidity of air, photosynthetically active radiation, rainfall, and wind speed, soil moisture, etc. were measured by the automatic weather stations. Diurnal and seasonal variations in sap flow rate with the different stem diameters and their correlations with meteorological factors were analyzed. The diurnal change in sap flow velocity showed a single-peak curve at the daily time scale, whereas a lower sap flow velocity can be observed in the largest DBH sample tree at night. The maximum average velocity was observed in August, whereas the minimum velocity was observed in January, and a large amount of water evaporated in summer owing to the higher sap flow velocity. In addition, sap flow velocity was closely related to changes in the micrometeorological factors, with average sap flow velocity showing significant linear correlations with air temperature, photosynthetically active radiation, rainfall, and vapor pressure deficit of air and soil moisture. Therefore, some measures, improving the light and temperature conditions, should be taken for protecting A. georgei var. smithii population in the Tibetan Plateau.
基金Under the auspices of National Key Research Program of Global Change Research (No.2010CB951302)National Natural Science Fundation of China (No.40771146)China Postdoctoral Science Foundation Funded Project (No.07Z7601MZ1)
文摘The fraction of photosynthetically active radiation （FPAR） is a key variable in the assessment of vegetation productivity and land ecosystem carbon cycles. Based on ground-measured corn hyperspectral reflectance and FPAR data over Northeast China, the correlations between corn-canopy FPAR and hyperspectral reflectance were analyzed, and the FPAR estimation performances using vegetation index （VI） and neural network （NN） methods with different two-band-combination hyperspectral reflectance were investigated. The results indicated that the corn-canopy FPAR retained almost a constant value in an entire day. The negative correlations between FPAR and visible and shortwave infrared reflectance （SWIR） bands are stronger than the positive correlations between FPAR and near-infrared band re- flectance （NIR）. For the six VIs, the normalized difference vegetation index （NDVI） and simple ratio （SR） performed best for estimating corn FPAR （the maximum R2 of 0.8849 and 0.8852, respectively）. However, the NN method esti- mated results （the maximum Rz is 0.9417） were obviously better than all of the VIs. For NN method, the two-band combinations showing the best corn FPAR estimation performances were from the NIR and visible bands; for VIs, however, they were from the SWIR and NIR bands. As for both the methods, the SWIR band performed exceptionally well for corn FPAR estimation. This may be attributable to the fact that the reflectance of the SWIR band were strongly controlled by leaf water content, which is a key component of corn photosynthesis and greatly affects the absorption of photosynthetically active radiation （APAR）, and makes further impact on corn-canopy FPAR.
文摘Investigations are directed to the development of high-power sources ofUWB （ultrawideband） radiation based on excitation of anterma arrays with bipolar voltage pulses. In the previously designed high-power UWB sources only one bipolar pulse former and different feeder systems for pulse distribution through the array elements were used. By means of this approach, a number of UWB sources were created with the bipolar voltage pulse length ranging from 0.2 to 2 ns and effective potential of radiation ranging from 0.4 to 3 MV. The approach has got a restriction related to the electrical breakdown in a bipolar voltage pulse former. A new approach to the creation of high-power UWB sources based on a multicharmel bipolar pulse former is suggested： the number of bipolar pulse formers is equal to the number of antennas in the array. The main problem in realization of this approach is a stable operation of bipolar pulse formers in order to ensure a coherent summation of radiated pulses in the far-field zone. The result of this work is the instability of-150 ps at the pulse length of 3 ns obtained in a one-channel bipolar pulse former indicating that the suggested approach is realizable.
